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Fluoride ion-catalyzed reduction of aldehydes and ketones with hydrosilanes. Synthetic and mechanistic aspects and an application to the threo-directed reduction of .alpha.-substituted alkanones
A convenient synthesis of bis-homotris: 4-amino-4-[1-(3-hydroxypropyl)]-1,7-heptanediol, and 1-azoniapropellane
Validation of the proton NMR chemical shift method for determination of stereochemistry in the bistetrahydrofuranyl moiety of uvaricin-related acetogenins from Annonaceae: rolliniastatin 1 (and asimicin)
Electron-transfer reactions in pulping systems. 5. Application of an intramolecular cyclization reaction as a detector of the formation of quinonemethide radical anions
Stereoselective intramolecular haloamidation of N-protected 3-hydroxy-4-pentenylamines and 4-hydroxy-5-hexenylamines
Deoxygenation of sulfoxides promoted by electrophilic silicon reagents: preparation of aryl-substituted sulfonium salts
Strong enthalpically driven complexation of neutral benzene guests in aqueous solution
Antiinsectan aflavinine derivatives from the sclerotia of Aspergillus flavus
High pressure mediated Diels-Alder reaction of furan with dialkyl (acetoxymethylene)malonate
Intraannular functionalization of macrocyclic polyethers via organolithium intermediates
A simple way to (3aR,4S,7aS)-(Z)-ethylideneoctahydro-7a-methyl-1H-4-indenol, a synthon for total synthesis of vitamins D
Synthesis and reactions of cyanovinyl substituted benzenediazonium salts for nonlinear optics
Transition-metal-promoted reactions. 25. Regioselective silylolefination of allylic dithioacetals. Stereoselective synthesis of 1-(trimethylsilyl)butadienes
Synthesis of (.+-.)-verrucarol using a remarkably facile alumina-catalyzed intramolecular Diels-Alder reaction
Radiolysis of solutions of diphenyliodonium and triphenylsulfonium hexafluorophosphates in various solvents
Efficient preparation of some biologically active substances from natural and nonnatural aromatic compounds by m-chloroperbenzoic acid oxidation
Highly stereoselective total synthesis of .beta.-ribofuranosylmalonate
A facile total synthesis of estrogens
Lewis acid induced .alpha.-alkoxyalkylation of 1,3-dicarbonyl compounds
A novel synthesis of the monobactam antibiotic carumonam
Isolation of a 1:1 oxazole-benzyne cycloadduct. An improved method for generating benzyne and a new approach to isobenzofuran
Interaction of the carbon-germanium or carbon-tin bond with positive charge on a .beta. carbon
Direct synthesis of .beta.-ketomethylenetriphenylphosphoranes from readily available phosphonium salts
Acid-catalyzed transformations of the heliangolide 15-hydroxyacetylleptocarpin
Evidence of termolecular complex formation of tetrabromo-p-benzoquinone with certain nonaromatic donors
A study of the sodium borohydride reduction of .alpha.,.beta.-acetylenic vs. .alpha.,.beta.-olefinic nitriles
Masthead
Anhydrides as acylating agents in lipase-catalyzed stereoselective esterification of racemic alcohols
Preferred conformation of C-glycosides. 5. Experimental support for the conformational similarity between C- and O-disaccharides
Photochemical synthesis of 1-hydroxyfluorenes: a correction
Asymmetric reduction of acylstannanes. Preparation of enantiomerically enriched .alpha.-alkoxystannanes
Conformational control of regioselectivity: rearrangements of cyclopropylcarbinyl and 5-substituted pent-3-enyl radicals
2-Iminooxetane chemistry. 2. General synthesis from ketene imine-aldehyde cycloadditions
Metal-promoted cyclization. 21. Palladium-catalyzed procedures for [3 + 2] annulation via intramolecular alkenylpalladation and arylpalladation
Synthesis of 1,3,5-tri-n-alkylbenzene compounds
Hydroboration. 83. Synthesis and hydroboration of 2-ethylapopinene. Comparison of monoisopinocampheylborane and its 2-ethyl analog for the chiral hydroboration of representative alkenes
Facile diacylation of glycidyl tosylate. Chiral synthesis of symmetric-chain glycerophospholipids
Thermolysis of unsaturated dicarboxylic acids in sulfuric acid and oleum. A comparison with the CIMS fragmentation patterns
A novel application of the Friedel-Crafts reaction to the synthesis of differently substituted polynuclear compounds
General method for the synthesis of enol ethers (vinyl ethers) from acetals
Topsentin, bromotopsentin, and dihydrodeoxybromotopsentin: antiviral and antitumor bis(indolyl)imidazoles from Caribbean deep-sea sponges of the family Halichondriidae. Structural and synthetic studies
Molecular mechanics (MM2) parameters for divinyl ethers and aromatic halide derivatives
Preparation of (+)- and (-)-N,S-dimethyl-S-phenylsulfoximine via an improved resolution. Accurate determination of very high enantiomeric purities by on-column GC analysis of diastereomeric derivatives
Diels-Alder approaches to model compounds related to fredericamycin A
Ring expansions via photoinduced single electron transfer promoted opening of cyclopropyl ethers
Prostaglandin synthesis via two-component coupling. Highly efficient synthesis of chiral prostaglandin intermediates 4-alkoxy-2-alkyl-2-cyclopenten-1-one and 4-alkoxy-3-alkenyl-2-methylenecyclopentan-1-one
Lactone synthesis of .alpha.,.omega.-diols with hydrogen peroxide catalyzed by heteropoly acids combined with cetylpyridinium chloride
Reactions of azines. 13. Thermal rearrangements of 1,5,6-triaza-1,2,4,6-heptatetraenes to 4,9-dihydropyrazolo[5,1-b]quinazolines and N-.alpha.-styryl-5-(phenylamino)pyrazoles
Synthesis of 4,6-dinitroresorcinol
Structurally new macrocycles from the resorcinol-aldehyde condensation. Configurational and conformational analyses by means of dynamic NMR, NOE, and T1 experiments
Aromatic bromination using bromine fluoride with no Friedel-Crafts catalyst
Mechanism of ester formation in the photosensitized oxidation of diazomethanes. Carbonyl oxides do not isomerize to dioxiranes in solution
Erythro-directive reduction of .alpha.-substituted alkanones by means of hydrosilanes in acidic media
Photoadditions of ethers, thioethers, and amines to 9,10-dicyanoanthracene by electron transfer pathways
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