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An unusual .gamma.-silyl effect in titanium tetrachloride catalyzed arylation of 1,4-benzoquinones
ESR studies of nitrogen-centered free radicals. 40. Exceptionally persistent nitrogen-centered free radicals. Preparation, isolation, and molecular structure of N-(arylthio)-2,4,6-triphenylanilino radicals
Experimental and calculated activation parameters for ring opening of the 1-bicyclo[1.1.1]pentyl radical: the effect of bridgehead substituents [Erratum to document cited in CA115(9):91450d]
Stereoselective opening of chiral dioxane acetals. Nucleophile dependence
The furan approach to oxygenated natural products. Total synthesis of (+)-KDO
Electrochemistry of anilines. 6. Reactions of electrogenerated biphenylylnitrenium ions [Erratum to document cited in CA115(5):49019v]
Cyclodextrin-induced conformational enantiomerism of dinaphthylmethanes
Round-trip radical probes: ring cleavage of the bicyclo[1.1.1]pentylcarbinyl radical
Isodicyclopentadienes and related molecules. 53. Unsymmetrical oxidative cleavage of cyclic ketones. Conversion to .omega.-ethoxycarbonyl aldoximes under alkaline conditions [Erratum to document cited in CA114(9):81071w]
Palladium-catalyzed polycyclization of dienynes: surprisingly facile formation of tetracyclic systems containing a three-membered ring
Adaptation of oxyanionic sigmatropy to the convergent enantioselective synthesis of ambergris-type odorants
Total synthesis of (-)-colletol
Mechanistic study of a synthetically useful monooxygenase model using the hypersensitive probe trans-2-phenyl-1-vinylcyclopropane
Regioselectivity in the acid-catalyzed isomerization of 2-substituted 1,4-dihydro-1,4-epoxynaphthalenes
Correlations between the solvent hydrogen-bond-donating parameter .alpha. and the calculated molecular surface electrostatic potential
A one-pot synthesis of sulfenamides
A new three-carbon homologating agent for synthesis of .gamma.-keto aldehydes
New agents for the selective reduction of the carbon-carbon double bond of .alpha.,.beta.-unsaturated carbonyl compounds
Ozonolysis of vinyl ethers in the presence of .alpha.-diketones and .alpha.-keto esters
An organic tridentate ligand stabilizing a 10-I-4 iodinane oxide and related species
Palladium-catalyzed carbonylative cyclization of o-allylbenzyl halides to produce benzo-annulated enol lactones and/or bicyclo[3.3.0]hept-3-en-6-ones. An efficient route to U-68,215
Preparation of N-substituted phthalimides by the palladium-catalyzed carbonylation and coupling of o-dihalo aromatics and primary amines
Studies of N-terminal templates for .alpha.-helix formation. Synthesis and conformational analysis of (2S,5S,8S,11S)-1-acetyl-1,4-diaza-3-keto-5-carboxy-10-thiatricyclo[2.8.1.04,8]tridecane (Ac-Hel1-OH)
Stereochemistry in nucleophilic vinylic substitution of activated nitro olefins. 2
1,2,3-Benzoxathiazole 2,2-dioxides: synthesis, mechanism of hydrolysis, and reactions with nucleophiles
An efficient synthesis of 2-vinylbenzimidazoles from 1-(2-(benzimidazol-2-ylethyl)pyridinium salts using an anion-exchange resin
Transformation of neoclerodane diterpenoids into 19-norneoclerodane derivatives
Studies of N-terminal templates for .alpha.-helix formation. Synthesis and conformational analysis of peptide conjugates of (2S,5S,8S,11S)-1-acetyl-1,4-diaza-3-keto-5-carboxy-10-thiatricyclo[2.8.1.04,8]tridecane (Ac-Hel1-OH)
Synthetic methods. 31. .alpha.-Substituted cyclobutanones as protecting groups for carboxylic acids [Erratum to document cited in CA111(21):194163j]
Stereoselective addition reactions of chiral .alpha.-sulfinyl ketimine anions with ene esters. Facile asymmetric synthesis of indolo[2,3-a]quinolizidine and yohimbanoid alkaloids [Erratum to document cited in CA112(1):7775w]
Stereochemistry of metalated aldimines. 1. An ab initio study of the potential energy surfaces of isolated acetaldimine anions, their monomeric lithium and sodium ion pairs, and mechanistic consequences
Stereospecific methylation of .gamma.,.delta.-epoxy acrylates by trimethylaluminum: a method for the iterative construction of polypropionate chains
Horsfiline, an oxindole alkaloid from Horsfieldia superba
Base-induced and -directed elimination and rearrangement of perhydronaphthalene-1,4-diol monosulfonate esters. Total synthesis of (.+-.)-alloaromadendrane-4.beta.,10.alpha.-diol and (.+-.)-alloaromadendrane-4.alpha.,10.alpha.-diol
A new procedure for the conversion of thiols into reactive sulfenylating agents
Evidence for ketene intermediates in the reactions of 2-oxobutanedioic acid diesters with alcohols and water [Erratum to document cited in CA112(25):234775q]
Enantiomeric synthesis of (+)-BCH-189 [(+)-(2S,5R)-1-[2-(hydroxymethyl)-1,3-oxathiolan-5-yl]cytosine] from D-mannose and its anti-HIV activity
Studies on nitrogen metabolism using carbon-13 NMR spectroscopy. 6. Biosynthesis of sarubicin A. Synthesis and incorporation of 6-hydroxy[13CO15NH2]anthranilamide
Palladium-catalyzed coupling of 2-bromonaphthoquinones with stannanes: a concise synthesis of antibiotics WS 5995 A and C and related compounds
Transmetalation reactions of alkylzirconocenes: copper-catalyzed conjugate addition to enones
Studies directed at the synthesis of optically active pretazettine via intramolecular nitrone/alkene cycloaddition reactions
Masthead
Probing a molecular model of taste utilizing peptidomimetic stereoisomers of 2-aminocyclopentanecarboxylic acid methyl ester
Cyclopenta[cd] pyrene and monomethyl isomers
Bioactive bromopyrrole metabolites from the Caribbean sponge Agelas conifera [Erratum to document cited in CA114(19):182417u]
Conformational study of (R)-(-)-2,2,2-trifluoro-1-(9-anthryl)ethanol (Pirkle's alcohol) by dynamic NMR
Benzoin enediol dianion and hydroxide ion in DMSO: a single electron transfer reduction system driven by the irreversible benzilic acid rearrangement
Cytotoxic five-membered cyclic peroxides from a Plakortis sponge
Total synthesis of 6-deoxy-6-aminoheptopyranuronic acid derivatives
Models for the use of .alpha.-amino acids as chiral auxiliaries in asymmetric Diels-Alder reactions
An efficient synthesis of hydroxyethylene dipeptide isosteres: the core unit of potent HIV-1 protease inhibitors
Synthetic studies on the macrodiolide elaiophylin
Reaction of enol silyl ethers and enol acetates with copper(II) nitrate-iodine: synthesis of .alpha.-iodo ketones
Accurate determination of small splitting constants for organic radicals by NMR
Stereospecific nucleophilic addition reactions to olefins. Addition of thiols to .alpha.,.beta.-unsaturated carboxylic acid derivatives
Stereochemistry of metalated aldimines. 2. A theoretical study of dimeric ion-pair aggregates of isomeric lithioacetaldimines and of their kinetically controlled reaction with formaldehyde
Direct cleavage of peptides from a solid support into aqueous buffer. Application in simultaneous multiple peptide synthesis
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