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3,4-Epoxyprecocenes as models of cytotoxic epoxides: synthesis of the cis adducts occurring in the glutathione metabolic pathway
An efficient screen for determining solid-state hydrogen-bonding patterns in carboxylic acids
Synthesis and reactions of highly electrophilic imines containing the N-cyano group
The theoretical structures of neutral, anionic, and lithiated P-allylphosphonic diamide
Advantages of fluoroformates as carboalkoxylating reagents for polar reactants
On the origin of enantioselectivity in the Katsuki-Sharpless epoxidation procedure
Anomalous reaction of pentafluorophenacyl bromide with hexamethylenetetramine. Structure of the product
Stereoselective intramolecular nitrone cycloadditions promoted by an allylic stereocenter
Studies of the total synthesis of fredericamycin A. Preparation of key partial structures and development of an intermolecular alkyne-chromium carbene complex benzannulation cyclization approach to the ABCD(E) ring system
Chiral sulfur compounds. II. Diastereoselective additions of (R)-(+)-methyl p-tolyl sulfoxide anion to imines. Asymmetric synthesis of (R)-(+)-tetrahydropalmatine
Stereoselective construction of quaternary carbons by the reaction of aldehydes with allylic chromium reagents prepared from 1,3-diene monoepoxides and chromium dichloride
Palladium- and molybdenum-catalyzed hydrostannation of alkynes. A novel access to regio- and stereodefined vinylstannanes
Synthesis and coordinating properties of ligands designed for modeling of the active site zinc of liver alcohol dehydrogenase
Efficient oxidation of phenyl groups to carboxylic acids with ruthenium tetraoxide. A simple synthesis of (R)-.gamma.-caprolactone, the pheromone of Trogoderma granarium
A convenient regioselective synthesis of substituted cycloheptenones
Masthead
Regioselective hydrogenation of conjugated dienes catalyzed by hydridopentacyanocobaltate anion using .beta.-cyclodextrin as the phase transfer agent and lanthanide halides as promoters
Intermolecular couplings between vinyl triflates and allylic cuprates: a mild and rapid atypical route to 1,4-dienes
Palladium-catalyzed [2,3] rearrangement of alkyl allyl sulfites to alkyl allylsulfonates
A simple conversion of 1-chloroethyl carbonates to fluoroformates: value in the preparation of tertiary alkyl fluoroformates
The chemistry of vicinal tricarbonyls. New routes to indolizidines
Oxidative cyclization of acyclic aryl-substituted N-vinylurethanes
Amine-induced reactions of diacyl peroxides
A concise total synthesis of enantiomerically pure (+)-cis- and (+)-trans-lauthisan
The chemistry of 2'-amino analogs of 2'-hydroxychalcone and its derivatives
A route to linear, bridged, or spiro polycyclic compounds: sequential use of the intermolecular Diels-Alder reaction and radical cyclization
Organoboranes. 53. A high-field variable-temperature proton and boron-11 NMR study of the effects of solvent and structure on reactivity in allylboration
Metabolites of the sponge Strongylophora durissima from Maricaban Island, Philippines
An improved synthesis of the taxol side chain and of RP 56976
Synthetic methods and reactions. 146. Olefins from crowded carbonyl compounds with tert-butyllithium (tert-butylmagnesium chloride)/thionyl chloride. Study of carbocationic reaction intermediates and rearrangement-cleavage under stable ion conditions using carbon-13 NMR spectroscopy
Transition metal promoted reactions. 28. Tungsten hexacarbonyl mediated desulfurdimerization of dithioacetals. Evidence for a thione intermediate
Synthesis of longitudinally twisted polycyclic aromatic hydrocarbons via a highly substituted aryne
1-Hydroxy-3-amino-2-piperidone (.delta.-N-hydroxycycloornithine) derivatives: key intermediates for the synthesis of hydroxamate-based siderophores
An improved method for the synthesis of .alpha.-diazo ketones
Studies on the synthesis of the antitumor agents esperamicin A1/calicheamicin .gamma.1. Stereospecific synthesis of the 12.beta.-hydroxybicyclo[7.3.1]diynene core structure via a dicobalt hexacarbonyl-acetylene-mediated synclinal aldol reaction
Tungstate-catalyzed oxidation of tetrahydroquinolines with hydrogen peroxide: A novel method for the synthesis of cyclic hydroxamic acids
Rearrangement of isoxazoline-5-spiro derivatives. 5. Diastereofacial selectivity in the cycloaddition of substituted five-membered cyclic nitrones and methylenecyclopropanes. Stereoselective synthesis of 3,5-substituted indolizidinones
Sterically crowded alkenes. Synthesis of 4-(di-tert-butylmethylene)tetramethyldihydro-2(3H)-furanone and furanols by ring expansion of 3-(di-tert-butylmethylene)tetramethylcyclobutanone
Two imidazole alkaloids from a sponge
Convenient syntheses of cytidine 5'-triphosphate, guanosine 5'-triphosphate, and uridine 5'-triphosphate and their use in the preparation of UDP-glucose, UDP-glucuronic acid, and GDP-mannose
Stereochemical course of the transannular cyclization, in chloroform, of epoxycembranoids derived from the geometrical isomers of (14S)-14-hydroxy-1,3,7,11-cembratetraenes
Tungstate-catalyzed oxidation of secondary amines to nitrones. .alpha.-Substitution of secondary amines via nitrones
Reactions of 1-nitro-2-(trialkylsilyl)acetylenes
Tantalum-alkyne complexes as synthetic intermediates. Stereoselective preparation of trisubstituted allylic alcohols from acetylenes and aldehydes
2-Amino-5-imino-4,5-dihydrothiazoles: synthesis by reaction of isocyanides with 2-amino-3-aza-1-thiabutadienes and base-induced rearrangement to imidazolines or diazolidines
Aromatic nucleophilic substitution. 27. Aromatic nucleophilic substitution reactions of 1-(alkylamino)-2,4-dinitronaphthalenes with various primary amines in dimethyl sulfoxide
The stereoselective osmylation of 1,1-disubstituted olefins. Effect of allylic substituents on reaction diastereoselectivity
Lipase-catalyzed resolution of acyclic amino alcohol precursors
Reaction of cyclic aminals with isocyanates
Transition metal promoted reactions. 29. (Z)-2,2'-Disubstituted bifluorenylidenes by intramolecular desulfurdimerization reactions
Oxidation of olefins by palladium(II). 12. Product distributions and kinetics of the oxidation of 3-buten-2-ol and 2-buten-1-ol by tetrachloropalladate (PdCl42-) in aqueous solution
Preparation of epoxides by oxidative decarboxylation of .beta.-hydroxy acids. Stereo- and regiochemistry of oxidative elimination of secondary radicals with cupric acetate
Photolysis of vinyl halides. Reaction of photogenerated vinyl cations with cyanate and thiocyanate ions
Sodium dichloroisocyanurate oxidation of a sterically hindered tetrahydro-9(10H)-acridinone
Energetic and rate effects of the trifluoromethyl group at C-2 and C-4 on the aliphatic Claisen rearrangement
Electrolytic transformation of fluoroorganic compounds. 5. Anodic cyanation of 2,2,2-trifluoroethylamines
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