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Chemistry of dioxiranes. 6. Electronic effects in the oxidation of sulfides and sulfoxides by dimethyldioxirane
Oxidation of silyl enol ethers using 2-sulfonyloxaziridines. Synthesis of .alpha.-siloxy epoxides and .alpha.-hydroxy carbonyl compounds
Polar effects in free-radical reactions. Solvent and isotope effects and effects of base catalysis on the regio- and chemoselectivity of the substitution of protonated heteroaromatic bases by nucleophilic carbon-centered radicals
Crystallization-induced asymmetric transformation: stereospecific synthesis of a potent peripheral CCK antagonist
Masthead
Large-scale synthesis of a cyclic hexapeptide analog of somatostatin
1-Methoxyisobenzofuran from base-induced and acid-catalyzed reactions of 1,3-dihydro-1,3-dimethoxyisobenzofuran
Synthetic methods and reactions. 128. Unusual .beta.-fluorination of secondary alkyl and cycloalkyl bromides in their reaction with NO2+ BF4- in (HF)n-pyridine solution
Carbanions: electron transfer vs. proton capture. 8. Use of sterically protected aromatic nitro compounds as base-resistant, one-electron oxidants
Effect of distortion on the hydrolytic reactivity of amides. 2. N-Pyramidalization: decomposition of N-benzoylaziridines in aqueous media
Absolute rate constants for the reaction of triethylsilyl radicals with ring-substituted benzyl chlorides
On the deuterium thermodynamic isotope effect on the equilibration of 2-cyclohexenol-.alpha.-d and -.gamma.-d
Unusual photochemistry of 4-chlorobiphenyl in water
The chemistry of sulfines. 13. 2-Thiabicyclo[2.2.1]hept-5-ene and its S-oxides and 3-alkyl derivatives: sulfine and sulfene cyclopentadiene Diels-Alder adducts. Conversion of the cyclopentadiene-sulfine adducts into 2-oxa-3-thiabicyclo[3.3.0]oct-7-enes, novel bicyclic sultenes
Reactions of (benzothiazol-2-ylthio)(trimethylsilyl)methane. A general method for .alpha.-mercaptoalkylation by alkylation and alkylative desilylation
Silafunctional compounds in organic synthesis. 33. Metalated allylaminosilane: a new, practical reagent for the stereoselective .alpha.-hydroxyallylation of aldehydes to erythro-1,2-diol skeletons
Synthesis and cation-extraction study of lithium-selective chromogenic 14-crown-4 derivatives
Reduction of carbonyl compounds with pentacoordinate hydridosilicates
Magnesium bromide-promoted addition of heterosubstituted methylketene silyl acetals to alkoxy aldehydes. Diastereoselective synthesis of 3,4-syn-2-methylene- and 2-(alkoxymethyl)-3-hydroxy-4-alkoxy esters
Synthesis of 1-fluoro-, 4-fluoro-, and 1,4-difluoro-4-demethoxydaunomycinone. Interesting D-ring analogs of adriamycin
Boron trifluoride-catalyzed cycloadditions of naturally occurring sesquiterpene p-benzoquinones
Fluorination of alkanes by chlorine trifluoride. Hydride abstraction mechanism
HZSM-5-catalyzed dihydroxybenzene equilibration
Chemical behavior of (+)-(1R,3S)-1,2,2-Trimethyl-1,3-bis(hydroxymethyl)cyclopentane upon attempted halogenation. Formation of (+)-(1S,3S)-1-bromo-3-(bromomethyl)-1,2,2-trimethylcyclohexane
Asymmetric induction in the addition reactions of chiral sulfinylallyl anions (ambident nucleophiles) with enones (ambident electrophiles). Ring closure of enol thioether ketones
Ring expansion of cyclobutanones to cyclopentanones via .alpha.-lithioalkyl aryl sulfoxides and selenoxides
Synthesis of the major metabolic dihydro diols of benzo[j]fluoranthene
Spectral properties of Rose Bengal derivatives in polar and nonpolar solvents
3-(Imidazol-1-ylmethyl)-4',4"-dimethoxytrityl: a new functionalized 5'-hydroxyl protecting group capable of rapid internucleotidic bond formation in the phosphorothio ester approach
Kinetics and mechanisms of reactions of (trialkylstannyl)lithiums with chlorides bearing activating .alpha. substituents
Synthesis of the enantiomers of endo-brevicomin
Formation of episulfonium ions from alkenes. Application to the synthesis of higher order carbocycles via episulfonium ion initiated polyene cyclizations
Effect of the leaving group in the hydrolysis of N-acylimidazoles. The hydroxide ion, water, and general-base catalyzed hydrolysis of N-acyl-4(5)-nitroimidazoles
Total synthesis of the methyl ester of the 9,11-dithia analog of 13,14-dehydro-PGH2
Preparation and assignment of configuration of cis- and trans-2,3,4,4a,5,6-hexahydro-2-naphthalenol
The reaction of metal fluorides with unsym-azetidinone disulfides and 2.beta.-(halomethyl)penams. The 3.beta.-fluoro-3.alpha.-methylcephams
A convenient, general synthesis of .alpha.-trichloromethyl carbinols
Addition compounds of alkali metal hydrides. 30. Rapid reaction of trialkylboranes with lithium aluminum hydride. A novel and quantitative synthesis of lithium dialkylborohydrides
Heteroatom-directed allylic substitution and rearrangement reactions
Regioselectivity of alkoxyisobenzofuran-aryne cycloadditions
Dichotomous regiochemistry of aldehyde and ketone in the reaction with dithio-substituted crotyllithium
An efficient synthesis of anhydroalditols and allylic-glycosides
A study and mechanistic interpretation of the electronic and steric effects that determine the stereochemical outcome of the reaction of Schiff bases with homophthalic anhydride and 3-phenylsuccinic anhydride
Palladium-catalyzed coupling of aryl halides with (trimethylstannyl)diphenylphosphine and (trimethylsilyl)diphenylphosphine
Rothemund and Adler-Longo reactions revisited: synthesis of tetraphenylporphyrins under equilibrium conditions
Reaction of thiamin analogs with sulfite ion: an example of zero-order kinetics
Pyrroles as terminators in cationic cyclizations. The preparation of 5,6,7,8-tetrahydroindolizidines and 6,7,8,9-tetrahydro-5H-pyrrolo[1,2-a]azepines
Abnormal micellar effects on reactions of azide and N-alkyl-2-bromopyridinium ions
Stereochemistry of room-temperature fluorination of alkenes with cesium fluoroxysulfate
Regioselective alkylations of 4,6-dialkyl substituted 2(H)-pyran-2-ones
Stability relationships of decalin diones. Modified MM2 force-field calculations
A novel method of functionalizing the ethyl chain of octaethylporphyrin
Photochemical reactions of aromatic compounds. 43. Direct photoamination of arenes with ammonia and primary amines in the presence of electron acceptors
Intramolecular [4 + 2]-cycloadditions of vinylnitrosonium cations with olefins
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