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Synthesis of functionalized hydroxyphthalides and their conversion to 3-cyano-1(3H)-isobenzofuranones. The Diels-Alder reaction of methyl 4,4-diethoxybutynoate and cyclohexadienes
Asymmetric periodate oxidation of functionalized sulfides catalyzed by bovine serum albumin
Synthetic studies toward complex diterpenoids. 16. A novel synthetic route to the carbocyclic skeleta of stemodin and stemarin by acid-catalyzed intramolecular C-alkylation and rearrangement reactions
Oxygen-17 NMR studies on 5-substituted uracils
Theoretical studies of the inductive effect. Part 5. Charged substituents in correlations of electronic substituent effects
Heterogeneous catalysis of glucose mutarotation by alumina in dimethyl sulfoxide. 2. Catalytic activity of various aluminas, effects of inhibitors, and the acid/base properties of the active sites
Neighboring group participation by a pyridine ring. 2. Effects of aromatic substituents on solvolysis of 5,8-methano-5,6,7,8-tetrahydroisoquinoline and benzonorbornene derivatives
Syntheses of (S)-(-)-3-piperidinol from L-glutamic acid and (S)-malic acid
Palladium-catalyzed polyhetero-Claisen rearrangement of 2-(allylthio)pyrimidin-4(3H)-ones
Nucleophilic additions to N-propargylpyridinium and N-allenylpyridinium salts and to 1,3-propenediylbis(pyridinium) salts
.beta.-Methylene-DL-asparagine
(-)-Methyl 4,5-O-benzylidene-4-epi-shikimate: an intermediate for the synthesis of (-)-chorismic acid and analogs
1,4-Bridged pyrazolin-5-ones from thermal ring enlargement of spiropyrazolium ylides
Masthead
C-(Methoxycarbonyl)ketene N-imidoylimine synthesis and rearrangement into methyl 4,6-diazahepta-2,4,6-trienoates. Cycloaddition reactions with isocyanides: preparation of imidazolines
Novel substituent orientation in Reimer-Tiemann reactions of pyrrole-2-carboxylates
Synthesis of 9-(4-hydroxy-2-oxobutyl)guanine, 9-(2,4-dihydroxybutyl)guanine and related acyclic nucleoside analogs
Heterocyclic ynammonium salts
Leaving group ability and pKa in elimination reactions
Diels-Alder reactions of cycloalkenones. 4. Short syntheses of some cadinenes
Pseudorotation barriers in cis-4,5-dimethyl- and cis-3,4,5,6-tetramethyl-9,10-dihydroxy-9,10-dihydrophenanthrene: measurement of the buttressing effect
Allylzinc reagents additions in aqueous media
An unusual thermal rearrangement of 5,5,6,6-tetracyano-2-thiabicyclo[2.2.0]hexane to a thiophene
Ozonolysis of styrene and p-nitrostyrene. Secondary deuterium isotope effects
The intramolecular diene-carbene cycloaddition equivalence and an enantioselective Birch reduction-alkylation by the chiral auxiliary approach. Total synthesis of (.+-.)- and (-)-longifolene
The .pi. nucleophilicity: the effect of charge delocalization on the efficiency of internal displacements in ElcB reactions
C-Alkylation and N-acylation of 4-amino-1-azabutadiene derivatives. A convenient route to monoalkylated 1,3-diketones
Bichromophoric compounds. Photophysics and photochemistry of 1-naphthylalkyl esters of fumaric, maleic, and oxalic acids
Synthesis and oxidative coupling of (.+-.)-3-oxoreticuline
A nitrile oxide based entry to 2,3-dihydropyran-4-ones. Synthesis of a protected version "compactin lactone" in racemic and optically active forms
3',4'-Diarylspiro[isobenzofuran-1(3H),5'(4'H)-isoxazol]-3-ones. Reaction of nitrile oxides with 3-benzylidenephthalides
Saudin, a hypoglycemic diterpenoid, with a novel 6,7-seco-labdane carbon skeleton, from Cluytia richardiana
1,2-Benzisoxazol-3-yl diphenyl phosphate: a new, reactive activating agent for the synthesis of amides, esters, and peptides via condensation
Formation of elusive vic-disulfoxides and OS-sulfenyl sulfinates during the m-chloroperoxybenzoic acid (MCPBA) oxidation of alkyl aryl disulfides and their regioisomeric sulfinothioic acid S-esters
Synthesis of 5-(dihydroxyboryl)-2'-deoxyuridine and related boron-containing pyrimidines
Effect of water on the extraction and reactions of fluoride anion by quaternary ammonium phase-transfer catalysts
Chlorohydroxylation of olefins with peroxides and titanium tetrachloride
Synthesis and multinuclear magnetic resonance study of para-substituted phenyl selenobenzoates
Elucidating the leaving group effect in the .beta.-lactam ring opening mechanism of cephalosporins
Synthesis of 4-substituted cycloheptatrienones by oxidative-cheletropic elimination of nitrosobenzene from 6-substituted 8-phenyl-8-azabicyclo[3.2.1]octa-3,6-dien-1-ones
Structural effects in solvolytic reactions. 48. Rates of ethanolysis of camphene hydrochloride and related .alpha.-methyl-substituted 1-chloro-1-methylcyclopentanes. Is the rate of ethanolysis of camphene hydrochloride exceptionally high?
Preparation of (3a.alpha.,6a.alpha.)-1,3-dibenzylhexahydro-1H-thieno[3,4-d]imidazol-2(3H)-one: a key biotin intermediate
Evidence for proton tunneling in the strong base catalyzed elimination reaction of .beta.-phenylethyl substrates
Synthesis with hypochlorous acid. Conversion to pulegone and isopulegol to menthofuran. Preparation of 3,6-dimethyl-2,6-cycloheptadien-1-one from phorone
Ionic reactions of the isodicyclopentadienes: roles and properties of the allylic cations
Nucleosides from carbohydrate adducts of diaminomaleonitrile. A novel synthesis of 5-amino-1-(.beta.-D-ribofuranosyl)imidazole-4-carboxamide and 5-amino-1-(.beta.-D-ribopyranosyl)imidazole-4-carboxamide
Cationic cyclocodimerization. 3. Syntheses of [3.3]paracyclo(1,4)naphthalenophane and [3.3](1,4)naphthalenophane derivatives. Stereoselectivity governed by the structures of .alpha.-naphthylmethylcarbenium ion and 1-vinylnaphthyl moiety
Preparation and thermolysis of cis- and trans-1-hydroxy-2-(2-pyridyl)cyclopentanes and cis- and trans-1-hydroxy-2-(2-pyrazyl)cyclopentanes
Conversion of .alpha.,.beta.-unsaturated esters to their .beta.,.gamma.-unsaturated isomers by photochemical deconjugation
Synthesis of 2(R),5(R)-bis(hydroxymethyl)-3(R),4(R)-dihydroxypyrrolidine. A novel glycosidase inhibitor
Regioselectivity of 1,3-dipolar cycloaddition reactions of nitrilimines with aryl vinyl sulfones
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