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Zinc-promoted reactions. 2. Ionic and nonionic pathways in the reduction of acetophenone and 2,2-dimethyl-1-phenylpropan-1-one
Nucleic acid-related compounds. 68. Fluorination at C5' of nucleoside 5'-thioethers with DAST/antimony(III) chloride or xenon difluoride to give 5'-S-aryl-5'-fluoro-5'-thiouridines
Peroxidation of saccharide phenylhydrazones: novel hydrazono-1,4-lactones
Copper-catalyzed aziridination of olefins by (N-(p-toluenesulfonyl)imino)phenyliodinane
Total synthesis of (.+-.)-clavukerin A: a new trinorguaiane sesquiterpene. Biomimetic synthesis of (.+-.)-clavularin A from (.+-.)-clavukerin A
Solid-state, and solution photochemistry of a 1-aza diene
Singlet oxygen mediated oxidative decarboxylation of pyrrole-2-carboxylic acids
Bimolecular cyclization of 2-fluoro-N-(hydroxyalkyl)benzamides. 2. Synthesis and structural characterization of 17- and 20-membered macrocycles
Novel azido-phenylselenenylation of double bonds. Evidence for a free-radical process
Reaction of the trimethyl ester of coenzyme PQQ(PQQTME) and amines in organic media. Products and mechanism
Synthesis of a conformationally restricted DNA hairpin
The gymnochromes: novel marine brominated phenanthroperylenequinone pigments from the stalked crinoid Gymnocrinus richeri
Formation and structure of a spiro dimer from methyl 2,3-bis(chloromethyl)thiophene-5-carboxylate by treatment with sodium iodide in DMF solution
The negative rate constants of Breslow and Huang [Erratum to document cited in CA115(19):208451y]
An improved synthesis of chiral oxazolidine-2-selones: highly sensitive selenium-77 NMR reagents for the detection and quantitation of chirality
Selective ortho lithiation of (2,5-dimethoxyphenyl)diphenylphosphine oxide and trapping of the resulting aryllithium with electrophiles
Substituted (carbazol-9-yl)(benzotriazol-1-yl)methanes: novel acyl anion equivalents
Synthesis of benzopyran derivatives. XVIII. gem-Difluorination vs. 1,3-dithiolane-dihydro-1,4-dithiin rearrangement. The role of benzylic carbons
Nitrogen-sulfur cleavage is faster than homolytic ring opening in single-electron transfer to some N-sulfonylaziridines. Competition between SN2 and SET
Relative bond dissociation energies for some NADH model compounds from hydride transfer/electron transfer equilibria in acetonitrile
Comparative structural studies of [3.1.0]-fused 2',3'-modified .beta.-D-nucleosides by x-ray crystallography, NMR spectroscopy, and molecular mechanics calculations
Intermediates in the Paal-Knorr synthesis of pyrroles
Tandem inter [4+2]/intra [3+2] cycloadditions. 3. The stereochemical influence of the Lewis acid
Addition of semidione radicals to arenediazonium ions: synthesis of 1,1-diacyl-2-arylhydrazines
Titration of organolithiums and Grignards with 1-pyreneacetic acid
Functional group hybrids. Reactivity of .alpha.'-nucleofuge .alpha.,.beta.-unsaturated ketones. 2. Reactions with malonate anion. Concerning the mechanism of the Favorskii rearrangement
Synthesis of the helicopodands: novel shapes for chiral clefts
Reaction of organic anions. 166. Sigmatropic rearrangements of ammonium benzylides: new preparative and mechanistic aspects
Direct, highly efficient synthesis from (S)-(+)-phenylglycine of the taxol and taxotere side chains
.beta.-Secondary deuterium kinetic isotope effect for the insertion of dichlorocarbene into a carbon-hydrogen bond
Syntheses of systems containing strained double bonds: cycloaddition reactions of trans-3,8-dicarbomethoxydihydroheptalene
New synthesis of 2-azetines and 1-azabutadienes and the use of the latter in Diels-Alder reactions: total synthesis of (.+-.)-.delta.-coniceine
Synthesis of racemic and optically active .DELTA.9-tetrahydrocannabinol (THC) metabolites
Synthesis of supertriptycene and two related iptycenes
Masthead
2-Aza 1,3-dienes: a new and simple method for the synthesis of functionalized pyridine derivatives
Two-step affinity chromatography. Model systems and an example using biotin-avidin binding and a fluoridolyzable linker
High-pressure induced 1,3-dipolar cycloadditions of azides with electron-deficient olefins
Enantioselective autoinduction in the asymmetric hydrocyanation of 3-phenoxybenzaldehyde catalyzed by cyclo[(R)-phenylalanyl-(R)-histidyl]
Stereoselective Z- and E-bromoenol lactonization of alkynoic acids
Asymmetric synthesis of benzoquinolizidines: a formal synthesis of (-)-emetine
Synthesis and reactions of 3-hydroxy-2-nosyloxy esters produced by the stereoselective reduction of 2-nosyloxy-3-keto esters
Total synthesis of griseolic acid derivatives from D-glucose
A novel method for the synthesis of bicyclo[4.2.1]nonanes by acid-catalyzed rearrangement of 6-substituted bicyclo[4.2.0]octanones
Functional group hybrids. Reactivity of .alpha.'-nucleofuge .alpha.,.beta.-unsaturated ketones. 1. Reactions with organocopper reagents
A new asymmetric synthesis of cyanohydrins and oxygen-functionalized derivatives: stereoselective addition of cyanide to chiral rhenium aldehyde and ketone complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(O:CRR')]+BF4-
Diethyl 2,4-dioxoimidazolidine-5-phosphonates: Horner-Wadsworth-Emmons reagents for the mild and efficient preparation of C-5 unsaturated hydantoin derivatives
Selenols catalyze the interchange reactions of dithiols and disulfides in water
Synthesis of [4-(2-guanin-8-ylethyl)benzoyl]glutamic acid, a guanine analog of DDATHF
Electrolytic reactions of fluoro organic compounds. 9. Fluoride ion promoted anodic substitutions of chalcogeno compounds. 1. Regioselective anodic alkoxylation of sulfides
Protonation and sulfinylation of isomeric isopropylpyrenes, 2,7-di-tert-butylpyrene, and tetracyclohexyl- and tetracyclopentylpyrenes: remarkably stable, sterically crowded pyrenium cations
Chemistry of cage-shaped polyquinane derivatives. The reaction of 14-iodohexacyclo[6.6.02,6.03,13.04,11.05,9]tetradecan-10-one in basic solution
Synthesis of three helically chiral iptycenes
Stereospecific photodimerization of coumarins in crystalline inclusion complexes. Molecular and crystal structure of 1:2 complex of (S,S)-(-)-1,6-bis(o-chlorophenyl)-1,6-diphenyl-hexa-2,4-diyne-1,6-diol and coumarin
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