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Barriers to rotation adjacent to double bonds. 5. Remote substituent effects on the syn/skew energy difference for 1-butene
Correlation of the circular dichroic spectra of 3-arylphthalides with absolute configuration and conformation
Intermolecular Diels-Alder reactions of 3-vinylcyclohex-2-en-1-ol and a silyl ether derivative
Metal-promoted cyclization. 17. A novel bicyclization methodology via cyclialkylation of .omega.-halo-1-metallo-1-alkynes containing aluminum and zinc
Geometry of porphyrin-porphyrin interactions
Intramolecular-catalyzed hydrolysis of sulfonamides. 10. Intramolecular nucleophilic catalysis by the neighboring hydroxyl group in acid- and base-catalyzed hydrolysis of aromatic sulfonamides and sultones. Mechanism of intramolecular nucleophilic substitution at sulfonyl sulfur
Intramolecular Friedel-Crafts alkylation and chloroalkylation of 5-aryl-1,1,1-trifluoropentan-2-ones. A route to (trifluoromethyl)dihydronaphthalenes and (trifluoromethyl)tetrahydronaphthalenes
Reduction of benzophenone with metal hydrides. A kinetic isotope effect and substituent effect study
Intra- and intermolecular hetero-Diels-Alder reactions. 17. Intramolecular hetero-Diels-Alder reaction of alkylidene- and benzylidenepyrazolones and benzylideneisoxazolones. Investigations toward the conformation of the transition state
Polymer-bound ephedrine as an efficient chiral catalyst for the enantioselective addition of dialkylzincs to aldehydes
Photochemistry of .alpha.,.beta.-unsaturated thiones: cycloaddition of thiocoumarin to electron-rich and electron-deficient olefins from T1
Electroorganic chemistry. 103. Selective C-alkylation of .beta.-diketones
Synthesis of .beta.-oxopropyl esters by catalytic addition of carboxylic acids and N-protected amino acids to propargyl alcohol
Masthead
Nitrile-stabilized carbanions. Nucleophilic substitution reactions on bromopyridines
Intramolecular Diels-Alder reactions of 6-azalumazines and 6-azapterins. A facile route to 6,7-annulated 5-deazapteridines
Oxidized nakafuran-8 sesquiterpenes from the sponge Dysidea etheria. Structure, stereochemistry, and biological activity
A convenient synthesis of 3,6-disubstituted 3,6-diazabicyclo[3.2.2]nonanes and 3,6-diazabicyclo[3.2.1]octanes
Preparation of .beta.-keto sulfones from [(phenylsulfonyl)methylene]dilithium and acid chlorides
A facile synthesis of statine and analogs by reduction of .beta.-keto esters derived from Boc-protected amino acids. HPLC analyses of their enantiomeric purity
Ring-size dependent orientation in dehydration of 1-[(ethoxycarbonyl)methyl]cycloalkanols
Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate
Cross-coupling reaction of tert-alkyl halides with Grignard reagents in dichloromethane as a non-Lewis basic medium
Some new 3-substituted 3-hydroxyselenetanes and their loss of selenium
A simple, efficient, and highly selective method for the regeneration of carbonyl compounds from oximes and semicarbazones
.alpha.-Trifluoromethyl-destabilized cations. A route to 1-(trifluoromethyl)tetralins by trifluoroacetolysis of 5-aryl-1,1,1-trifluoropentan-2-ols and derivatives
Phase-transfer catalytic oxidation of terminal alkynes to keto aldehydes by dilute hydrogen peroxide
A new stereoselective approach for the total synthesis of (.+-.)-isotadeonal, (.+-.)-polygodial, (.+-.)-warburganal, and (.+-.)-muzigadial
New approach to 6-chlorosalicylates and 1-hydroxyacridones
Characterization of new mesomeric betaines arising from methylation of imidazo[2,1-c][1,2,4]triazin-4(1H)-one, pyrazolo[5,1-c][1,2,4]triazin-4(1H)-one, and 1,2,4-triazolo[5,1-c][1,2,4]triazin-4(1H)-one
Carbenes and the oxygen-hydrogen bond: benzoannelated cycloheptatrienylidenes
MNDO study of nucleophilic aromatic substitution
Thermally irreversible photochromic systems. Reversible photocyclization of diarylethene derivatives
Synthesis of semisynthetic dipeptides using N-carboxyanhydrides and chiral induction on Raney nickel. A method practical for large scale
Intramolecular cycloaddition reactions of N-acyl imines. A stereoselective approach to the N-terminal amino acid component of nikkomycin B
Photochemical, photophysical, and theoretical studies on cyclobutanethiones. .alpha.-Cleavage reactions
Total synthesis of (+)-4-oxo-5,6,9,10-tetradehydro-4,5-secofuranoeremophilane-5,1-carbolactone via novel lactone construction through allene intramolecular cycloaddition
Photochemistry of some group V onium salts. Effect of magnetic nuclei on in-cage radical coupling reactions
Quinone methide p-hydroxybenzylation of 1,3-diketones
Convenient preparation of 11H-benzo[a]fluorenone and 11H-benzo[b]fluorenone
Improved syntheses of substituted carbazoles and benzocarbazoles via lithiation of the (dialkylamino)methyl (aminal) derivatives
A short and efficient synthesis of (3S,4S)-4-[(tert-Butyloxycarbonyl)amino]-5-cyclohexyl-3-hydroxypentanoic acid ethyl ester
Umpolung of .pi.-allylpalladium intermediates. A chemoselective reductive elimination of diols
Silicon-functionalized silyl enol ethers. Part 2. Silyl enol ethers bearing stereogenic silicon atoms and chiral alkoxy groups: the effect of these groups upon the facial selectivity of the epoxidation of an enol double bond
Microcomputer and organic synthesis. 3. The MARSEIL/SOS expert system, a new graphic approach. An electronic lab note for organic synthesis
Investigation by two-dimensional NMR of the structure and stereochemistry of a methyl p-nitrocinnamate photodimer
Enhancement of the equilibrium acidities of carbon acids by polyfluoroaryl substituents
Oxidation of cyclic ketones catalyzed by polyethylene glycol and rhenium carbonyl under basic and exceptionally mild conditions
The relationship between the Broensted acidities of imides and their hydrogen-bonding acidities toward oxygen bases
Deconjugation-alkylation of ethyl 3-(trimethylstannyl)-2-alkenoates. Stereocontrolled synthesis of ethyl 2-alkylidene-3-methylenecyclobutanecarboxylates
Synthetic (S)-5-(benzoyloxy)-6-oxohexanoic acid ethyl ester and [S,S-(E)-3-(hydroxymethyl)oxiranebutanoic acid methyl ester, important synthons for leukotrienes B4 and A4, from D-arabinose
Regioselective synthesis of substituted 1-thiohex-2-enopyranosides
Separation of mass law and solvent effects in kinetics of solvolyses of p-nitrobenzoyl chloride in aqueous binary mixtures
A direct synthesis of c-glycosyl compounds
Some observations on the stereochemical and regiochemical outcome of hydrostannylation of substituted propargyl alcohols
Synthesis and evidence for the stability of a glycerophosphochloridate: rac-1-O-hexadecyl-2-O-(methylcarbamyl)-sn-glycero-3-phosphorochloridocholine
Lewis acid-mediated condensation of alkenols and aldehydes. A selective synthesis of tetrahydropyrans and oxepanes
Photo-Stevens rearrangement of 9-dimethylsulfonium fluorenylide
Probing ergot alkaloid biosynthesis: synthesis and feeding of a proposed intermediate along the biosynthetic pathway. A new amidomalonate for tryptophan elaboration
Methyl ester nonequivalence in the 1H NMR spectra of diastereomeric dipeptide esters incorporating N-terminal .alpha.-phenylglycine units
Thioanhydrides. 2. Synthesis of phthalic thiothionoanhydrides
Avermectin chemistry. 2. A secure and flawless strategy for the final synthetic stages
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