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Dimethyldioxirane oxidation of primary amines
Directed ortho lithiation of phenylcarbamic acid 1,1-dimethylethyl ester (N-BOC-aniline). Revision and improvements
Antibody catalysis in low water content media
Facile generation and trapping of .alpha.-oxo-o-quinodimethanes: synthesis of 3-aryl-3,4-dihydroisocoumarins and protoberberines
Homolytic substitution reactions of electron-rich pentatomic heteroaromatics by electrophilic carbon-centered radicals. Synthesis of .alpha.-heteroarylacetic acids
Novel [3+2] and [3+3] 4-quinolone annulations by tandem Claisen-Cope amidoalkylation reaction
Transaminative desilylation of (aminomethyl)trimethylsilane and transitory inactivation of plasma amine oxidase
Single-component organic conductors based on neutral radicals containing the pyrazino-TCNQ skeleton
Synthesis of (.+-.)-.gamma.-lycorane by the intramolecular cycloaddition of an azide with an .omega.-chloroalkene
Preparation of (p-phenylene)bis(aryliodonium) ditriflates and their double substitution by some nucleophiles
Spontaneous homopolymerization competes with Diels-Alder cycloaddition of 1-aryl-1,3-butadienes to dienophiles containing a leaving group
Nucleophilic cleavage of 4,5-dihydro-3H-dinaphth[2,1-c:1',2'-e]azepinium quaternary salts. A convenient approach to new axially dissymmetric and axially asymmetric ligands
Reductive cyclization of quinone methides
Reactivity and synthetic applications of bis(iminophosphoranes). One-pot preparation of pyrido[2,3,4-de]quinazolines and benzo[de][1,6]naphthyridines
Asymmetric synthesis of alkane- and arenesulfinates of diacetone-D-glucose (DAG): an improved and general route to both enantiomerically pure sulfoxides
The Pauson-Khand reaction in triquinane synthesis: approaches to pentalenene, pentalenic acid, and silphinene
6-O-(Pentafluorophenyl)-2'-deoxyguanosine: a versatile synthon for nucleoside and oligonucleotide synthesis
Rearrangements of 1,6,7-trisubstituted 2-methyl-1,2,3,4-tetrahydroisoquinolinium 2-methylides
Novel cryptand chromoionophores for determination of lithium ions
Diels-Alder reactions of aza- and phospha-1,3-butadienes with ethylene. An ab initio study
Regioselectivity in the reaction of tantalum-unsymmetrical acetylene complexes with carbonyl compounds. Stereoselective preparation of 1-alkenyl sulfides, .alpha.,.beta.-unsaturated esters, and amides
Solution conformation of two C2-symmetric amino derivatives of 1,1'-binaphthalene by circular dichroism and liquid crystal technique
Structure-activity relationships of illudins: analogs with improved therapeutic index.
Divergent reaction pathways between rhodium(II)-stabilized vinylcarbenoids and benzenes
Synthesis of gram quantities of C60 by plasma discharge in a modified round-bottomed flask. Key parameters for yield optimization and purification
Palladium-catalyzed, carbonylative, intramolecular coupling of hydroxyvinyl triflates. Synthesis of substituted .alpha.,.beta.-butenolides
Buffer catalysis of the trifluoroethanolysis of phenoxydimethylphenylsilane
Six-membered cyclic .beta.-keto esters by tandem conjugate addition-Dieckmann condensation reactions
Synthesis of 7-azaindole and 7-azaoxindole derivatives through a palladium-catalyzed cross-coupling reaction
Masthead
[abc]-Annelated [18]annulenes
Synthesis of carbocyclic analogs of guanosine 5'-(.beta.-L-fucopyranosyl diphosphate) (GDP-fucose) as potential inhibitors of fucosyltransferases.
A Novel Darzens type reaction promoted by tributylstannylcarbamate
Bipyridyl amino acid-metal complexes and their characterization by electrospray mass spectrometry
An improved procedure for the synthesis and use of [RuCl2(BINAP)]2.cntdot.NEt3. Dependence of the ruthenium(II)-BINAP catalyzed asymmetric hydrogenation of .beta.-keto esters on trace amounts of acid
Spongian pentacyclic diterpenes. Stereoselective synthesis of (-)-dendrillol-1
Nucleophilic reactions of molybdate
Synthesis of the hydroxyethylene isostere of Leu-Val
Ionic photodissociation of polyenes via a highly polarized singlet excited state
Cycloaddition reactions of isoquinoline-pyrroline-2,3-dione and .beta.-carboline-pyrroline-2,3-dione with benzyne. Total synthesis of 8-oxypseudopalmatine and decarbomethoxydihydrogambirtannine
Preparation and reactivity of the adducts of ketene alkylsilyl acetals with ethyl propiolate in the presence of titanium tetrachloride
Synthesis of optically active arylglycines by photolysis of optically active (.beta.-hydroxyamino) carbene-chromium(0) complexes
Anti-tumor agents. 136. Cumingianosides A-F, potent antileukemic new triterpene glucosides, and cumindysosides A and B, trisnor- and tetranortriterpene glucosides with a 14,18-cycloapoeuphane-type skeleton from Dysoxylum cumingianum
Synthesis of novel carbo- and heteropolycycles. 22. Novel synthetic route to benzopolyazamacrocycles. Synthesis of 16-membered tetrabenzotetraazamacrocycles via bisquinazolinone annelation and reductive ring enlargement
New crystalline hosts based on tartaric acid. Synthesis, inclusion properties, and x-ray structural characterization of interaction modes with alcohol guests
Reactivity of allylic dimetallic zinc reagents. 1
Deactivation reaction in the hydroxylation of benzene with Fenton's reagent
Kinetically controlled peptide bond formation in anhydrous alcohol catalyzed by the industrial protease alcalase
Molecular recognition through C-H.cntdot..cntdot..cntdot.O hydrogen bonding in charge-transfer crystals: highly selective complexation of 2,4,7-trinitrofluorenone with 2,6-dimethylnaphthalene
A peptide-aluminum complex as a novel chiral Lewis acid. Asymmetric addition of cyanotrimethylsilane to aldehydes
Synthesis of thiiranecarboxylic esters from cysteine and cystine esters
Economical and convenient synthesis of p-ethynylbenzoic acid and p-ethynylbenzoyl chloride
Tributylstannane-mediated cyclization of thionocarboxylic acid derivatives
Polyazapolycyclics by condensation of aldehydes with amines. 3. Formation of 2,4,6,8-tetrabenzyl-2,4,6,8-tetraazabicyclo[3.3.0]octanes from formaldehyde, glyoxal, and benzylamines
Synthesis of racemic .alpha.-amino carboxamides via Lewis acid-mediated reactions of .alpha.-methoxyglycinamide derivatives with allylsilanes: enzymic resolution to optically active .alpha.-amino acids
A novel bioactive sesterterpene based on an unprecedented tricyclic skeleton from the caribbean sponge Cacospongia cf. linteiformis
Medium-sized cyclophanes. 24. Bromination of 8-substituted [2.2]metaparacyclophanes
.alpha.-Selective coupling reactions of allylic alcohols with aldehydes using trimethylsilyl chloride/sodium iodide/water-tin
Double group-transfer reactions: a theoretical (AM1) approach
Asymmetric Diels-Alder reactions of (S)-2-(p-tolylsulfinyl)-1,4-naphthoquinones
A potentially general regiospecific synthesis of substituted quinones from dimethyl squarate
Stachybotrins A and B: novel bioactive metabolites from a brackish water isolate of the fungus Stachybotrys sp
Solution structure and conformational equilibria of a symmetrical calix[6]arene. Complete sequential and cyclostereospecific assignment of the low-temperature NMR spectra of a cycloasymmetric molecule
First asymmetric synthesis of the Troger's base unit on a chiral template
Metalation-alkylation of O-trimethylsilyl formyltrimethylsilane cyanohydrin in the synthesis of oxazoles
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