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Direct Amino-Crotylsilylation of Achiral Acetals and Aldehydes: Asymmetric Synthesis of Homoallylic Amines and Functionalized Pyrrolidines
A New and Safe Approach to (N-Vinylimino)phosphoranes
A Convenient Triphosgene-Mediated Synthesis of Symmetric Carboxylic Acid Anhydrides
Affinity Capillary Electrophoresis: Insights into the Binding of SH3 Domains by Peptides Derived from an SH3-Binding Protein
Influence of the Nature of the Solvent on the Enantioselectivity of Lipase-Catalyzed Transesterifications: A Comparison between the Lipases from Porcine Pancreas and Pseudomonas Fluorescens
Oxidation of N-Acylindoles by Dimethyldioxirane and Singlet Oxygen: Substituent Effects on Thermally Persistent Indole Epoxides and Dioxetanes
Mild and Selective Oxygenation of Sulfides to Sulfoxides and Sulfones by Perfluoro-cis-2,3-dialkyloxaziridines
2,4,6,8-Tetracarbomethoxybarbaralane
Masthead
A General and Efficient Synthesis of .alpha.-Azido Ketones
Tandem Fragmentation of Cyclopropylcarbinyl/Oxiranylcarbinyl Radicals. On the Reversibility of Oxiranylcarbinyl/Allyloxyl Radical Formation
Influence of Lone Pair Repulsion vs Resonance Energy on the Relative Stabilities of Molecular Structures: A Theoretical Approach to the Equilibrium between 1H- and 2H-Benzotriazole Tautomers
Total Synthesis of Sarcophytol A, an Anticarcinogenic Marine Cembranoid
Spectroscopy and Photochemistry of Phenylacetic Acid Esters and Related Substrates. The Stereoelectronic Dependence of the Aryl/Carboxyl Bichromophore Interaction
Separation of Ring Polar and Resonance Effects on the Rate and Equilibrium Constants for Methoxide Ion-Promoted Addition of Methanol to N-Benzylideneanilines Substituted at the Benzylidene Moiety
[3 + 2] and [3 + 3] Cycloadditions of Azides with Allylic Carbocations
Separation of Ring Polar and Resonance Effects on the Rate Constants for Uncatalyzed N-Arylidenepropylamine Formation in Methanol
Synthesis and Characterization of New "Expanded" Thiophene- and Furan-Containing Macrocycles
Synthesis of a Water-Soluble Dicyanoanthracene as a Cap For .beta.-Cyclodextrin
.beta.-Stannyl Allylic Alcohols through Photooxygenation (Schenck Reaction) of Vinylstannanes and Reduction of the Resulting Allylic Hydroperoxides: Synthesis and Selected Transformations
.pi.-Plus Contributions in .DELTA.E and .DELTA.C Dual-Parameter Correlations. Curved Hammett Plots and 19F Shifts
The Structure of "R2Cu(CN)Li2" Lithium Cuprates: Lower-Order Aggregates of Gilman Reagents and Organo Lithium Compounds
Novel Donor 1,4-Benzothiazino[2,3-b]phenothiazine
An Easy Route to (-)-10(R)-Isothiocyanoaromadendrane and (-)-10(S)-Isothiocyanoalloaromadendrane
A Novel Fluoride Ion Mediated Olefination of Electron-Deficient Aryl Ketones by Alkanesulfonyl Halides
Enantioselective Total Synthesis of the Antifungal Natural Products Chlorotetaine, Bacilysin, and Anticapsin and of Related Compounds: Revision of the Relative Configuration
Total Syntheses of All Four Isomers of cis-1,2-Dihydroxypyrrolizidine
Hydroboration/Intramolecular Reduction of Allyl Ketones with (Diisopinocampheyl)borane: A Convenient Synthesis of Enantiomerically Enriched 1,4-Diols
Synthesis of [(Trialkoxysilyl)propyl]imides
Efficient Preparation of the .alpha.,.alpha.,.alpha.,.alpha.-Atropoisomer of meso-Tetrakis[2-(2,3,4,6-tetraacetyl-O-.beta.-glucosyl)phenyl]porphyrin
A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX2-TiCl4-Zn Systems by Addition of Lead
Metal-Catalyzed, Intramolecular Reactions of .alpha.-Diazo Ketones with Isoxazoles
A Dramatic Effect of a Catalytic Amount of Lead on the Simmons-Smith Reaction and Formation of Alkylzinc Compounds from Iodoalkanes. Reactivity of Zinc Metal: Activation and Deactivation
A Concluding Specification of the Dimensions of the Active Site Model of Pig Liver Esterase
A Concise, Stereocontrolled Thiazolium Ylide Approach to Kainic Acid
A Short, Stereocontrolled Synthesis of Strychnine
Molecular Structures and Photochemical Behavior of Doubly Bridged Prismanes
General Approach to the Synthesis of Specifically Deuterium-Labeled Nucleosides
Simple Designs for the Construction of Complex trans-Fused Polyether Toxin Frameworks. A Linear Strategy Based on Entropically Favored Oxirane Ring Enlargement in Epoxycycloalkenes Followed by Carbon-Carbon or Carbon-Oxygen Bond-Forming Cyclizations
Boronic Acids Mediate Glycoside Transport through a Liquid Organic Membrane via Reversible Formation of Trigonal Boronate Esters
Syntheses of Substituted Succinimides by Radical .beta.-Fragmentation of Bicyclic Carbinol Amides. A New Expeditious Synthesis of 2-[2-(Methoxycarbonyl)ethyl]-3-[(methoxycarbonyl)methyl]- 3-methylsuccinimide, the Ring-B Imide of Vitamin B12
Equilibrium Acidities of HA2+ Dications in Dimethyl Sulfoxide Solution
Acylcyanation of Terminal Acetylenes: Palladium-Catalyzed Addition of Aryloyl Cyanides to Arylacetylenes
Regioselective Aryl Radical Cyclization. 1. Stereocontrolled Synthesis of Linearly Condensed Hydroaromatic Carbocyclic Systems through 6-endo-Ring Closures
Multiple Reaction Channels of (N-Acyl-N-alkylcarbamoyl)oxyl Radicals from N-Acyl PTOC Carbamates
Free-Radical Addition of Alkanethiols to Alkynes. Rearrangements of the Intermediate .beta.-(Vinylthio) Radicals
Chemoenzymic Synthesis of 3-Deoxy-D-arabino-heptulosonic Acid from Cycloheptatriene
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