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Hydrolysis of imines. 4. Micellar effects upon the spontaneous acid, base, and copper(II) ion induced hydrolysis of N-salicylidene-2-aminothiazole and N-salicylidene-2-aminopyridine
Modification of the catalytic activity of zinc chloride. A kinetic investigation in zinc chloride-ether-dichloromethane mixtures
Gas-phase ion chemistry of azides. The generation of CH2:N- and CH2:NCH2-
Total synthesis of aromatic steroids
Electroreduction of cyclobutadienopleiadiene cathodic hydrogenation of a fused cyclobutene ring
Twin benzannulation of naphthalene via 1,3-, 1,6-, and 2,6-naphthodiyne synthetic equivalents. New syntheses of triphenylene, benz[a]anthracene, and naphthacene
An intriguing C16-alkadienone-substituted 2-pyridine from a marine mollusk
Photolysis of 1,1,4,4-tetraphenyl-3-buten-2-one: ketene formation from an acyclic .alpha.,.beta.-unsaturated ketone
Electrostatic control of regioselectivity in competing bimolecular eliminations
Metacyclophanes and related compounds. 14. Preparation of 8,16-difluoro[2.2]metacyclophane
Application of kinetic, asymmetric selection to the breaking of molecular symmetry
Masthead
Stereospecific synthesis of secondary allylic alcohols: selenoxide chemistry
Formation of cyclic ethers in the double Baeyer-Villiger oxidation of ketals derived from cyclic ketones
Methods for pyranoannulation: an approach to a new class of polyethers
Structure determination of a new cyclodepsipeptide antibiotic from fusaria fungi
Barriers to rotation of peri methyl groups in 1,8-dimethylquinolinium iodide and related compounds
Deformation density and dissociation energy of strained carbon-carbon bonds
Onium ions. 28. Methyl(4-diazoniophenyloxonium dication: a diazonium oxonium dication
Acyclic stereoselection. 30. Stereoselection in the Michael addition reaction. 2. Stereochemistry of the kinetic Michael reaction of amide enolates with enones
Adiabatic photodehydroxylation of 9-phenylxanthen-9-ol. Observation of carbocation fluorescence in neutral aqueous solution
Synthesis of .alpha.-oxo sulfines from enol silyl ethers and thionyl chloride
Stereochemistry of addition of organocopper reagents and of the hydride ion to 1-(arylsulfonyl)bicyclo[1.1.0]butanes
Facile synthesis of chiral glycine from D-ribose
Acyclic stereoselection. 31. Stereoselection in the Michael addition reaction. 3. Relationship between ester enolate geometry and adduct stereochemistry in the kinetic Michael reaction of lithium enolates with enones
Nitrogen bridgehead compounds. 48. Synthesis and stereochemistry of 4-oxo-1,6,7,8,9,9a-hexahydro-4H-pyrido[1,2-a]pyrimidine-3-carboxamides
Synthesis of N-(formylmethyl)protoporphyrin and N-(2-hydroxyethyl)protoporphyrin IX dimethyl esters
Reactions of the chlorine complex of tetrahydrothiophene
Sterols in marine invertebrates. 51. Isolation and structure elucidation of C-18 functionalized sterols from the soft coral Sinularia dissecta
Studies on amphiprotic compounds. 2. Experimental determination of the hydrogen bond acceptor basicities of monomeric alcohols
Bridgehead reactivity, nucleophilic and radical additions, and lithium aluminum hydride reduction of 1-(arylsulfonyl)bicyclobutanes: general access to substituted, functionalized cyclobutanes. Syntheses of (.+-.)-citrilol acetate, (.+-.)-junionone, and the tricyclo[3.3.0.01,4]octane and tricyclo[4.3.0.01,7]nonane ring systems
Marine natural product: spongian derivatives from the sponge Igernella notabilis
Cholest-5-ene-2.alpha.,3.alpha.,7.beta.,15.beta.,18-pentol 2,7,15,18-tetraacetate, a novel highly hydroxylated sterol from the marine hydroid Eudendrium glomeratum
N-Methylpiperidine N-oxide as a source of nonstabilized ylide: a new and efficient route to octahydroindolizine derivatives
Hydroboration. 72. Hydroboration-oxidation of 1,4-epoxy-1,4-dihydronaphthalene with and without ring opening
Light-catalyzed and silver acetate catalyzed oxidation of alcohols with N-iodosuccinimide: two different pathways
Synthesis of alkylpyrroles by the sodium borohydride reduction of acylpyrroles
Synthesis of dichlorocyclobuta[b]benzofuran-2a-carboxylic derivatives and 3-(trichlorovinyl)coumarin through the cross photocycloadduct of coumarin and tetrachloroethylene
Formal steric enthalpy
Dioxiranes: synthesis and reactions of methyldioxiranes
1,1,6,6-Tetramethyldibenzo[b,e]phosphajulolidine
Synthesis of 3-amino-4(3H)-quinazolinones from N-(2-carbomethoxyphenyl)imidate esters
The equilibrium between an areneselenenic acid and its anhydride
Concerning the mechanism of isomerization of cis-azoalkanes
The structure of tetrahydrobinor-S (pentacyclo[8.4.0.02,6.03,8.09,13]tetradecane) based on carbon-carbon connectivity two-dimensional NMR study
Additions of 1,1-diethoxyethene to 1,2-diketones
Photochemistry of meta-substituted and para-substituted aromatic polycarbonyl compounds
Photochemistry of aromatic .alpha.,.beta.-epoxy ketones. Substituent effects on oxirane ring-opening and related ylide behavior
Substituent effects and isokinetic relations in the homolysis of hyponitrite esters. The question of free-radical homoconjugation
Structure of malyngamide C
Stereochemistry of the photoinduced addition of nucleophiles to the enone of decompostin
[2,3]-Sigmatropic rearrangement of an in situ prepared ylide and a thio ether to thio ester conversion as key steps in short syntheses of sarkomycin and its phenyl thio ester
Enantioselective reduction of ketones with reagents from lithium aluminum hydride and axially chiral 2,2'-diamino-1,1'-dinaphthyls
Mechanism of fragmentation of alkylidene-Meldrum's acids. Carboxyketene, vinylketene, and methyleneketene intermediates from 5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione
A highly unusual condensation reaction between 3-chloro-3-methyl-2-butanone and lithium diisopropylamide
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