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New imidoyl isothiocyanates. Chemical behavior in polar solvents. Reaction with sulfenyl thiocyanates: preparation of 1,2-dihydro-2-thioxo-1,3,5-triazines and 1,3,4,6,6a-triazadithia[6aS(IV)]pentalenes
Synthesis of a C-15 substituted porphyrin from a b-bilene precursor
Palladium-catalyzed propargylic vs. allylic alkylation
Ring transformations of heterocycles with nucleophilic reagents. 34. Frontier-orbital interactions in the reaction of 5-nitropyrimidine with electron-rich olefins. An example of superjacent orbital control
Thermochemistry of unstable enols: the O-(Cd)(H) group equivalent
.beta.-Deuterium secondary isotope effects in heterolytic decarboxylation reactions. Manifestations of negative hyperconjugation
Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride
A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols
Dipeptide analogs. Versatile synthesis of the hydroxyethylene isostere
Regioselective 1,4-addition to .alpha.,.beta.-unsaturated ketones with Grignard reagents mediated by (N,N,N',N'-tetramethylethylenediamine)zinc(II) chloride
The synthesis of proximal-benzoguanine and a simplified synthesis of proximal-benzohypoxanthine
A comparison of the reactions of [(phenylthio)(trimethylsilyl)methyl]lithium with .alpha.,.beta.-unsaturated ketones and those of other acyl anion equivalents containing sulfur
Improved preparation of (3.beta.,5.alpha.,14.alpha.)-3-hydroxy-14-methylcholest-7-en-15-one. Synthesis of ergostenone and 20.alpha.-(hydroxymethyl)pregnenone analogs
Masthead
Mechanisms of heterocyclic ring formations. 4. A carbon-13 NMR study of the reaction of .beta.-keto esters with hydroxylamine
Novel preparation of cyclohepta[b]pyrrol-2-ones
The synthesis and properties of two stable benzo[c]furans. An x-ray crystallographic structure determination of the geometry of 1-cyano-5,6-(methylenedioxy)benzo[c]furan
Kinetics and mechanism of the acid-catalyzed bromination of ring-substituted acetophenones in methanol. Thermodynamics of the ketone-acetal-enol ether system in methanol and water
The first two-step 1,3-dipolar cycloadditions: interception of intermediate
Chiral multifunctional isoprene units by ring contraction of riboside oxiranes
Reactions of carbenes and photoexcited ketones with phosphorus compounds
Electrochemical synthesis of organosilicon compounds
(E)- and (Z)-1-Hydroxy-1,3-butadiene: new kinetically unstable C4H6O isomers
Novel potentiators of .beta.-lactam antibiotics. Structures of SQ 28504 and SQ 28546
Polymer-supported reagents. 4. Oxidation of alcohols by complex chromates, soluble models and supported species
Convenient preparation of 5-alkyl-4-carbalkoxy-1,2,3-thiadiazoles
Nucleobase difunctionalized .beta.-cyclodextrins. Preparation and spectral observation of base stacking and the hydrogen-bonded nucleic acid base pair
Di- and trisubstituted .gamma.-lactones. Conformational study by molecular mechanics calculations and coupling constant analysis
A stereocontrolled synthesis of dl-biflora-4,10(19),15-triene
Catalysis by undissociated H3PO4 in aqueous H2PO4-/HPO4= buffer solutions: dependence on the magnitude of the Broensted exponent
Synthesis of five- and six-membered nitrogen heterocycles via palladium(II)-catalyzed cyclization of unsaturated amides
Preparation and characterization of base-sensitive destructible surfactants
New syntheses of 2-fluoroisovanillin and 5-fluorovanillin
An improved synthesis of 4-fluoroveratrole. Efficient route to 6-fluoroveratraldehyde and 6-fluoro-D,L-DOPA
Mesyl azide: a superior reagent for diazo transfer
New derivatizing agents for amino acids and peptides. 1. Facile synthesis of N-substituted 1-cyanobenz[f]isoindoles and their spectroscopic properties
Michael and anti-Michael additions to benzoyl(trifluoromethyl)acetylene
Stereochemistry of the asymmetric oxidation of ketone enolates using (camphorylsulfonyl)oxaziridines
Photochemistry of polyhaloarenes. 4. Phototransformations of perchloro-o-phenoxyphenol in basic media
Molecular mechanics calculations on the Csp3-Csp2 rotation in the N,3,3-trimethyl-2-phenyl-4-piperidone system
Iodide reduction of sulfilimines. Secondary deuterium isotope effects on sulfurane formation
Chirality transfer in stereoselective synthesis. A highly stereocontrolled synthesis of 22-hydroxylated steroid side chains via the [2,3]-Wittig rearrangement
Synthesis of allylic alcohol single-chain PGH analogs. A synthetic application of the argon laser
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