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Inert carbon free radicals. 9. The first perchlorinated triarylmethyl and fluorenyl radicals with a heteroaromatic ring, and related compounds
Synthesis of adamantane derivatives by bridgehead radical addition to electron-deficient unsaturated bonds
Kinetics of thermal interconversion between cis,cis-1,3,5-octatriene, cis,cis,cis-2,4,6-octatriene, and cis,cis,trans-2,4,6-octatriene
N-Dienyl lactams: preparation and selectivity in the Diels-Alder reaction
Synthesis of naturally occuring quinones. Part 20. Tandem Michael/Diels-Alder addition as a new strategy toward tetracyclic systems: synthesis of 11-deoxyanthracyclinones
Direct lithiation of chalcogenachromones, -flavones, and -pyranones. The interconversion and electrophilic capture of ring-opened and ring-closed anions
Alkylation of allylic derivatives. 13. Cross-coupling reactions of the isomeric 2,3,4,4a,5,6-hexahydro-2-naphthalenyl carboxylates with organocopper and Grignard reagents
Determination of oxygen-18 exchange accompanying basic hydrolysis of p-toluamide and N,N-dimethyl-p-toluamide
Oxidations of vitamin E (.alpha.-tocopherol) and its model compound. 2,2,5,7,8-Pentamethyl-6-hydroxychroman. A new dimer
Regioselective ring opening in annelated benzocyclopropenes
Barrier to internal rotation in 1,2-bis(bromochloromethyl)-3,4,5,6-tetraisopropylbenzene
Photodesulfurization of indoline-2-thiones: a facile synthesis of indoles
Trisubstituted (stannylmethyl)lithium as a methylene double anion equivalent. Reaction with esters
Ruthenium carbonyl catalyzed reductive carbonylation of aromatic nitro compounds. A selective route to carbamates
Anionic cyclizations of .alpha.-alkoxy lithiums. New, stereoselective routes to substituted tetrahydrofurans
Polarizability effects on the aqueous solution basicity of substituted pyridines
Absolute configuration of the enantiomers of 7-chloro-4-[[4-(diethylamino)-1-methylbutyl]amino]quinoline (chloroquine)
Chiral synthesis via organoboranes. 15. Selective reductions. 42. Asymmetric reduction of representative prochiral ketones with potassium 9-O-(1,2:5,6-di-O-isopropylidene-.alpha.-D-glucofuranosyl)-9-boratabicyclo[3.3.1]nonane
Oxoiminium ions for N-demethylation: 1-oxo-2,2,6,6-tetramethylpiperidinium chloride
Synthesis of bay-region diol epoxides and other derivatives of benzo[h]quinoline
High-pressure asymmetric Michael additions of thiols, nitromethane, and methyl oxoindancarboxylate to enones
Regiospecific ring-opening reactions of benzyl 3,4-anhydro-.alpha.-D-ribopyranoside with nucleophiles: a systematic study
Furan-2-carboxyaldehyde N,N-dimethylhydrazones in Diels-Alder cycloadditions
Scytonemin A, a novel calcium antagonist from a blue-green alga
Bisannelation with a benzo[1,2-c:4,5-c']difuran equivalent: a new route to linear acene derivatives
Homogeneous nucleophile exchange. 1. Simple, high-yield synthesis of some heterodihalides
Activation barrier for the .alpha.-cleavage process in thiones
Semiempirical calculations of carbenes with aromatic substituents: a comparison of theory with experiment
.alpha.-Nitro keto hydrazone and keto imine dianions. Synthetic equivalents for the nitroalkene d3 synthon
Allene epoxidation. Efficient synthesis and synthetic conversions of 1,4-dioxaspiro[2.2]pentanes
Ultrasound in organic synthesis. 13. Some fundamental aspects of the sonochemical Barbier reaction
Achiral hexaisopropylbenzene isotopomers: analogs of the achiral trihydroxyglutaric acid diastereomers
Pseudophrynamine A: an unusual prenyl pyrrolo[2,3-b]indole ester from an Australian frog, Pseudophryne coriacea (Myobatrachidae)
New access to 2-(arylazo)-, 2-(arylhydrazo)-, and 2-aminoindoles, -benzofurans, and -thianaphthenes
Palladium-catalyzed coupling of 2-bromoanilines with vinylstannanes. A regiocontrolled synthesis of substituted indoles
Stereochemistry of 1,2,3,4,5,6,7,8-octakis(dichloromethyl)anthracene
An efficient synthesis of [8-13C]adenine
New method for the introduction of a carbon-carbon triple bond at C-13 in prostaglandin synthesis. Stereocontrolled synthesis of ZK 96 480
Titanium(IV)-mediated aldol-type condensation of zinc esters and zinc ketones with carbonyl electrophiles
Synthesis of tetrahydrolipstatin and tetrahydroesterastin, compounds with a .beta.-lactone moiety. Stereoselective hydrogenation of a .beta.-keto .delta.-lactone and conversion of the .delta.-lactone into a .beta.-lactone
Diene-substituent effects on the rate of the retro-Diels-Alder reaction. Cycloreversion reactivity varying over a range of 105
Tautomerism in 2-hydroxy-5,10,15,20-tetraphenylporphyrin: an equilibrium between enol, keto, and aromatic hydroxyl tautomers
A regiocontrolled synthesis of N7- and N9-guanine nucleosides
Direct aromatic substitution by trimethylsilyl cations
Peroxidation of S-(2-methyl-2-propyl) 2-methyl-2-propanesulfinothioate
Easy approach to N-(aminoacyl)taurine derivatives
Petrosamine, a novel pigment from the marine sponge Petrosia sp
Reactions of quinuclidines and oxyanions with substituted diphenyl sulfites. Inductive effects mutually exerted between entering and leaving groups in transition states
Studies on the keto-enol equilibria of methyl 2-oxocycloalkanoates with 5-8 carbons in the ring by IR, carbon-13 NMR, and mass spectrometry
Carbonyl-to-methylene conversion: selenium-assisted reduction of aromatic ketones with carbon monoxide and water
Masthead
Lead tetraacetate mediated oxidation of the enamides derived from 1-benzyl-3,4-dihydroisoquinolines
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