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Construction of trifluoromethylated quaternary carbons via Diels-Alder reactions of 2-(trifluoromethyl)propenoic acid derivatives: application to the synthesis of 16,16,16-trifluororetinal
Reactions of the serotonergic neurotoxin 5, 6-dihydroxytryptamine with glutathione
Synthesis and reactivity of stable silyl-substituted nitrilimines
Oxygen-17 NMR spectroscopy: evaluation of intra- and intermolecular hydrogen bonding of phenols to carbonyl groups
Remote aromatic metalation. An anionic Friedel-Crafts equivalent for the regioselective synthesis of condensed fluorenones from biaryl and m-teraryl 2-amides
Intramolecular Diels-Alder reactions of 1,2,4-triazines. Synthesis of 2,3-cyclopentenopyridines and 5,6,7,8-tetrahydroquinolines
Addition of twisted 1-thioacyl-2,2-diaminoethylenes to dimethyl acetylenedicarboxylate. Formation and ring opening of thiopyran-4-spiro-2'-(1',3'-diazacyclanes)
Amination of olefinic compounds with bis(2,2,2-trichloroethyl) azodicarboxylate
2,2-Bis(trifluoromethyl)ethylene-1,1-dicarbonitrile as a unique enophile
Syntheses and NMR spectra of substituted 2-tert-butyladamantan-2-ols
Transacetoacetylation with tert-butyl acetoacetate: synthetic applications
Rearrangement of 1,3-diradicals. Arylcyclopropane photochemistry
Further studies on the photoisomerization and hydrolysis of chlorobiphenyls in water. Common-ion effect in the photohydrolysis of 4-chlorobiphenyl
.alpha.-Oximino amide trianions in the stereoselective synthesis of isoxazolines and .gamma.-hydroxy .alpha.-amino acids
Organometallic reactions of .omega.-heterosubstituted N-acyl lactams. A new route to .gamma.-keto aldehydes from 5-ethoxy-2-pyrrolidinone
A general synthetic route to isobenzofurans bearing a functionalized C-1 substituent
Palladium(II) acetate-tert-alkyl isocyanide as a highly efficient catalyst for the inter- and intramolecular bis-silylation of carbon-carbon triple bonds
A novel synthesis of furans by base-catalyzed isomerization of alkynyloxiranes
Methoxymetacyclophanes from 2,6-dimethylanisole
Enantioselective synthesis of both enantiomers of phosphinothricin via asymmetric hydrogenation of .alpha.-acylamido acrylates
Cyano phosphate: an efficient intermediate for the chemoselective conversion of carbonyl compounds to nitriles
Solvent and substituent effects on the reaction of phenylchlorocarbene with pyridine
Conformational studies by dynamic NMR. 39. Clefts in simple acyclic organic molecules. Correlated stereodynamics of N-tert-alkylbenzylamines studied by dynamic NMR spectroscopy, x-ray diffraction, and molecular mechanics calculations
Novel photoreactions of benzhydrylidenequadricyclane and quadricyclanone: a new route to trimethylenemethane and oxyallyl derivatives
Mechanism of phosphodiester cleavage with .beta.-cyclodextrin
Pteridines. 54. A novel synthetic approach to C-6 carbon substituted pterins via intermolecular 1,3-dipolar cycloaddition reactions
Masthead
Solvolysis rates and .beta.-deuterium secondary kinetic isotope effects of some tertiary and secondary alk-5-enyl derivatives. Evidence for .pi.-participation
Observation of .alpha.-silyl carbanions in the metalation of 3,4,6-tri-O-(tert-butyldimethylsilyl)-D-glucal
Analogs of the cyclic hydroxamic acid 2,4-dihydroxy-7-methoxy-2H-1,4-benzoxazin-3-one (DIMBOA): decomposition to benzoxazolinones and reaction with .beta.-mercaptoethanol
Synthesis and molecular structure of two new crystalline 6,8-dioxabicyclo[3.2.1]octanes
Diels-Alder reactions of 1,2-(1,1'-binaphthalene-2,2'-diyldisulfonyl)ethylene with symmetrical and unsymmetrical dienes
Stereoselective synthesis of terminal 1,3-butadienes by the condensation reaction of aldehydes and ketones with .gamma.-trimethylsilyl-substituted allylboranes
An investigation of the palladium-catalyzed, formate-mediated hydroxycarbonylation of optically active 1-arylethyl esters
Carbon-centered optically active organosilanes. A rational approach to an efficient silylated chiral auxiliary
Conformational studies by dynamic NMR. 40. Conformational atropoisomerism in highly hindered naphthylamines
An enantioselective synthesis of SK&F 93505, a key intermediate for preparing cardiotonic agents
Reactions of substituted 2-tert-butyladamantan-2-ols
Conformationally restricted leukotriene antagonists. Synthesis of chiral 4-hydroxy-4-alkylcyclohexanecarboxylic acids as leukotriene D4 analogs
A rapid and efficient synthesis of chiral 2-hydro-2-oxazolines
The electron-deficient olefin 2,2-bis(trifluoromethyl)ethylene-1,1-dicarbonitrile: hydride abstractions from allyl and isobutenyl ethers and thioethers
Synthesis of the angular anthraquinone subunit of dynemicin A
Intramolecular Ullmann condensation reaction: an effective approach to macrocyclic diaryl ethers
An improved scale of solvent nucleophilicity based on the solvolysis of the S-methyldibenzothiophenium ion
A simple approach for the evaluation of local aromaticities
Stereocontrolled reductive deoxygenation using low-valent titanium: effects of ultrasound waves and solvents
Preferred conformation about the C5-C6 bond of N-acetylneuraminyl(2-6)-D-galacto- and -D-glucopyranosides in solution
Cembrane and pseudopterane diterpenoids of the octocoral Pseudopterogorgia acerosa
Model studies directed toward the molybdenum cofactor: 2-alkylidene- and 2-(phenylimino)-1,3-dithioles from acetylenes
Wagner-Meerwein rearrangements of longipinane derivatives
A convenient synthesis of 1,4-dihydro-2,3-benzoxathiin 3-oxide, a useful precursor of o-quinodimethane
Enyne[3]cumulene. Synthesis and mode of aromatization
Alkyl substituent effects on the neutral hydrolysis of 1-acyl-(3-substituted)-1,2,4-triazoles in highly aqueous reaction media. The importance of solvation
A reinvestigation of the reactions occurring upon photoexcitation of cyclohexenone in the presence of triethylamine
Reaction of simple arenes with FSO3H.cntdot.SbF5/SO2: one-pot synthesis of aromatic sulfoxides. Mechanistic aspects and synthetic utility
Lewis acid catalyzed Diels-Alder reactions of 3-methyl-1-(triisopropylsiloxy)-1,3-cyclohexadiene: factors influencing the stereoselectivity
Amplification of enantioselectivity in biocatalyzed kinetic resolution of racemic alcohols
Efficient and practical asymmetric synthesis of the taxol C-13 side chain, N-benzoyl-(2R,3S)-3-phenylisoserine, and its analogs via chiral 3-hydroxy-4-aryl-.beta.-lactams through chiral ester enolate-imine cyclocondensation
Oxidative fragmentation of catharanthine by dichlorodicyanoquinone
Comparison of the photochemistry of diarylchloronium, diarylbromonium, and diaryliodonium salts
A convenient method for the synthesis of 3.beta.-hydroxy 4-en-6-one steroids
Synthesis of nucleoside 5'-O-(1,3-dithiotriphosphates) and 5'-O-(1,1-dithiotriphosphates)
Construction of polycyclic compounds by cyclocarbonylation. 6. Palladium-catalyzed cyclocarbonylation of 3-(heteroaryl)allyl acetates
Preparation of 3-amino-4-(hydroxymethyl)azetidin-2-ones from the reaction of glycine enolates with imines of a glycoaldehyde
Stereochemical investigations: reduction of syn-8-chloro- and cleavage of anti-8-tert-butoxy-endo-3,3-diphenyltricyclo[3.2.1.02,4]oct-6-enes
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