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Substituent effects on excited-state efficiencies: thermolysis of 3,3-(2,2'-biphenyldiyl)-4-methyl-4-aryl-1,2-dioxetanes
A new synthetic route to tropane alkaloids based on [4 + 2] nitroso cycloaddition to 1,3-cycloheptadienes
Asymmetric synthesis of the enkephalinase inhibitor thiorphan
Kinetics and mechanism of the reactions of S-ethoxycarbonyl O-ethyl dithiocarbonate with O-ethyl xanthate and O-ethyl thiocarbonate ions
Prosthetic group radioiodination at no-carrier added levels of carbonyl-containing molecules
Oxidatively assisted nucleophilic substitution of iodine in alkyl iodides by nucleofugic anions
Synthesis of spiroimidazolidin-2-ones via intramolecular N-carbamoyliminium ion cyclization reactions
A direct synthesis of [(tert-butoxycarbonyl)methylidene]azacycloalkanes
Spontaneous hydroxylation of a cyclization intermediate of allopurinol
Aromatic fluoroalkoxylation via direct displacement of a nitro or fluoro group
The Mannich reaction. 1-Alkyl-3,3-diphenyl-4-piperidinones, 1,6'-dialkyl-3',4',5',6',7',8'-hexahydro-5,5,8',8'-tetraphenylspiro[piperidine-3,2'-[2H]pyrano[3,2-c]pyridin]-4-ones and their derivatives
Acyclic stereocontrol through the dianionic Claisen rearrangement of .beta.-hydroxy esters: synthesis of (.+-.)-botryodiplodin
A synthesis of .beta.-methylene-.gamma.-butyrolactones.
Large electron acceptors for molecular metals: 13,13,14,14-tetracyano-4,5,9,10-tetrahydro-2,7-pyrenoquinodimethane (TCNTP) anions of 13,13,14,14-tetracyano-2,7-pyrenoquinodimethane (TCNP)
Computer-assisted synthetic analysis. Selection of protective groups for multistep organic syntheses.
A simple procedure for stereospecific vicinal dicarboxylation of olefins
Enantioselective oxidation of 1,2-diols to L-.alpha.-hydroxy acids using co-immobilized alcohol and aldehyde dehydrogenases as catalysts
Lewis acid and photochemically mediated cyclization of olefinic .beta.-keto esters
A convenient preparation of cyclopentadiene from its dimer
Stereochemistry of crotylboronate additions to .alpha.,.beta.-dialkoxy aldehydes
A useful synthon approach to bicyclic enols: acid-catalyzed and base-catalyzed rearrangements of Diels-Alder adducts of 2-methoxy-5-methyl-1,4-benzoquinone
Base-catalyzed hydroperoxy keto aldehyde cyclization
Synthesis of biological markers in fossil fuels. 3. Degraded and rearranged C27 hopanes
A study of the reaction of 2-haloacyl halides with trialkyl phosphites. Synthesis of 2-substituted acyl phosphonates
A study of chemical carcinogenesis. 75. Synthesis of methylated benzo[b]fluoranthenes and benzo[k]fluoranthenes
Organoboranes in organic synthesis: reactions of homo- and heterocuprates with 9-borabicyclo[3.3.1]nonane
Micelles. Part 1. Cascade molecules: a new approach to micelles. A [27]-arborol
Lithium aluminum hydride reduction of 1-aryl-3-halopropenes, 1-aryl-3-halobutenes, and (9-anthryl)arylmethyl halides. Nucleophilic substitution vs. single electron transfer
Folate analogs. 24. Syntheses of the antitumor agents 10-deazaaminopterin (10-DAAM) and 10-ethyl-10-deazaaminopterin (10-EDAAM)
Preparation of optically active, functionalized cis-.DELTA.6-1-octalones
Zinc-modified cyanoborohydride as a selective reducing agent
Diels-Alder reaction between vinylcyclohexene and benzoquinones. A shortcoming of the FMO approach
Synthesis of adamantane derivatives. 77. Synthesis of some novel functionalized monoazatricyclic ring systems via intramolecular cycloaddition of N-(bicycloalkenyl)nitrones
Improved procedure for the tungstate-catalyzed epoxidation of .alpha.,.beta.-unsaturated acids
Heterodienophiles. 10. Stereoselectivity in the 1,4-cycloaddition of N-(ethoxycarbonyl)-C-alkylaldiminium ions with 1,3-cyclohexadiene
Regioselectivity of the intermolecular Diels-Alder reaction of acyl nitroso compounds (C-nitrosocarbonyl compounds) and nitrosoformates (O-nitrosocarbonyl compounds). Preparation of functionalized cis-.DELTA.6-1-octalones
Catalytic asymmetric synthesis of chiral 4-substituted 2-oxetanones
Stereoselective syntheses of alkenyl substituted 1,3-dioxolanes or 4,7-dihydro-1,3-dioxepins or an (E)-.alpha.,.beta.-unsaturated aldehyde from (Z)-2-butene-1,4-diols
Thermolysis of bibenzyl: roles of sulfur and hydrogen sulfide
Alcohols and aluminum alkoxides in the presence of Raney nickel as alkylating agents. 3. Reduction of Schiff bases with isopropyl alcohol and aluminum isopropoxide in the presence of Raney nickel
Preparation of .alpha.-oxo amidines by the direct nucleophilic acylation of carbodiimides
Stereoselective synthesis and solvolytic behavior of the isomeric 7-dehydrocholesterol 5,6-oxides
Reactivity in the para oxo ketene route of ester hydrolysis. The effect of internal nucleophilicity and the irrelevance of B strain
A novel approach to cardenolides
Masthead
Syntheses and inclusion behavior of 5,8,14,17,23,26,32,35-octamethoxy[3.3.3.3]paracyclophane and [3.3.3.3](2,5)-p-benzoquinonophane
Stereochemistry of phosphorus-nitrogen bond cleavage. First crystal and structural assignment in cyclic phosphoramidofluoridates
Cationic carbon-to-nitrogen rearrangements in N-(arylsulfonoxy)amines
Diels-Alder approach to bicyclic .alpha.-hydroxy ketones. Facile ketol rearrangements of strained .alpha.-hydroxy ketones
Tailor-made butadienes for the site-selective cycloaddition with quinizarinquinone and other unsymmetrically substituted quinones
An approach to the synthesis of neplanocin A
Novel Smiles-type rearrangement in thienamycin derivative
Ortho allylation of benzyl alcohols
Cyclization of 5-hexenyllithium to (cyclopentylmethyl)lithium
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