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Deacylation of pyrrole and other aromatic ketones
Mercury in organic chemistry. 28. Synthesis of (.pi.-allyl)palladium compounds by remote palladium migration
Funebrine, a structurally novel pyrrole alkaloid, and other .gamma.-hydroxyisoleucine-related metabolites of Quararibea funebris (Llave) Vischer (Bombacaceae)
Aureolic acid antibiotics: synthesis of naphthocyclobutene precursors
Electron donor-acceptor quenching and photoinduced electron transfer for coumarin dyes
Aerosol direct fluorination: alkyl halides. 2. Chlorine shifts and the stability of radicals
Enamines from iodine oxidation of trialkylamines. 1. Electrophilic capture by cationic heterocyclic rings
Quasi-concerted allylic rearrangement in the reaction of allylic chlorides with methyltin tris(methanethiolate)
Structural effects in solvolytic reactions. 47. Effects of p-alkyl and p-cycloalkyl groups on the carbon-13 NMR shifts of the cationic carbon center in p-alkyl-tert-cumyl cations
Chemistry of organosilicon compounds. 191. Acetalization of carbonyl compounds with alkoxysilanes catalyzed by iodotrimethylsilane. One-pot allylation reactions of carbonyl compounds to homoallyl ethers using an allylsilane
Photochemical aromatic cyanomethylation: aromatic substitution by way of radical cations
Cyclodehydration of 1,4-butanediols by pentaethoxyphosphorane
Masthead
Synthesis and absolute configuration of (-)-rothrockene, a non-head-to-tail monoterpene
Photostimulated reactions of o-bis(phenylsulfonyl)benzene derivatives with sodium arenethiolates in dimethyl sulfoxide. Evidence for competing pathways involving a common intermediate .sigma. radical
Synthesis of pyrethroid amides via epoxy amide cyclization
Novel synthesis of 3,5-disubstituted pyridines by 1,4-cycloaddition of 1-aza-1,3-butadienes with enamines
An unusual oxidative dimerization of 2-(vinyloxy)phenols
Facile, economical synthesis of L-[.alpha.-2H]-.alpha.-amino acids
Rauwolfia alkaloid synthesis approach employing the zwitterionic amino-Claisen rearrangement. Improvements in the efficiency for yohimbane ring construction and unambiguous de-ring-fusion stereochemical assignments
A convenient synthesis of 12,12,12-trifluorododecanoic acid
A novel fragmentation mechanism for 5-fluorouracil-olefin photocycloaddition products to 5-substituted uracils. A synthon for the uracil 5-carbanion
Reactive nitrogenous molecules from Meldrum's acid derivatives, pyrrole-2,3-diones, and isoxazolones
Benzopyrans. 17. Triethylamine-mediated transformation of 4-oxo-4H-[1]benzopyran-3-carboxaldehyde
Synthesis of amphotericin B. 1. Fragment A of the aglycon
Heteropentalenes. The thermal addition of pyrazolo- and triazolobenzotriazoles to dimethyl acetylenedicarboxylate
Bimanes. 28. Remarks on the infrared spectrum of 9,10-dioxa-syn-(hydro,chloro)bimane [3,7-dichloro-1,5-diazabicyclo[3.3.0]octa-3,6-diene-2,8-dione]
A general, enantiospecific synthesis of cyclopentanoid monoterpenes (iridoids). The total synthesis of (-)-1-O-methylsweroside aglycon
Regiospecific synthesis of aromatic compounds via organometallic intermediates. 4. Synthesis of ortho-disubstituted benzenes
Fluorination of polycyclic aromatic hydrocarbons: charge vs. frontier orbital control in substitution reactions of radical cations
Synthesis of N-[3-(dimethylamino)-2-(substituted thio)-2-propenylidene]-N-methylmethanaminium salts via 2-(alkylthio)- and 2-(arylthio)-3-(dimethylamino)acroleins
A novel synthesis of brassinolide
Product studies of the photocycloaddition reactions of 5-chloro- and 5-fluorouracil derivatives and olefins. An interesting and useful effect of fluorine on regioselectivity
Essential oil constituents of Artemisia tridentata rothrockii. The isolation and characterization of two new irregular monoterpenes
Diastereofacial selection in nitrile oxide cycloaddition reactions. The anti-directing effect of an allylic oxygen and some new results on the ring metalation of isoxazolines. A synthesis of (.+-.)-blastmycinone
Structures of eurycomalactone and related terpenoids
One-pot synthesis of N-[(trimethylsilyl)methyl]imines and (trimethylsilyl)methyl-substituted heterocumulenes from (trimethylsilyl)methyl azide
Synthesis of 1-bromoestradiol
Reductive amination of ethyl 2-oxo-4-phenylbutanoate with L-alanyl-L-proline. Synthesis of enalapril maleate
Self-condensation of 3H-pyrrol-3-one 1-oxides
Photochemical reactions in constrained systems: changes in mode of solubilization due to long-chain hydrophobic groups
Palladium-catalyzed reactions in the synthesis of 3- and 4-substituted indoles. Approaches to ergot alkaloids
1,1-Dichloroethyl hydroperoxide and 1,1-dichloroethyl peroxide ion as intermediates in the ozonolysis of 2,3-dichloro-2-butene
Dicarboxylic acids from ozonolysis of cycloalkenes
Applications of intramolecular amidomercuration. 3. Stereoselectivity in intramolecular amidomercuration. Kinetic vs. thermodynamic control
Stereochemistry of dimeric microbial metabolites of primaquine
Pictet-Spengler reactions in aprotic media
ESR studies of nitrogen-centered free radicals. Part 21. Electron spin resonance study of N-(arylthio)alkylaminyl radicals generated by photolysis of N,N-bis(arylthio)alkylamines
Tests of a piperidino mask for the protection of functionalized carbon sites in multistep syntheses
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