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A route to several stereoisomers of castanospermine
Nucleophilic substitution on the ultimate hepatacarcinogen N-(sulfonatooxy)-2-(acetylamino)fluorene by aromatic amines
Dicyclopenta[ef,kl]heptalene (azupyrene) chemistry. Electrophilic monosubstitution: acetylation, halogenation, and thiocyanation. 1-(Ethoxymethyl)azupyrene and dimethyl (1-azupyrenylmethyl)malonate. Acetylazupyrene geometry. [Erratum to document cited in CA107(17):154056n]
Tandem photocyclization-intramolecular addition reactions of aryl vinyl sulfides. Observation of a novel [2 + 2] cycloaddition-allylic sulfide rearrangement
Alkyldiazonium ion pairs and deamination. 46. N-nitrososulfamates: sources of carbonium ions in aqueous media and substrates in solid-state decompositions
Toward the development of radiolabeled fluorophenyl azide-based photolabeling reagents: synthesis and photolysis of iodinated 4-azidoperfluorobenzoates and 4-azido-3,5,6-trifluorobenzoates
Reactivity of (3-chloro-2-methylenecycloalkyl)palladium chloride dimers: a palladium-mediated ring homologation - functionalization approach to 4-aryltropones related to colchicine
Electrophilic trifluoroacetylation of dicyclopenta[ef,kl]heptalene (azupyrene). [Erratum to document cited in CA92(17):146483f]
Synthesis of allylazo compounds by reactions of aryldiazonium salts with allylsilanes
A new route to the synthesis of amino acids through the mercury cyclization of chiral amidals
A nitrone-based approach to the enantioselective total synthesis of (-)-anisomycin
The thermal isomerization of [2a,11-13C2]dicyclopenta[ef,kl]heptalene (azupyrene) to pyrene. [Erratum to document cited in CA114(5):41792a]
Reactivity of nitrile oxides toward the 5,6-double bond of uracil derivatives: synthesis of some 5-aroylpyrimidine nucleoside oximes
Biosynthesis of purpactin A
Nucleophilic addition of 2'-deoxynucleosides to the o-quinone methides 10-(acetyloxy)- and 10-methoxy-3,4-dihydro-9(2H)-anthracenone
Biosynthetic origin of the oxygen atoms of aquayamycin: aspects for the biosynthesis of the urdamycin family and for aquayamycin-containing angucycline antibiotics in general
Masthead
Stereospecific thermal rearrangement of the four labile isomers of retinal. Activation parameters and FT-IR data
Regioselective epoxidation of allylic alcohols with monoperoxyphthalic acid in water
Pyranose .alpha.-enones provided ready access to functionalized trans-decalins via bis-annulated pyranosides obtained by intramolecular Diels-Alder reactions. A key intermediate for forskolin.
Synthesis and taste properties of L-aspartyl-methylated 1-aminocyclopropanecarboxylic acid methyl esters
Stereospecific enammonium-iminium rearrangements in a benzo[a]quinolizidine system
Diterpenoids from the gorgonian Solenopodium stechei
Synthesis of enantioenriched homopropargylic alcohols through diastereoselective SE' additions of chiral allenylstannanes to aldehydes
Microbiological transformations. 22. Microbiologically mediated Baeyer-Villiger reactions: a unique route to several bicyclic .gamma.-lactones in high enantiomeric purity
Synthesis of mutidentate imidazole-containing macrocycles
Substituent effects on sulfur-33 chemical shifts and nuclear quadrupole coupling constants in 4-substituted benzene sulfonates
5,6,11,12-Tetrahydrochrysenes: synthesis of rigid stilbene systems designed to be fluorescent ligands for the estrogen receptor
A strategy for the convergent synthesis of gilvocarcins via chromium carbene benzannulation. 1-O-Methyldefucogilvocarcin V in seven steps. [Erratum to document cited in CA114(9):82308r]
Stable carbocations. 283. Carbon-13 NMR spectroscopic investigation of tertiary spiro[cyclopropane-3'-norbornan]-2'-yl cations and their rearrangements
A new reagent for the determination of the optical purity of primary, secondary, and tertiary chiral alcohols and of thiols
(R)-1-Acetyl-5-isopropoxy-3-pyrrolin-2-one: a versatile chiral dienophile from (S)-malic acid
A formal total synthesis of (+)-macbecin I
Fluorinated tertiary alcohols and alkoxides from nucleophilic trifluoromethylation of carbonyl compounds
Tunable regioselectivity associated with the reaction of 2,3-dihalo-1-(phenylsulfonyl)-1-propenes with ambident nucleophilic reagents
Stereoselective synthesis of 1,3-amino alcohols and 1,3-amino ketones
Electroorganic chemistry. 134. Facile electroreduction of methyl esters and N,N-dimethylamides of aliphatic carboxylic acids to primary alcohols
Kinetics of hydroxide and nitromethide ion addition to substituted .beta.-nitrostyrenes in dimethyl sulfoxide-water mixtures. Solvent dependence of .pi.-donor substituent effects and of intrinsic rate constants
2,3-Dihalo-1-(phenylsulfonyl)-1-propenes as versatile reagents for the synthesis of annulated furans and cyclopentenones
The metalation-silylation of O-trimethylsilyl aldehyde cyanohydrins
Biocatalytic resolutions of sulfinylalkanoates: a facile route to optically active sulfoxides
Asymmetric synthesis of macbecin I
Diastereoselection in the Lewis acid catalyzed cycloaddition reaction of .alpha.-alkoxy imines
A short synthesis of (.+-.)-.beta.-isocomene
Calophycin, a fungicidal cyclic decapeptide from the terrestrial blue-green alga Calothrix fusca
The first enantioselective total syntheses of the allopumiliotoxin A alkaloids 267A and 339B
Ipso nitration of p-tert-butylcalix[4]arenes
Enantiomerically pure 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives (naked sugars) as synthetic intermediates. XII. Highly stereoselective total syntheses of octoses and derivatives. [Erratum to document cited in CA114(25):247589y]
Inversion of configuration in the displacement of lithium by hydrogen during a transannular 1,4-hydrogen transfer accompanying a [1,2]-Wittig rearrangement
Proton, electron, and hydrogen atom transfers from ions, radicals, and radical ions derived from substituted urazoles and triazolinediones
A theoretical analysis of the relative reactivity in radical addition reactions: acceptor-donor, acceptor-acceptor, and donor-donor 1,1-disubstituted ethenes. The effect of ground-state destabilization on reactivity
CC-1065 partial structures: enhancement of noncovalent affinity for DNA minor groove binding through introduction of stabilizing electrostatic interactions
Synthesis of C-disaccharides through dimerization of exo-glycals
Stereochemical features of the (2 + 2) cycloaddition reactions of chiral allenes. 4. The cycloaddition of enantioenriched 1,3-dimethylallene with methyl propiolate
Kinetic vs. thermodynamic factors in .alpha.-hydrogen atom abstractions from alkylaromatics. 2. Reactivities of .alpha.-alkylnaphthalenes and several conformationally locked alkylaromatics toward bromine atom. [Erratum to document cited in CA115(19):207432f]
Enzyme-catalyzed formation of chiral monosubstituted mixed diesters and half esters of malonic acid in organic solvents
1,2- vs. 1,4-addition of nucleophilic organometallics to nonracemic 2-(1-naphthyl)- and 2-cinnamyl-1,3-oxazolidines
Acylal hydrolysis. The pH-independent breakdown of 7-oxo-6,8-dioxabicyclo[3.2.1]octane
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