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Selective syntheses of mono- and bis(2-fluoro-2,2-dinitroethoxy)alkanes. Scope of the utility of triflate intermediates
Force-field modeling of the stereoselective Michael additions of an optically active amine and its lithium amide to acrylates
Stereoselectivity differences in Wittig reactions of semistabilized ylides
Synthetic studies toward gelsemine. 2. Preparation of the tetracyclic skeletal part by way of a highly stereospecific intramolecular reaction of a silyl enol ether with an N-acyliminium ion
Carbocation stabilization by the thioamide group
Synthesis and spectroscopic analysis of branched RNA fragments: messenger RNA splicing intermediates
Study of the regiochemistry and stereochemistry of the [3 + 2] cycloaddition between nonstabilized azomethine ylides generated from tertiary amine N-oxides and various dipolarophiles
Synthesis of 2-[[(p-nitrophenyl)sulfonyl]oxy] esters from ketene silyl acetals and bis[(p-nitrophenyl)sulfonyl] peroxide
Mechanistic study of the Wittig reaction of benzophenone with a nonstabilized ylide
Conversion of dehydroabietic acid into 20-keto-C-aryl-18-norsteroids. Formation of the D ring
Use of Broensted relationship to detect a mechanistic shift for reaction of 2-(methylthio)ethyl chloride with thiophenoxide anions
Robustadials. 3. Total synthesis of camphane analogs
Stereoselective generation and facile dimerization of (E)-2-methylene-3-alkenoic acid esters
Synthesis of benzhydryl 2.alpha.-(chloromethyl)-2.beta.-methyl-6,6-dihydropenam-3.alpha.-carboxylate 1,1-dioxide: the 2.alpha.-isomer of the potent .beta.-lactamase inhibitor, BL-P2013
Enolization of 2-decalones
Enzymic regioselectivity in the hydroxylation of cholesterol catalyzed by a membrane-spanning metalloporphyrin
Syntheses via vinyl sulfones. 28. Seven-ring annulation. A linch-pin approach to a tetracyclic precursor of the lathrane diterpenes
Robustadials. 2. Total synthesis of the bicyclo[3.2.0]heptane structure proposed for robustadials A and B
Photochlorination of n-alkanes adsorbed on pentasil zeolites
Photochemistry. 152. Cyclopropanols and the di-.pi.-methane rearrangement: mechanistic and exploratory organic photochemistry
Synthesis of (3S,4S)-dihydro-4-ethyl-3-hydroxy-4-methyl-2(3H)-furanone, a pantolactone homolog isolated from Marshallia tenuifolia
Applications of phase transfer catalysis. 39. Do simple optically active phase-transfer agents catalyze enantioselective ether formation?
On the isolation and characterization of methyl (trifluoromethyl) dioxirane
Reagents and synthetic methods. Part 67. Preparation of 4-unsubstituted .beta.-lactams from 4-acetoxyazetidin-2-ones. A formal approach to monobactams and nocardicins
Synthesis and absolute structure of galantinamic acid
Antioxidant activity of 1-thio-.alpha.-tocopherol and related compounds. EPR, ENDOR, and UV-visible absorption spectra of some of the derived phenoxyl radicals
A highly versatile synthesis of 2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropane-1-carboxylic acid esters
Construction of polycyclic systems by cyclocarbonylation. Part 3. A novel palladium- or platinum-catalyzed cyclocarbonylation reaction of cinnamyl compounds for synthesis of 1-naphthol derivatives
Octahydroquinoline synthesis via immonium ion based Diels-Alder chemistry. Synthesis of (-)-8a-epipumiliotoxin C
The stereospecific synthesis of (Z)- and (E)-diethyl (3,3,3-trifluoro-1-propenyl)phosphonate
Dual hydrogen bond association of (R,R)-N,N'-diisopropyltartramide with (S,S)-9,10-dimethyl-9,10-dihydrophenanathrene-9,10-diol
Rearrangement approaches to cyclic skeletons. 6. Total synthesis of (.+-.)-ptilocaulin on the basis of formal bridgehead substitution and photochemical [1,3] acyl migration of a bicyclo[3.2.2]non-6-en-2-one system
Thermolysis of nitromethane in pressurized supercritical media
Studies of the solvolysis of 2-adamantyl pentafluorobenzenesulfonate. A YPFBS scale
The photobiology of the gilvocarcins. Total synthesis of defucogilvocarcin V and a related photoactive vinyl phenol
Meerwein-Ponndorf-Verley-type reduction of dicarbonyl compounds to hydroxy carbonyl compounds and .alpha.,.beta.-unsaturated carbonyl compounds to allylic alcohols catalyzed by zirconocene and hafnocene complexes
Organosulfur chemistry. 57. Generation of diatomic sulfur from organometallic precursors
Study of the reductive cleavage of selenides with nickel boride. A convenient deselenization procedure
Synthesis of 4-azidoindole-3-acetic acid, a photoprobe causing sustained auxin activity
Highly stereocontrolled synthesis of the four individual stereoisomers of statine
The He(I) photoelectron spectra of methylenecyclopropene derivatives. Correlation with electrochemical oxidation
Structure of brassicicolin A: a novel isocyanide antibiotic from the phylloplane fungus Alternaria brassicicola
Defined dimensional alterations in enzyme substrates. Birch reduction of lin-benzopurines. A contribution to information concerning the binding sites of adenosine deaminase and xanthine oxidase
A highly stereoselective synthesis of podophyllotoxin and analogues based on an intramolecular Diels-Alder reaction
Robustadials. 4. Molecular mechanics and NMR studies of conformational and configurational equilibria: 3,4-dihydrospiro[2H-1-benzopyran-2,2'-bicyclo[2.2.1]heptanes]
An efficient, palladium-catalyzed route to protected allylic amines
Masthead
Systematic evaluation of the anomeric effect in 2-(arylseleno)-1,3-dithianes. Evidence for stabilizing orbital interactions
Reaction of dilithiated carboxylic acids with iodine: evidence for the formation of a radical anion intermediate
Preparation of 10-g quantities of 15-O-acetyl-4-deoxynivalenol
Selective deoxygenation of unsaturated carbohydrates with Pd(0)/Ph2SiH2/ZnCl2. Total synthesis of (+)-(S,S)-(6-methyltetrahydropyran-2-yl)acetic acid
Synthesis of 7,9-diphenyl-8-tropyliumyl-8H-cyclopent[a]acenaphthylene cation having an intramolecular charge-transfer interaction and its transformation into the sesquifulvalene derivative
Acyl substituent effects on ester aminolysis
Reactions of weak carbon acids under phase transfer catalysis conditions: oxidations and hydrogen-deuterium exchange
Intramolecular cyclization of allyl- and propargylsilanes. The regio- and stereochemical outcome of the cyclization
Convenient route to 1,3-disubstituted cyclobutanes. An inexpensive synthesis of 3-oxocyclobutanecarboxylic acid
Highly diastereoselective deprotonation and substitution of chiral 5,6-dihydro-4H-1,2-oxazines
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