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Prismene: a theoretically predicted target for experimental studies
Remote asymmetric induction based on carbonyl-ene reactions with bishomoallylic silyl ethers: dramatic changeover of regioselectivity by the remarkable siloxy effect
Copper-catalyzed redox deacylation of isomeric N- and O-benzoylhydroxylamines
Cytotoxic polyketides from Annona densicoma (annonaceae): 10,13-trans-13,14-erythro-densicomacin, 10,13-trans-13,14-threo-densicomacin, and 8-hydroxyannonacin
An improved method for the preparation of pyrrolidines by the cycloaddition of nonstabilized 2-azaallyl anions with alkenes
Protected .beta.- and .gamma.-aspartic and -glutamic acid fluorides
Synthesis of carbon-linked glycopeptides as stable glycopeptide models
Reaction of azoalkanes with isolable cation radical salts
Synthesis of hypusine and other polyamines using dibenzyltriazones for amino protection
Enantiospecific synthesis of a chrysanthemic acid precursor
Diastereoselective synthesis of anti and syn .alpha.,.beta.-dihydroxy thioesters by titanium enolate aldol condensation
Prediction of ring conformations of indolactams. Crystal and solution structures
Synthesis of diribonucleoside phosphorothioates via stereospecific sulfuration of H-phosphonate diesters
Nucleophilic substitution in 1-substituted 3-iodobicyclo[1.1.1]pentanes. A new synthetic route to functionalized bicyclo[1.1.1]pentane derivatives
Facilitated intramolecular conjugate addition of N-(p-methoxyphenyl)-3-(3',6'-dioxo-2',4'-dimethylcyclohexa-1',4'-dienyl)-3,3-dimethylpropionamide. 1. Product characterization
Synthesis of (optically active) sulfur-containing trifunctional amino acids by radical addition to (optically active) unsaturated amino acids
The synthesis of phosphonate esters; an extension of the Mitsunobu reaction
Origin of the unusual infrared absorption band at .apprx.1600 cm-1 in 1,4-dioxaspiro[2.2]pentanes
Synthesis and complexation properties of new unsymmetrical cryptands
Diastereoselectivity in the lateral metalation and electrophilic quenching of isoxazolyloxazolines
Syntheses of all four stereoisomers which are conformationally constrained 1,4-dioxanyl analogs of the antineoplastic ether lipid ET-18-OCH3
Novel .pi.-extended thiophene-fused electron acceptors for organic metals
C5H9O2+ ions: the correlation between their thermochemistry in acidic solution and their chemistry in the gas phase
Stereoselective photocyclization of some phenolic, highly congested benzophenones and benzaldehydes. Use of cis-2-arylbenzocyclobutenol methyl ethers for the synthesis of lignans
Electron demand in the transition state of the cyclopropylidene to allene ring opening
A novel method for stereospecific generation of either C-20 epimer in steroid side chains by palladium-catalyzed hydrogenolysis of C-20 allylic carbonates
Masthead
Intramolecular photoreaction of synthetic oligopeptide-linked anthraquinone molecules
An asymmetric route to enantiomerically pure 1,2,3-trisubstituted cyclopropanes
Synthesis of N-thietan-3-yl-.alpha.-oxo nitrogen heterocycles from iminothioethers. A novel transformation
Five-membered ring annulation via propargyl- and allylsilanes
Influence of microwaves on the rate of esterification of 2,4,6-trimethylbenzoic acid with 2-propanol
Synthesis of CBI-PDE-I-dimer, the benzannelated analog of CC-1065
Bis-heteroannulation. 16. A synthetic approach to geigerin
Osmium-mediated asymmetric synthesis of glycosyl-myo-inositols from oxanorbornanes
Tin(II) amides: new reagents for the conversion of esters to amides
Attempts to trap radicals formed in solution by a magnesium surface
The use of 2-oxazolidinones as latent aziridine equivalents. 2. Aminoethylation of aromatic amines, phenols, and thiophenols
Preparation of piperidinylpyridines via selective reduction of bipyridines with nickel-aluminum alloy
Intramolecularity and the function of the side arm base of simple models of transaminases
A cyclic sulfate route to methylenecyclopropanes
A convenient method for the direct incorporation of 5-fluoro-2'-deoxycytidine into oligodeoxynucleotides
Chiral organosilicon compounds in asymmetric synthesis of chiral 1,3-diols
Chemoselective ring construction from unsymmetrical 1,6-dienes via radical addition of sulfonyl halides
The photochemical reaction between aromatic nitriles and allylsilane
11-Hydroxystaurosporine: a highly cytotoxic, powerful protein kinase C inhibitor from a tunicate
Photoinduced electron-transfer reactions of 1-substituted 2,3-diphenylaziridines with 9,10-dicyanoanthracene and chloranil
A non-photochemical approach for synthesizing functionalized pentacyclo[5.4.0.02,6.03,10.05,9]undecanes using samarium (II) iodide
Evidence for a hydrogen atom transfer mechanism or a fast proton/electron transfer mechanism for monoamine oxidase
Enantioselective metal carbene transformations with polyethylene-bound soluble recoverable dirhodium(II) 2-pyrrolidone-5(S)-carboxylates
Selective hydrosilylation of alkenes catalyzed by an organoyttrium complex
Simultaneous determination of conformation and configuration using distance geometry
A polymer-supported chiral auxiliary applied to the iodolactonization reaction: preparation of .gamma.-butyrolactones
Asymmetric synthesis of (S)-4-aminohex-5-enoic acid: a potent inhibitor of 4-aminobutyrate-2-oxoglutarate aminotransferase
Secondary amine/nitric oxide complex ions, R2N[N(O)NO]-. O-Functionalization chemistry
A new approach to kainoids through tandem Michael reaction methodology: application to the enantioselective synthesis of (+)- and (-)-.alpha.-allokainic acid and to the formal synthesis of (-)-.alpha.-kainic acid
Asymmetric epoxidation of allylic alcohols catalyzed by titanium alkoxide-peptide and -.alpha.-amino acid complexes anchored by phenolic Schiff base.
Synthesis of N-Boc-protected 1-amino-3-alken-2-ols from allylic carbamates via palladium(II)-catalyzed oxidative cyclization
Stereoselective formation of E- or Z-exocyclic alkenes via radical cyclization reactions of acetylenic esters
Synthesis of ketone and alcohol derivatives of methylene-bridged polyarenes, potentially new classes of active metabolites of carcinogenic hydrocarbons
Palladium-catalyzed coupling of aryl arenesulfonates with organostannanes
Medium-sized cyclophanes. 16. Bromination of 8,16-dihydroxy[2.2]metacyclophanes
The kinetic acidity of 1,1,1-triphenylethane
Organoboranes for synthesis. 14. Convenient procedures for the direct oxidation of organoboranes from terminal alkenes to carboxylic acids
Photochemistry of matrix-isolated (.alpha.-diazobenzyl)phosphonate. Observation and reactions of phosphonylphenylcarbene, phosphonyl phenyl ketone oxide, and phenylphosphonyldioxirane
2-Arylbenzoxazole formation through o-fluoro displacement reactions
Anodic amide oxidations: the synthesis of two spirocyclic L-pyroglutamide building blocks
Highly regioselective bromination of 2,3-dimethylanisole with N-bromosuccinimide
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