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Cycloisomerization approach to tetrahydrofurans
Studies in biomimetic alkaloid syntheses. 17. Syntheses of iboxyphylline and related alkaloids
[3]- and [1,3]-Sigmatropic amino-Claisen rearrangements of electron-rich alkenes [1,3,1',3'-tetraallyl-2,2'-biimidazolidinylidenes]
Studies of the furan-carbonyl photocycloaddition reaction: vinylic substitution reactions
A new preparation of ethyl 3-oxo-4-pentenoate: a useful annelating reagent
Stereoselective syntheses of S-phenyl tetrahydrofuran-2-thiocarboxylate and tetrahydropyran-2-thiocarboxylate derivatives using (phenylthio)nitromethane
syn-8,16-Dimethylphenanthro[9,10:1',2'][2.2]methacyclophane-1,9-diene: the first derivative of 8,16-dimethyl[2.2]methacyclophanediene failing to undergo spontaneous valence isomerization to the dihydropyrene system
Solvolytic cyclization of 4,15-anhydroverrucarol. A facile trichothecene-10,13-cyclotrichothecene rearrangement
Chirospecific synthesis of nitrogen and side chain modified analogs of (+)-anatoxin
Oxidation of 3- or 4-substituted N,N-dimethylanilines with molecular oxygen in the presence of either ferric chloride or [Fe(salen)]OAc
A new entry into C7-oxygenated tetrahydro-1H-3-benzazepines; efficient labeling with carbon-14 in the benzo ring
Highly stereoselective radical cyclization: copper or ruthenium-catalyzed preparation of cis- and trans-.beta.,.gamma.-dialkyl .gamma.-lactams from acyclic N-allyltrichloroacetamide derivatives
The absolute configuration of jesromotetrol and other ent-rosenes
Photochemistry of stilbenes. 8. Eliminative photocyclization of o-methoxystilbenes
An efficient stereocontrolled route to both enantiomers of platelet activating factor and analogs with long-chain esters at C-2: saturated and unsaturated ether glycerolipids by opening of glycidyl arenesulfonates
Trichothecene synthesis using organoiron complexes: diastereoselective total syntheses of (.+-.)-trichodiene, (.+-.)-12,13-epoxytrichothec-9-ene, and (.+-.)-trichodermol
A novel synthesis of 4-[alkyl(aryl)sulfonyl]benzaldehydes: alkyl(aryl)sulfinate anion as a nucleophile in aromatic substitutions
Short intramolecular Diels-Alder approach to spirovetavanes. Total synthesis of dl-hinesol
Reactions of alkylthio-substituted chromium carbene complexes with alkynes: application to synthesis of visnagan
Rate constants and Arrhenius functions for hydrogen atom transfer from tert-butyl thiol to primary alkyl radicals
The triplex Diels-Alder reaction of 1,3-dienes with enol, alkene, and acetylenic dienophiles: scope and utility [Erratum to document cited in CA110(25):230861a]
Nucleophilic attack on iodonium ion intermediate. "Real" regiochemistry of the iodo azide adduct of 1-phenylcyclohexene and of its dehydrohalogenation product
Macrocycles containing tin. The preparation of macrobicyclic Lewis acidic hosts containing two tin atoms and tin-119 NMR studies of their chloride and bromide binding properties in solution
Improved preparation of .gamma.-ketocyclobutanones
Selective reductions. 45. Asymmetric reduction of prochiral ketones by iso-2-methyl-, iso-2-ethyl-, and [iso-2-[2-(benzyloxy)ethyl]apopinocampheyl]-tert-butylchloroboranes. Evidence for a major influence of the steric requirements of the 2-substituent on the efficiency of asymmetric reduction
Reaction of novel imide reducing reagents with pyrrolizidinediones
Synthesis and alkali-hydrolysis reactions of some 2,3'-(substituted imino)pyrimidine nucleosides lacking a 2'-hydroxyl group
Stereoselection in carbon monoxide trapping by the 1-methyl-3-chlorocyclopentyl cation. Absence of chlorine coordination in a .gamma.-chloroacyl cation
Syntheses of (.+-.)-alchorneine and (.+-.)-isoalchorneine
Total synthesis of marine mercaptohistidines: ovothiols A, B, and C
Conformation studies by dynamic NMR. 37. Monitoring the stereomutations of symmetric amines by a chiral auxiliary agent
Formation of cyclopentenethiones via cyclization of .beta.-thioallyl cations
Nonempirical confirmations of the absolute configuration of (+)-.alpha.-methoxy-.alpha.-(trifluoromethyl)phenylacetic acid
Effect of the side chain on the racemization of amino acids in aqueous solution
Unstable compounds. Synthesis and experimental and computational study of the chemical behavior of 9-[1-(2,4,6-cycloheptatrienyl)]-9-xanthydrol
Effects of substitution on intramolecular alkoxypalladation carbonylation reactions
Microbial transformations. 12. Regiospecific and asymmetric oxidation of the remote double bond of geraniol
Counter anion effects on complexation of cations
Stereoselective synthesis of the tricyclic skeleton of the taxane diterpenes. The first C-silylation of a ketone enolate
Aromatization of hydrocarbons by oxidative dehydrogenation catalyzed by the mixed addenda heteropoly acid H5PMo10V2O40
Palladium(II)-assisted carboacylation of enamides to produce functionalized .beta.-amino acids. Synthesis of relays to (.+-.)-thienamycin
Asymmetric synthesis of the (4aS,8aR,8S)-hydrolilolidone system. A formal total synthesis of unnatural (+)-aspidospermine
A new method for the enzymic synthesis of nucleosides using purine nucleoside phosphorylase
Stereoselective formation of tetrahydrofuran rings via intramolecular alkoxycarbonylation of hydroxyalkenes
Direct oxygenation of enolates generated by anionic oxy-Cope rearrangement. Expedient preparation of polycyclic .alpha.-hydroxy ketones
Regiospecific opening of glycidyl derivatives mediated by boron trifluoride. Asymmetric synthesis of ether-linked phospholipids
Synthesis of monotritiomethyl iodide from thioethers. Hydrogenolysis in the presence of thioethers
On the origin of diastereoselection in the cyclization of enynes on low-valent zirconium centers. Substituent and torsional effects on annulation stereochemistry
Synthetic 8-vinylbenzo[d]naphtho[1,2-b]pyran-6-one C-glycoside
Formation of acrylic acid from lactic acid in supercritical water
Molecular mechanics explorations with 1,2-dioxetanes
Electron transfer in the additions of organolithium reagents to benzophenone and benzaldehyde
Masthead
Reinvestigation of the mechanism of the acid-catalyzed epimerization of reserpine to isoreserpine
Ultrasound in organic synthesis. 18. Selective oxymercuration via sonochemically in situ generated mercury salts
New and effective routes to fluoro analogs of aliphatic and aromatic amino acids
Secondary .beta.-aminobenzamide and heteroatom directed lithiation in the synthesis of 5,6-dimethoxyanthranilamides and related compounds
Inert carbon free radicals. 10. Chlorination of perchlorotriphenylmethyl (PTM) radical. Synthesis, structure, and reactivity of perchloro(diphenylmethylene)cyclohexa-1,4-diene
Synthesis of (+)-lasalocid aldehyde
Oxidation of 4-(phenylazo)-1,2-naphthalenediol
Chiral dipole-stabilized anions: experiment and theory in nonbenzylic systems. 100% stereoselective deprotonation and two-electron versus single-electron transfer in the chemistry of lithium and copper piperidinooxazolines [Erratum to document cited in CA110(5):38353v]
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