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Product study of some one-electron oxidations of bibenzyl and 4-ethylbibenzyl. Evidence against carbon-carbon bond cleavage of the bibenzyl radical cation in solution
Rate-limiting proton transfer in .sigma.-complex formation between 1,3,5-trinitrobenzene and N-methylaniline in dimethyl sulfoxide. The differing reactivities of aromatic and aliphatic amines in .sigma.-complex formation and in SNAr processes
Trapping of the 6,6-dimethylbicyclo[3.1.1]hept-2-yl free radical by H2S reaction with peracid
Diastereoselective synthesis of chiral secondary amines with two chiral centers directly attached to the nitrogen atom
Small rings. 29. Synthesis and ring expansion of vinylazetidines. A synthesis of hydroazocines
Synthesis and Diels-Alder reactions of N-carbalkoxydihydropyridines. Substituent effects on the regiochemistry of reduction of N-carbalkoxypyridinium ions
Ketovinylation of arylthallium compounds catalyzed by lithium tetrachloropalladate
Consequences of hydrophobic association in photoreactions: photodimerization of stilbenes in water
Direct addition of elemental fluorine to double bonds
A novel synthesis of 1,4-dihydrobenzo[c]-1,5-naphthyridin-2(3H)-ones from pyrrolo[1,2-b]isoquinolines
Theoretical structures for the phenyl and benzyl radicals
Lewis acid catalyzed inter- and intramolecular [2 + 2] cycloadditions of conjugated allenic esters to alkenes
Reactions of alkylidenecarbenes derived from N,N-disubstituted-2-oxopropanamides: the formation of 3-pyrrol-2-ones and 2-butynamides
The asymmetric synthesis of branched chain polyketide compounds through stereoselective aldol condensations of .beta.-heteroatom ester enolates
Molecular receptors. Synthesis and x-ray crystal structure of a calix[4] arene tetracarbonate-acetonitrile (1:1) clathrate
The origin of regioselectivity of .alpha.-cleavage reactions of cyclopropenethiones: potential role of pseudo-Jahn-Teller effect in substituted cyclopropenyl systems
Dehydrobromination of 1,2-dibromoethyoxyethane using various amine bases
Determination of enantiomeric purity of tertiary amines by proton NMR of .alpha.-methoxy-.alpha.-(trifluoromethyl)phenylacetic acid complexes
endo-Selective insertion by norcaranylidene carbenoid into the .alpha. C-H bond of alkoxides: evidence of a hydride abstraction-recombination mechanism
Single electron transfer in the Meerwein-Ponndorf-Verley reduction of benzophenone by lithium alkoxides
Alicyclic reaction mechanisms. 7. The predominance and quantification of steric effects in the solvolysis of secondary aliphatic esters
Mechanistic studies in strong acids. 11. An excess acidity analysis of acylal and thioacylal hydrolysis in sulfuric acid. Variation of .rho. with acidity
Carbonylation in strong acid. Lactones from allylic derivatives
Carbonylation of aldehydes in strong acid. A general synthesis of 3,4-dialkyl-2(5H)-furanones
Asymmetric epoxidation of allyl alcohol: efficient routes to homochiral .beta.-adrenergic blocking agents
Synthesis of .delta.-lactones via radical carbon-carbon bond formation using chiral radical precursors
Regioselective removal of allylic nitro groups via hydride transfer
Masthead
Cycloaddition of chloro-, cyano-, methoxy-, and (phenylthio)allene with 1,1-dichloro-2,2-difluoroethene (1122). Competitive cyclodimerization and trapping of the cyclodimers with 1122
Oxidation of enolates by dibenzyl peroxydicarbonate to carbonates of .alpha.-hydroxy carbonyl compounds
Nucleophilic trapping of intermediates in the singlet oxygenations of isomeric 1,4-di-t-butoxy-1,3-butadienes
Synthesis of (racemization prone) optically active thiols by SN2 substitution using cesium thiocarboxylates
Organic photochemistry. 64. Aryl-activated carbon-chlorine bond cleavage at the bridgehead positions in 1-chloro- and 1,4-dichloro-7,7-dimethoxybenzonorbornene
Ionization of 2-brexyl brosylate: an exo-like rate without symmetrical bridging
Products and mechanism of the oxidation of 9-methylanthracene by peroxydisulfate. Proton loss and nucleophile addition reactions of the 9-methylanthracene radical cation
Phase managed organic synthesis. A new synthesis of mixed formic anhydrides
Synthetic applications of the 1-cyclobutenyltriphenylphosphonium salt. Synthesis and reactions of 1,2-difunctionalized cyclobutanes
Functionalization of aromatic systems: a highly chemoselective synthesis of trimethylsilylmethylnitroarenes
Differentially protected .alpha.-aminoglycine
(Fluoren-9-ylmethoxy)carbonyl (Fmoc) amino acid chlorides. Synthesis, characterization, and application to the rapid synthesis of short peptide segments
Silylstannanes in organic synthesis. Scope and limitation of palladium-catalyzed reaction with acetylenes
Nitrogen-15 NMR spectra of tertiary amines with the 7-azanorbornene framework
Applications of the cyclopropyl iminium ion rearrangement: preparation of tetracyclic ring C functionalized intermediates related to lycorine
Directed lithiation of tertiary .beta.-amino benzamides
The use of 5-halocyclooctenes as a radical probe. Reactions with lithium aluminum hydride
Photochemical transformations. 44. Ground-state and excited-state reactions of benzotricyclo[3.2.1.02,7]octenes
Deuterium isotope effects in the intramolecular hydrogen transfer reactions of some 1-alkyl substituted cyclopropenes
High pressure [4 + 2] cycloaddition reactions of 3,4-dimethoxyfuran with dichloromaleic anhydride and with cyclopropane derivatives
Spiro asymmetric induction. Synthesis of optically pure .alpha.-hydroxy acid derivatives by alkylation of a chiral glycolate enolate
A new synthesis of lepidopterenes
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