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.alpha.,.beta.-Unsaturated acyl cyanides. 6. Self-condensation and conjugate addition of allyl-, allenyl-, propargyl-, and alkynyltrimethylsilanes
Synthesis of 9-[5-(alkylthio)-5-deoxy-.beta.-D-erythro-pent-4-enofuranosyl)adenines as potential inhibitors of transmethylation
A new and efficient synthesis of guanosine
Empirical correlations in ultraviolet spectra of substituted benzenes. 1. Compounds with electron-withdrawing parent groups
Dynamic structures of zinc, magnesium and aluminum azaallylmetal reagents
Diethylaluminum chloride-amine complex mediated aminolysis of activated cyclopropanes
Unusual temperature-dependent isotope effects in the reactions of phenylcarbene with cyclohexene and cyclohexane
Micellar effects on competitive hydrolysis and hydration of vinyl phosphonium salts
Syntheses of .alpha.-phenylneopentyl chloride enantiomers: (S)-(-)-1-chloro-1-phenyl-2,2-dimethylpropane from (R)-(+)-1-phenyl-2,2-dimethyl-1-propanol via the reaction of tri-n-butylphosphine in carbon tetrachloride and (R)-(+)-1-chloro-1-phenyl-2,2-dimethylpropane from anthranilic acid
Halogenated epoxides. 9. Reaction of trans-2,3-dichlorooxirane with dimethyl sulfide
Dramatic reversal of diastereoselectivity in an N-acyliminium ion cyclization leading to hexahydropyrrolo[2,1-a]isoquinolines. A case of competing steric interactions
Ester cleavage by a phenolic quaternary phosphonium surfactant
Masthead
Proton NMR 2D conformational study of 2-selenated 3-substituted cyclohexanones. Evidence of trans diaxial conformers
Studies on the synthesis of side-chain hydroxylated metabolites of vitamin D. 2. Stereocontrolled synthesis of 25-hydroxyvitamin D2
Empirical force field calculations. 27. A study on the conformations of the simple vicinal diols
Reactions of 2-halothiazoles with ketone enolates and nitrile carbanions
NMR spectroscopy and cyclic voltammetry of N-aryl-P,P,P-triphenylphospha-.lambda.5-azenes. Substituent effects and correlation with molecular orbital calculations
Studies on the synthesis of side-chain hydroxylated metabolites of vitamin D. 3. Synthesis of 25-ketovitamin D3 and 25-hydroxyvitamin D3
Observations on the synthesis and spectroscopic characteristics of purpurins
Reaction of 16-bromo-17-oxo steroids with potassium cyanide
Use of proton spin-lattice relaxation and nuclear Overhauser effect data in structure analysis of alkaloids
Solvolysis of 1-(1-naphthyl)- and 1-(9-anthryl)-2,2,2-trifluoroethyl sulfonates
Unexpected formation of 1,4,7,9-tetrafluorodiamantane in the reaction of 1,4,9-tribromodiamantane with NO2+BF4-/pyridinium polyhydrogen fluoride (PPHF)
Preparation and reactions of tetrakis(2-formyl-2-propyl)ethylene, and acyclic derivative of tetra-tert-butylethylene
ESR studies of nitrogen-centered free radicals. 27. First electron spin resonance spectroscopic study of aliphatic RCONSR1 radicals. Oxygen-17 and sulfur-33 hyperfine splittings
Stereoselective reductions of a vinylogous urethane. Structure in a highly substituted indolo[2,3-a]quinolizidine
Three-electron-bonded sulfur-centered radical cations and possible ylide formation during the oxidation of various 1,3-dithiacylopentanes
Antineoplastic agents. 114. Synthesis of azotomycin
Benzobicyclo[4.1.0]hepta-2,4,6-trienes
Cobalt(III)-catalyzed trifluoroacetoxylation of benzene
An efficient chemomicrobiological synthesis of stable isotope-labeled L-tyrosine and L-phenylalanine
Chemical carcinogenesis. 93. Synthesis of potential phenolic metabolites of benzo[b]fluoranthene
Electrolytic reduction of tert-butyl bromide at mercury cathodes in dimethylformamide
The chemistry of N-sulfonyl enamines
Reactions of N-chlorobenzylmethylamines with secondary amines in acetonitrile. Effect of base strength upon the imine-forming transition state
Conformational analysis of sulfur-carbon-phosphorus anomeric interactions. 3. The conformational preference of the diphenylphosphinoyl group in cyclohexane
Isobenzofuran-aryne cycloadducts: formation and regioselective conversion to anthrones and substituted polycyclic aromatics
A chemoenzymatic synthesis of leukotriene B4
Selective oxidation of organoboranes with anhydrous trimethylamine N-oxide
Propionyl and n-butyryl hypobromites and hypoiodites as intermediates in the mercuric propionate and n-butyrate induced halogenation of alkylbenzenes
A convergent approach to heterocycle synthesis via silver ion mediated .alpha.-ketoimidoyl halide-arene cyclizations. An application to the synthesis of the erythrinane skeleton
Rearrangement of linalool, geraniol, nerol and their derivatives
Synthesis of enantiomerically pure 24-alkylsterol side chains, in both enantiomeric forms, starting from (R)-(+)-limonene
A novel and stereospecific synthesis of (.+-.)- and (-)-aristeromycin
Efficient conversion of (1R,5R)-(+)-.alpha.-pinene to (1S,5R)-(-)-nopinone
Vinyl isocyanates as aza diene equivalents. A method for the synthesis of functionalized 4-hydroxy-2(1H)-pyridones
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