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Synthesis and characterization of the first fullerene-peptide
Mechanism of the solvolysis of bicyclo[1.1.1]pent-1-yl derivatives
Stereochemistry of the iodocarbonatation of cis- and trans-3-methyl-4-pentene-1,2-diols: the unusual formation of several anti iodo carbonates
A novel approach to extended phenalenones
Free-radical annelation in the synthesis of bicyclic .beta.-lactams. 7. A one-pot, four-step, sequential reaction
Total synthesis of (.+-.)-calanolide A, a non-nucleoside inhibitor of HIV-1 reverse transcriptase
Free-radical homolytic substitution at selenium: an efficient method for the preparation of selenophenes
Structure and synthesis of petrosynes, new acetylenic enol ether glycerides from the Okinawan marine sponge of the genus Petrosia
Reactions of perhydro-2,2'-bipyrimidines with carbonyl compounds bearing .alpha.-carbonyl functionality
1,6-Addition of organolithium compounds to acceptor-substituted enynes catalyzed by a copper(I) arenethiolate
Stereocontrolled total synthesis of (+)- and (-)-epibatidine
Near-degeneracy between the low- and high-spin states in an alternant hydrocarbon diradical: topology and geometry
Reaction of oximes with dimethyl carbonate: a new entry to 3-methyl-4,5-disubstituted-4-oxazolin-2-ones
New reagents for the syntheses of fluorescent chemosensors. Anthrylogous ethylene dibromides
Structure correction and synthesis of the naturally occurring benzothiazinone BMY 40662
Synthesis and reactivity of Cp2Zr(.eta.2-C,N-C{:N-tert-Bu}CH3)+. Regioselective acetylation of alkynes and alkenes
Two-laser-sensitized decomposition of carbon tetrachloride: photoacid generation
Dimethyl amino[(phenylthio)methyl]malonate: a useful C-3 unit in a mild, direct synthesis of oxazole-4-carboxylates
Investigation of the purity of alkali metal diphenylphosphides and their reactions with organic halides. Evidence for single electron transfer
An efficient synthesis of the sterically strained hydrocarbon tetrabenzo[de,hi,mn,qr]naphthacene
A regiospecific fluorination strategy: synthesis of .alpha.-fluoropropargyl- and .alpha.-fluoroallylphosphonate esters
Electrophilic amination of higher order cuprates with N,O-bis(trimethylsilyl)hydroxylamine
Photolysis of (arylmethyl)triphenylphosphonium salts. Substituent, counterion, and solvent effects on reaction products
Ab initio molecular orbital studies on C2H5O+ and C2H4FO+: oxonium ion, carbocation, protonated aldehyde, and related transition-state structures
Tandem radical [2+1] cycloaddition. Remarkable silyl substituent effect on the chemoselectivity of the radical cyclization reactions
Temporary tethering strategies for [5 + 2] pyrone-alkene cycloadditions
Novel plots of data from combined multistep enzymic resolutions of enantiomers
Stereocontrolled synthesis of N-vinyl-, N-(1'-propenyl)-, and N-unsubstituted-.beta.-lactams from 2-aza-1,3-butadienes via the Staudinger reaction
Masthead
Lewis acid-promoted 1,4-addition to chiral imide derivatives in the synthesis of .beta.-amino acids
Thiol anions in nucleophilic aromatic substitution reactions with activated aryl halides. Attack on carbon vs attack on halogen
Allenyl allylic ethers: synthesis and thermal rearrangements
Differentiation of contiguous hydroxyl groups by regioselective conversion of acetonides into tert-butyl hydroxyalkyl ethers
An efficient enantioselective total synthesis of antitumor lignans: synthesis of enantiomerically pure 4-hydroxyalkanenitriles via an enzymic reaction
A general and facile synthesis of .beta.- and .gamma.-hydroxy phosphonates from epoxides
Quenching behavior of singlet excited 9-arylxanthylium cations
Total synthesis of cyclotheonamide A
Crucigasterins, new polyunsaturated amino alcohols from the mediterranean tunicate Pseudodistoma crucigaster
Stereoselectivity in the reaction of dimethylsulfonium phenacylide with dibenzoylethylene
Synthesis and conformational analysis of nitropolycyclic fluoranthenes
Methods for the stereoselective synthesis of 2-fluoroalkenoates. Carbonyl condensation reactions of 3,3-bis(methylthio)-2-fluoropropenal, a highly-functionalized fluoroacrylate cation equivalent
Synthesis of a thromboxane A2 receptor antagonist possessing the dioxabicycloheptane nucleus of TXA2
Efficient syntheses of yuehchukene and .beta.-(dehydroprenyl)indole
Synthesis of methylene-bridged polycyclic aromatic hydrocarbons: an efficient, double Friedel-Crafts cyclization approach to 11H-benz[bc]aceanthrylene
Isotopic exchange involving the [8]annulene anion radical and its dimerization to the [16]annulene anion radical
Organometallic addition to N-(N-acyl-N-methylamino)cycloimminium salts: a general method for ketone synthesis
Stereoselection in the chromium mediated intramolecular [2 + 2] cycloadditions of vinyl ketenes and alkenes
Reactions of cobalt-complexed acetylenic aldehydes with chiral (.gamma.-alkoxyallyl)boranes: enantioselective synthesis of 3,4-dioxy-1,5-enynes
Conformational studies by dynamic NMR. 50. Atropisomerism in hindered naphthyl sulfoxides: structure, stereodynamics, and chiral resolution
An unexpected Heck reaction. Inversion of olefin geometry facilitated by the apparent intramolecular carbamate chelation of the .sigma.-palladium intermediate
Novel intramolecular cycloaddition reactions of arylamino-substituted Fischer chromium carbenes
Preparation of quinol N-acyl- and quinol ether imines via anodic oxidation of para-substituted anilide derivatives
Stereochemistry. 83. Unusual rearrangements in cage compounds due to proximity effects
Oxidation of 2-methylcyclohexanone and cyclohexanone by dioxygen catalyzed by vanadium-containing heteropolyanions
Pendant-capped porphyrins. 2. Structural analysis and dynamics of the biphenyl pendant-capped porphyrin model of catalase and its iron(III) complex by one- and two-dimensional proton NMR spectroscopy and distance geometry/molecular modeling refinement
Direct, low temperature, in situ nucleophilic aroylation with aroyllithium reagents
Concerning the mechanism for bifunctional catalysis in the methanolysis of methoxymethylphenoxyphenylsilane
Precise control of the formation of a covalent and an ionic bond in carbocation-carbanion combination reactions
Cesium dithiolate based syntheses of keto-functionalized thio-crown ethers employing the novel building block 1,3-dimercaptoacetone. Molecular structures of 2,5,9,12-tetrathia-7-oxo-(13)-m-benzenophane and 1,4,7,10,13-pentathiacyclohexadecan-15-one
Allenyl ethers as precursors of .alpha.-methylene-.gamma.-butyrolactones and botryodiplodin derivatives
Free energy halide affinities of carbenium ions in the gas phase and in solution
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