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Photocycloaddition reactions of 1,4-benzoxazin-2-ones and electron-poor olefins
Epoxidation of alkenes with potassium hydrogen persulfate
Imidate anions: stereochemistry, equilibrium, nitrogen inversion, and comparison with proton exchange
A simple method for the synthesis of long-chain alkyl esters of amino acids
Effect of poly(methacrylic acid) hypercoils on the neutral and acid-catalyzed hydrolysis of 1-acyl-1,2,4-triazoles in aqueous solution
Ruthenium complex catalyzed N-heterocyclization. Syntheses of N-substituted piperidines, morpholines, and piperazines from amines and 1,5-diols
A mass spectrometry study of levoglucosenone
Masthead
Facile one-step synthesis of phenyl-tert-butylnitrone (PBN) and its derivatives
Fluorine-19 nuclear magnetic resonance studies of 4-substituted bicyclo[2.2.2]oct-1-yl fluorides: resonance effects of some group 14 substituents attached to saturated carbon centers
1,3-Oxathiole-2-thiones from the reaction of carbon disulfide with zwitterionic iodonium compounds
Reaction of .beta.-nitroenamines with electrophilic reagents. Synthesis of .beta.-substituted .beta.-nitroenamines and 2-imino-5-nitro-4-thiazolines
.alpha.-Lithiation of N-alkylcarbazoles: preparation of N-(E)-styrylcarbazole
Glycosidic coupling of regiospecifically synthesized xantho[2,3-g]tetralin aglycones to afford antileukemic but redox inactive structures related to anthracyclines
Sterols in marine invertebrates. 49. Isolation and structure elucidation of eight new polyhydroxylated sterols from the soft coral Sinularia dissecta
Chemistry of proximal double bonds: reaction of 9,10-benzotricyclo[4.2.2.22,5]dodeca-3,7,9-triene with bromine
Delocalized carbanions: the facile-synthesis of disubstituted butadienes and diols
The mixed-chain alternative to the postulated .pi. and .sigma. reactivities of the succinimidyl radical: cyclopentane/cyclohexane. A critical examination of the rebuttal of the previous report
Acenaphthenedithione
Syntheses of (+)-.alpha.- and (+)-.beta.-eudesmol and their diastereomers by intramolecular nitrone-olefin cycloaddition
Metallic nickel-mediated synthesis of ketones by the reaction of benzylic, allylic, vinylic, and pentafluorophenyl halides with acid halides
Electroreductive dehalogenation of fluorobenzenes
A synthesis of ibogamine
Studies on the racemization and coupling of N.alpha.,Nim-protected histidine active esters
Conformational analysis of 1,3-dioxacycloheptanes. 5. Conformations of 4-isopropyl-3,5-dioxabicyclo[5.n.0]alkanes
The oxahydrindene component of the avermectins
Reduction of .beta.-keto sulfoxides: a highly efficient asymmetric synthesis of both enantiomers of allylic alcohols
Expedient chemical synthesis of sequence-specific 2',5'-oligonucleotides
Aromatic substitution. 52. Superacid-catalyzed carbonylation of aromatics with carbon monoxide
Pyrimidines. 54. Ring transformation of 5-(2-carbamoylvinyl)uracil derivatives to 5-carbamoylpyridin-2-ones
Thermal rearrangement of .alpha.-(aryloxy)methylacrylic acids: a facile synthesis of 3-methylcoumarins
Enantiospecific synthesis of the trans-9-[3-(3,5-dimethyl-1-piperazinyl)propyl]carbazoles
Total synthesis of ionophore antibiotic X-14547A
Monochlorination of n-alkyl phenyl ethers in micellar sodium dodecyl sulfate
Allylic carbonates. Efficient allylating agents of carbonucleophiles in palladium-catalyzed reactions under neutral conditions
Michael addition to 1,3-bis(alkoxycarbonyl)allenes: synthesis of heterocyclic compounds having glutaconate structure in the molecules
Oxidation by superoxide ion of catechols, ascorbic acid, dihydrophenazine, and reduced flavins to their respective anion radicals. A common mechanism via a combined proton-hydrogen atom transfer
Photochemistry of phthalimides with olefins. Solvent-incorporated addition vs. cycloaddition to imide C(=O)-N bond accompanying ring enlargement
A formal synthesis of (.+-.)-ibogamine
Host-guest complexation. 33. Search for new chiral hosts
Diels-Alder and retro-Diels-Alder reactions: from N'-(thioacyl)formamidines to thio amide vinylogs
Stereochemistry of the hydride reduction of 7-oxabicyclo[2.2.1]heptanes
Ozonolysis of 1-methylindenes. Solvent, temperature, and substituent electronic effects on the ozonide exo/endo ratio
Nucleophilic opening of 2,3-epoxy acids and amides mediated by titanium isopropoxide. Highly enhanced C-3 selectivity
Selective reductions. 37. Asymmetric reduction of prochiral ketones with B-(3-pinanyl)-9-borabicyclo[3.3.1]nonane
Magnetic isotope effects in photochemical reactions. Observation of carbonyl oxygen-17 hyperfine coupling to phenylacetyl and benzoyl radicals. Oxygen-17 enrichment studies
Enantioselectivity of the microsomal epoxide hydrolase-catalyzed hydrolysis of trans-4,5-dimethyl-1,2-epoxycyclohexane
Synthetic applications of 2-cyano-1,2,3,6-tetrahydropyridines. 2. Synthesis of isodasycarpidone and related systems, the ervitsine skeleton and its benzo analog
Titanium isopropoxide-mediated nucleophilic openings of 2,3-epoxy alcohols. A mild procedure for regioselective ring-opening
An unprecedented selective autoxidation of tertiary amines to amine oxides
Synthesis and structure of a new stable carbocation stabilized by two neighboring sulfur atoms. Dimethyl[9,9-bis(methylthio)-1-fluorenyl]carbenium ion
Selective addition of unsaturated carboxylic acids to terminal acetylenes catalyzed by bis(.eta.5-cyclooctadienyl)ruthenium(II)-tri-n-butylphosphine. A novel synthesis of enol esters
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