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Microbial products. 9. Roxaticin, a new oxo pentaene antibiotic
An efficient synthesis of novel .alpha.-diketone and .alpha.-keto ester derivatives of N-protected amino acids and peptides
.alpha.,.beta.-Epoxy sulfoxides as useful intermediates in organic synthesis. 22. Stereospecific desulfinylation of sulfinylaziridines with alkylmetals: a novel synthesis including asymmetric synthesis of (Z)-N-arylaziridines and some mechanistic studies
Alkaline hydrolysis of 1,3-dibromo-1,1-difluoroalkanes: a two-step vinyl carboxylation
Synthesis and structure of 2.alpha.-hydroxytropan-3-one
A molecular mechanics study of amide conformations
Templates for intramolecular O,N-acyl transfer via cyclic intermediates derived from mercury derivatives of L-cysteine: progress toward a mercury-based thiol capture strategy
Masthead
Enantioselective Robinson annulation: synthesis of (+)-O-methyljoubertiamine
On the mechanism of the reduction of .alpha.-haloketones by 1,3-dimethyl-2-phenylbenzimidazoline. Reduction by a SET (single electron transfer)-hydrogen atom abstraction chain mechanism
Synthesis of the branched nine-carbon unit of the type A streptogramins and other antibiotics
Synthesis and novel properties of N-phosphoryl peptides
Stereochemistry of reduction and methylation of 5-(trimethylsilyl)adamantan-2-one and 5-(trimethylstannyl)adamantan-2-one
Secondary deuterium kinetic isotope effects in the cleavage of thiamin and N-methylthiaminium ion: first evidence to identify the rate-limiting step
A convenient synthesis of a macrocyclic dioxo pentaamine and x-ray crystal structure of its monohydrazoic acid salt
Formation and characterization of 3-O-arenediazoascorbic acids. New stable diazo ethers
Mechanism of an acid chloride-imine reaction by low-temperature FT-IR: .beta.-lactam formation occurs exclusively through a ketene intermediate
Reactions of some cyclopropanes activated by a spiro-linked fluorene. Importance of electronic matching of a reacting partner in thermal cycloaddition with TCNE and ring-opening dehydrogenation with DDQ
Diterpenes from the marine sponge Aplysilla polyrhaphis and the dorid nudibranch Chromodoris norrisi
C-nucleosides. 10. Synthesis of 1,3-dimethyl-7-(.beta.-D-ribofuranosyl)lumazine
Polar effects in the decomposition of diaroyl peroxides. Benzoyl peroxide on silica gel
Molecular clefts. 1. Synthetic methodology for the preparation of analogs of Kagan's ether
Synthesis and reactivity of benzylic epoxides derived from 1,2,3,9,10,10a-hexahydrophenanthrene. Search for a unified mechanism for the ring opening of 2-aryloxiranes
Unexpectedly facile solvolysis of 3-oxobicyclo[2.2.2]oct-1-yl triflates: through-bond interaction of the .beta.-carbonyl lone pair with the cationic p orbital
Radical addition to carbonyl carbon promoted by aqueous titanium trichloride: stereoselective synthesis of .alpha.,.beta.-dihydroxy ketones
The Wittig-Horner reaction in weakly hydrated solid/liquid media: structure and reactivity of carbanionic species formed from ethyl (diethyl phosphono)acetate by adsorption on solid inorganic bases
Surrogates for chiral aminomalondialdehyde. Synthesis of N-(9-phenylfluoren-9-yl)serinal and N-(9-phenylfluoren-9-yl)vinylglycinal
Effects of two oppositely polarizing, distant substituents on the rate and stereochemistry of solvolysis of 2-adamantyl tosylate
A versatile synthesis of 1,1-dioxo 7-substituted cephems: preparation of the human leukocyte elastase (HLE) inhibitor 1,1-dioxo-trans-7-methoxycephalosporanic acid tert-butyl ester
Acyl anion equivalents in the synthesis of 2H-pyran-2-ones: an efficient synthesis of anibine
Synthesis of highly functionalized trans-alkene isosteres of dipeptides
Characterization of a stable carboxylic acid intermediate from 1,3-dipolar cycloaddition of a munchnone with 1,2-dicyanocyclobutene
Chemistry of fruit flies. Composition of the rectal gland secretion of (male) Dacus cucumis (cucumber fly) and Dacus halfordiae. Characterization of (Z,Z)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane
Strong participation of selenium substituents in decomposition of pyrazolines formed by 1,3-dipolar cycloaddition of appropriate vinyl selenides with diazoalkanes
Studies on the reactivity of bicyclomycin with nucleophilic amino acid derivatives
Halogenated adamantanes: intermolecular interactions in the solid state. X-ray structures of difluorodiiodo-, trifluoroiodo- and tetraiodoadamantane
Enantioselective synthesis of .alpha.-amino acid derivatives via the stereoselective alkylation of a homochiral glycine enolate synthon
Functionalization of olefins by alkoximidoylnitrenes
Electron transfer processes. 48. Free-radical alkylations of enones involving proton transfers
A solvatochromic method for determining second-order polarizabilities of organic molecules
Chemistry of singlet oxygen. 53. Environmental effects on the photooxygenation of 2-methoxy-3-methyl-2-cyclopenten-1-one
Cycloaddition reactions of bisallenes. Stereochemistry of the (4 + 2) cycloaddition process
Kinetic medium effects in N-cyclohexyl-2-pyrrolidone-water mixtures. Evidence for a low critical hydrophobic interaction concentration
Synthesis of biologically active carbocyclic analogs of N-acetylmuramyl-L-alanyl-D-isoglutamine (MDP)
A formal total synthesis of (.+-.)-9-isocyanopupukeanane
Resonance and solvent effects on absorption spectra. 7. Substituent solvation effects on nitrogen-15 chemical shifts of para-substituted anilines and meta-substituted 2-nitroanilines
Aromatic substitution. 56. Observation of aluminum trichloride-catalyzed trialkylsilylation of benzene and toluene with chlorotrialkylsilanes in the presence of Huenig bases
Reactions of some cyclopropylethylenes with TCNE. A remarkable effect of spiro-activation in the cycloaddition
Synthesis of (.+-.)-marmelo oxides by a radical cyclization reaction
Resolution and determination of the absolute stereochemistry of .alpha.- and .beta.-aryl-substituted .gamma.-methylenevalerolactones, alternate substrate inhibitors for serine proteases
Host-guest properties of new water-soluble calixarenes derived from p-(chloromethyl) calixarenes
Regioselectivity in the semiconductor-mediated photooxidation of 1,4-pentanediol
Synthesis of 3-methoxyestra-1,3,5(10),6-tetraen-17-one
Unusual rearrangements in di-.pi.-methane systems: Mechanistic and exploratory organic photochemistry
Stereocontrolled functionalization of cycloheptadiene using organometallic chemistry: synthesis of the (+)-Prelog-Djerassi lactone and a tylosin subunit
Functionalization of phenyl rings by imidoyl nitrenes
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