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Vinylic organoboranes. 12. Synthesis of (Z)-1-halo-1-alkenes via hydroboration of 1-halo-1-alkynes followed by protonolysis
Stereochemistry of hydrogen loss on formation of the vinyl group in the biosynthesis of ravidomycin
Masthead
Cycloalkenone synthesis via Lewis acid-catalyzed retro Diels-Alder reactions of norbornene derivatives: synthesis of 12-oxophytodienoic acid (12-oxoPDA)
Stereoselective synthesis of exocyclic alkenes via zirconium-promoted alkyl-diene coupling
Interactive computer modeling of the octant rule: applications to the CD of floppy molecules
A practical, efficient large-scale synthesis of 1,6-anhydrohexopyranoses
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation of silyl enol ethers to enones via DDQ-substrate adducts
Discrimination between amino acid amide conformers by imprinted polymers
Total synthesis of 13-oxygenated prostanoids derived from arachidonate: an instance of extraordinary variability in the stereochemical sense of a Mukaiyama aldol reaction
Conformational analysis of some 1,4-dioxepines by molecular mechanics (MM2)
Reactivity of (3-chloro-2-methylenecycloalkyl)palladium chloride dimers: addition of stabilized carbon nucleophiles and application to cyclopentannulation and cyclohexannulation
Hydroboration. 84. Controlled and sequential hydroboration of simple representative alkenes with monoorganylboranes in tetrahydrofuran. A convenient synthesis of mixed borinic esters, R1R2BOR3, and mixed trialkylboranes, R1R2R3B. An examination of positional selectivity in the first and second states of hydroboration
Electroorganic chemistry. 118. Electroreductive intermolecular coupling of ketones with olefins
Perfluoro- and polyfluorosulfonic acids. 21. Synthesis of difluoromethyl esters using fluorosulfonyldifluoroacetic acid as a difluorocarbene precursor [Erratum to document cited in CA111(3):23174j]
Theoretical predictions of torquoselectivity in pentadienyl cation electrocyclizations
Rearrangements of cyclobutenones. Conversion of selected 4-allylcyclobutenones to bicyclo[3.2.0]heptenones
Mechanistic definition of trimethylstannylation of 1,4-dihalobicyclo[2.2.1]heptanes: bridgehead nucleophilic substitution mediated by the intermediacy of radicals, radical anions, carbanions, and [2.2.1.]propellane
Synthesis of deuterium-labeled sesquiterpene lactones isolated from Inula helenium L
Sonication-induced halogenative decarboxylation of thiohydroxamic esters
Novel synthesis of cyclohexa-2,4-dien-1-ones. Its use in a partial synthesis of the chromophore portion of phomenoic acid
Rate constants and Arrhenius functions for rearrangements of the 2,2-dimethyl-3-butenyl and (2,2-dimethylcyclopropyl)methyl radicals [Erratum to document cited in CA110(25):230883j]
Reactions of 1-(.alpha.-alkoxyalkyl)- and 1-(.alpha.-(aryloxy)alkyl)benzotriazoles with the Grignard reagents. A new and versatile method for the preparation of ethers
The configuration of trans-5-nitro-6-glyconorbornenes. Synthesis of the enantiomerically pure trans-5-nitronorbornene-6-carboxaldehydes
Stereochemical aspects of the additions of anti-selective, crotyl organometallic reagents to .alpha.-alkoxy aldehydes
Coupling reactions of O-(trimethylsilyl) glycosides and 6-O-(tert-butyldiphenylsilyl)-protected galactosides in the presence of trimethylsilyl triflate. A new method of forming .beta.-(1 .fwdarw. 6)-oligosaccharidic linkages
Addition of oxygen- and sulfur-centered radicals to [1.1.1]propellane
Additions and Corrections - Quantitative Rearrangement of Monocyclic Endoperoxides to Furans Catalyzed by Co(II).
Octamethylcalix[4]arene
Vinylic organoboranes. 14. A stereospecific synthesis of (E)-1-halo-1-alkenes from 1-alkynes
Vinylic organoboranes. 13. A convenient stereospecific synthesis of (Z)-1-halo-1-alkenes from 1-alkynes via (E)-1-alkenylborane derivatives with halogens
Diels-Alder reactions of cycloalkenones. 17. Site selectivity of Diels-Alder reactions of a bicyclic, heteroannular dienone
The chemistry of vicinal tricarbonyls. Preparation and reactions of acetylenic tricarbonyls
Efficient preparation of ketones from N-(ethoxymethylene)aniline and organometallic reagents
Optically active tetrahydro-.alpha.-phenyl-6,7-dimethoxyisoquinoline-1-methanols from (1-phenylethyl)ureas. Absolute configuration of (-)- and (+)-isomers of the erythro series [Erratum to document cited in CA111(3):23762z]
Vinylic organoboranes. 15. Mercuration of 2-alkenyl-1,3,2-benzodioxaboroles and boronic acids. A convenient stereospecific procedure for the conversion of alkynes into (E)-1-halo-1-alkenes via mercuric salts
Ambident nucleophilicity of silver hyponitrite toward organic halides [Erratum to document cited in CA110(25):231201x]
Isolation and structure of the cytostatic linear depsipeptide dolastatin 15
Quantitative predictions of tautomeric equilibria for 2-, 3-, and 4-substituted pyridines in both the gas phase and aqueous solution: combination of AM1 with reaction field theory
Trispiro[2.1.2.1.2.1]dodecane-4,8,12-trione and other oligomers of carbonylcyclopropane. The organozinc route
5,10,15,20-Tetrakis(.alpha.,.alpha.,.alpha.,.alpha.-o-(N-tert-butyl-carbamoyl)phenyl)porphyrin: synthesis and redox properties of zinc(II) and copper(II) complexes
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