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Asymmetric additions to chiral naphthyloxazolines. An entry into tetracyclic terpene ring systems related to aphidicolin, scopadulcic acid, and kauranes
Formation of polysubstituted 1,2,5,6-tetrahydropyridines from the 4+2 cycloaddition reaction of bis(phenylsulfonyl)butadienes with aryl imines
On the remarkable propensity for carbon-carbon bond cleavage reactions in the C(8)-C(10) region of FK-506
Magnetic circular dichroism of metallotexaphyrins
Synthetic methods and reactions. 157. Reductive alkylation and reduction of tertiary, secondary, and benzylic alcohols with trimethyl-(triethyl-, and triisopropyl)boron/trifluoromethanesulfonic (triflic) acid
Homolytic acylation of protonated pyridines and pyrazines with .alpha.-keto acids: the problem of monoacylation
Metal-halogen exchange reactions of 1,5-diiodonaphthalene. Synthesis of 1,5-disubstituted naphthalene derivatives
A novel concept for regiochemical and stereochemical control in Lewis acid promoted [3 + 4] annulation reactions
Synthesis of 1,4-keto esters and 1,4-diketones via palladium-catalyzed acylation of siloxycyclopropanes. Synthetic and mechanistic studies
Stereospecific reduction and cross-coupling of .gamma.-monosubstituted allylic chlorides using coordinatively unsaturated palladium catalysts
Reaction of epoxides with metaphosphoric acid derivatives
Total syntheses of tubotaiwine and 19,20-dihydro-20-epi-akuammicine
Heats of reaction of resonance-stabilized carbenium ions with nitrogen bases
Stereochemistry of alkylation of .alpha.-lithio piperidines: differing effects of formamidine and urethane activating groups
N-phenyl-P,P,P-triarylphospha-.lambda.5-azenes, triarylphosphines, and triarylphosphine oxides. Substituent effects on nitrogen-15, phosphorus-31, and carbon-13 NMR spectra
Tandem radical cyclization of acyclic homoallylic xanthates: cyclopentannulated .gamma.-thionolactone and .gamma.-lactones
Selective transformations of threo-2,3-dihydroxy esters
Nucleophilic substitution at nitrogen and carboxyl carbon of N-aryl-O-pivaloylhydroxylamines in aqueous solution: competition with SN1 solvolysis of model carcinogens
Masthead
Synthetic approaches to 3'-azido-3'-deoxythymidine and other modified nucleosides
Synthesis of proline-valine pseudodipeptide enol lactones, serine protease inhibitors
A rule to predict which enantiomer of a secondary alcohol reacts faster in reactions catalyzed by cholesterol esterase, lipase from Pseudomonas cepacia, and lipase from Candida rugosa
Perimeter model and magnetic circular dichroism of porphyrin analogs
Zwitterionic quaternary ammonium alkoxides: organic strong bases
Reaction of perfluoroalkanesulfinates with allyl and propargyl halides. A convenient synthesis of 3-(perfluoroalkyl)prop-1-enes and 3-(perfluoroalkyl)allenes
Preparation of anthraquinones from 10-hydroxy-9-anthracenecarbonitriles obtained from a novel aryne annulation reaction
Carbon-nitrogen bond rotational barriers in ferrocenecarboxamides
Chemical synthesis of stereospecifically labeled pyridoxamine 5'-phosphate
tert-Butyloxycarbonyl and benzyloxycarbonyl amino acid fluorides. New, stable rapid-acting acylating agents for peptide synthesis
Preparation and structural properties of large-cavity peraza macrocycles containing pyridine, phenanthroline, or piperazine subcyclic units
Electrochemical oxidation of proline derivatives: total syntheses of bulgecinine and bulgecin C
Synthesis and conformation of dithia[3]metacyclo[3]thiophenophanes and [2]metacyclo[2]thiophenophanes
Metabolic transformation of the phytoalexin brassinin by the "blackleg" fungus
The synthesis of 2,3,3a,4,5,7a-hexahydro-1H-inden-1-ols by intramolecular Diels-Alder reactions of 1,3,8-nonatrien-5-ols. Dependence of product stereochemistry on the substitution pattern
Formation and electrophilic reactions of benzeneselenenyl p-toluenesulfonate. Preparation and properties of addition products with acetylenes
Reductive decyanization of .alpha.-amino nitriles by borane
Regioselective, palladium-catalyzed hetero- and carboannulation of 1,2-dienes using functionally substituted aryl halides
[(9-Fluorenylmethyl)oxy]carbonyl (Fmoc) amino acid chlorides in solid-phase peptide synthesis
Nature of the reactions involving 4-haloisoquinolines and amide ion in ammonia. Remarkable competition between SRN1 substitution and .sigma. complex formation
Revised structure of bryostatin 3 and isolation of the bryostatin 3 26-ketone from Bugula neritina
Prostaglandin 1,15-lactones of the F series from the nudibranch mollusk Tethys fimbria
A tabtoxinine-related metabolite from Pseudomonas syringae pv. tabaci
Stereoselective syntheses of substituted .gamma.-lactams from 3-alkenamides
The stereochemical requirement in the fragmentation of 9-bromocamphor derivatives. A new class of chiral pool elements containing asymmetric quaternary carbon centers
Regiospecific and highly stereoselective electrophilic addition to furanoid glycals: synthesis of phosphonate nucleotide analogs with potent activity against HIV
Direct prediction of linear free energy substituent effects from 3D structures using comparative molecular field analysis. 1. Electronic effects of substituted benzoic acids
Use of N,N'-dimethoxy-N,N'-dimethylurea as a carbonyl dication equivalent in organometallic addition reactions. Synthesis of unsymmetrical ketones
A relationship between experimentally determined pKas and molecular surface ionization energies for some azines and azoles
Stereocontrolled epoxidations of cycloheptene derivatives in the palladium-catalyzed route to tropane alkaloids. Total syntheses of scopine and pseudoscopine
Structural requirements for glyme catalysis in butylaminolysis of aryl acetates in chlorobenzene. Identification of -OCH2CH2OCH2CH2OCH2CH2O- as the optimal subunit for catalysis
A systematic study of benzyl cation initiated cyclization reactions
The reaction of alkynes and formic acid
1,2,3-Triazoles from (Z)-.beta.-(formyloxy)vinyl azides and triethyl phosphite
Photochemistry of large-ring 2-phenylcycloalkanones in various environments. Intramolecular para-coupling products of acyl benzyl biradicals
Direct conversion of N-alkoxy .beta.-lactams to carbapenams: application to the synthesis of the bicyclic PS-5 keto ester
Synthesis of .beta.-resorcylic macrolides via organopalladium chemistry. Application to the total synthesis of (S)-zearalenone
Synthesis of (.+-.)-aspidospermidine
Effects of temperature on atom transfer cyclization reactions of allylic .alpha.-iodo esters and amides
Highly diastereoselective Michael addition of lithiated camphor imines of glycine esters to .alpha.,.beta.-unsaturated esters. Synthesis of optically pure 5-oxo-2,4-pyrrolidinedicarboxylates of unnatural stereochemistry
An efficient synthesis of 2-methyl-5,6,7,8-tetrahydro-4H-furo[2,3-d]azepines
Multiple rearrangements of 1-methoxyfluorenylidene to 1-phenanthrenol
A Friedel-Crafts cyclization approach toward cephalotaxine
Selective reduction of disulfides by tris(2-carboxyethyl)phosphine
Absolute configuration of hydroazulenoid diterpenes based on circular dichroism
Synthesis and properties of new .PI.-donor sulfur heterocycles
Regioselective synthesis of alkylpyrazines
Structure determination of natural epoxycyclopentanes by x-ray crystallography and NMR spectroscopy
Stereocontrolled oxazolidinone formation by the addition of 4,5-disubstituted iminodioxolane to oxirane via a spiro compound
Cyclialkylation studies. 1. A practical synthetic approach to the 2,3:6,7-dibenzobicyclo[3.2.2]nona-2,6-diene system
Unexpected behavior of limonene in the oxidative aminomercuration reaction with HgO/HBF4 and aromatic amines: stereospecific synthesis of 1,2-diamines
Synthesis of N-(tert-butyloxycarbonyl)-CBI, CBI, CBI-CDPI1, and CBI-CDPI2: enhanced functional analogs of CC-1065 incorporating the 1,2,9,9a-tetrahydrocyclopropa[c]benz[e]indol-4-one (CBI) left-hand subunit [Erratum to document cited in CA113(23):211667n]
Total syntheses of yohimbe alkaloids, with stereoselection for the normal, allo, and 3-epiallo series, based on annelations of 4-methoxy-1,2-dihydropyridones
Cycloadditions. 46. Thermally induced intramolecular oxime olefin cycloadditions leading to N-bridgehead systems. Stereochemistry and molecular mechanics calculations
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