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Catalytic Enantioselective Synthesis of 20(S)-Camptothecin: A Practical Application of the Sharpless Asymmetric Dihydroxylation Reaction
Radical Addition Reactions to Allylstannanes Having Substituents at C-1. Highly Efficient Synthesis of Enantiomerically Pure .alpha.-Alkylcyclopentenones, the Key Component for Synthesis of Prostaglandins by the Two-Component Coupling Process
Chloriolins A-C, Chlorinated Sesquiterpenes Produced by Fungal Cultures Separated from a Jaspis Marine Sponge
Synthesis of (+)-8-Deoxyvernolepin
Synthesis of Sphingomyelin and Ceramide 1-Phosphate from Ceramide without Protection of the Allylic Hydroxyl Group
Chiral Acetal-Initiated Asymmetric Pentacyclization. Enantioselective Synthesis of 18.alpha.(H)-Oleananes
Ritterazine A, a highly cytotoxic dimeric steroidal alkaloid, from the tunicate Ritterella tokioka
Changes in Transition State Structure for Protonation of Aryldiazomethanes in Aqueous Solutions
Preussomerins and Deoxypreussomerins: Novel Inhibitors of Ras Farnesyl-Protein Transferase
Nonreductive Desulfenylation of 3-Indolyl Sulfides. Improved Syntheses of 2-Substituted Indoles and 2-Indolyl Sulfides
Electrochemical Oxidation of a Galvinol-Substituted Alkanethiol Monolayer
Steric Effects on the Regioselectivity of an Azide-Alkyne Dipolar Cycloaddition Reaction: The Synthesis of Human Leukocyte Elastase Inhibitors
Thermolysis of Geminal BisAzoalkanes. Stabilization of a Carbon-Centered Radical by the Azo Substituent
Mechanism of Arene Hydroxylation by Vanadium Picolinato Peroxo Complexes
Formation of Carbon-Carbon Bonds via Quinone Methide-Initiated Cyclization Reactions
Efficient Synthesis of Losartan,A Nonpeptide Angiotensin II Receptor Antagonist
A Stereodivergent Access to Naturally Occurring Aminocarba Sugars from (Phenylsulfonyl)-7-oxabicyclo[2.2.1]heptane Derivatives. Total Synthesis of Penta-N,O-Acetyl-(.+-.)-Validamine and Its C1 and C2 Stereoisomers
The Dolastatins. 21. Synthesis, X-ray Crystal Structure, and Molecular Modeling of (6R)-Isodolastatin 10
Hydrolysis of O-Isopropenyl Glucopyranosides Involves C-Protonation and Alkenyl Ether Cleavage and Exhibits a Kinetic Influence of Anomeric Configuration
Aulosirazole, a novel solid tumor selective cytotoxin from the blue-green alga Aulosira fertilissima
Effect of C-9 Substituents on the Regioselectivity of A-Ring Reactions in Derivatives of the Wieland-Miescher Ketone
Solvolyses of 4-Oxo-2eq- and -2ax-adamantyl Triflates: Significant Through-Bond Interaction of the .beta.-Carbonyl Lone Pair with the Cationic p Orbital in Equatorial Solvolyses
Nucleophilic Substitution Reactions of Phenacyl Bromide Oxime: Effect of the Solvent and the Basicity of the Nucleophile
Asymmetric Allylation of Aldehydes with Chiral Lewis Bases
Asymmetric Synthesis of .gamma.-D- and -L-Glutamyl-L-meso-diaminopimelic Acid Dipeptide
Synthesis, Crystal Structure, Dynamic Behavior and Reactivity of Dinaphtho[2,1-b:1',2'-d]phospholes and Related Atropisomeric Phosphacyclic Derivatives
Acidities and Homolytic Bond Dissociation Enthalpies (BDEs) of the Acidic H-A Bonds in Acyclic and Cyclic Alkoxycarbonyl Compounds (Esters and Carbamates)
Cation Radicals as Intermediates in Aromatic Halogenation with Iodine Monochloride: Solvent and Salt Effects on the Competition between Chlorination and Iodination
Reactions of (Vinylimino)phosphoranes and Related Compounds: Access to the Azacarbolines and Aplysinopsines
Solvolysis of the (p-Methoxybenzyl)dimethylsulfonium Ion. Development and Use of a Scale to Correct for Dispersion in Grunwald-Winstein Plots
Preparation of Sugar-Derived .beta.-Keto Phosphonates and Their Use in the Synthesis of Higher Sugars
A New Spiroketal Type from the Insect Kingdom
Synthesis of Enantiopure .alpha.,.omega.-Diamino Dicarboxylates and Azabicycloalkane Amino Acids by Claisen Condensation of .alpha.-[N-(Phenylfluorenyl)amino] Dicarboxylates
Large scale production of recombinant .alpha.-1,2-mannosyltransferase from E. coli for the study of acceptor specificity and use of the recombinant whole cells in synthesis
Novel Synthesis of 5-(Arylimino)-4-(dialkylamino)-5H-1,2,3-dithiazoles and the Mechanism of Their Formation
Nonpeptide HIV Protease Inhibitors. Differential Introduction of Alkylamino Groups into the Two Aryl Rings of Haloperidol
Mechanism of Reaction of Geminal Dihalides with Magnesium. Evidence for the Formation of Carbenes from Radical Precursors. The Similarity in Reactions of Geminal Dihalides with Magnesium and LiAlH4
Oxidation of vic-Diols to .alpha.-Dicarbonyl Compounds Using the Oxoammonium Salt Derived from 4-Acetamido-TEMPO and p-Toluenesulfonic Acid
Peptide Analog Systems. 9. Synthesis of 1,2,4-Triazines. 16. Bridged Azapeptides, a Class of Novel 1,4,5,6-Tetrahydro-1,2,4-triazin-3(2H)ones
The Dolastatins. 17. Synthesis of Dolaproine and Related Diastereoisomers
SINDO1 Study of the Photochemical Synthesis of Cyclobutadiene from .alpha.-Pyrone
Mechanism of Alkaline Cyclization of 2-(Substituted benzamido)benzamides to 4-Quinazolinones
Novel nor-Sesquiterpenoids in New Zealand Honeys. The Relative and Absolute Stereochemistry of the Kamahines: An Extension of the Mosher Method to Hemiacetals
Synthetic Photochemistry. 65. Synthesis of Hexacyclo[6.4.2.02,7.03,11.06,10.09,12]tetradecane
SINDO1 Study of Photochemical Synthesis of Azacyclobutadiene from 1,3-Oxazin-6-one
Total Synthesis of (.+-.)-Atpenin B. An Original "Clockwise" Functionalization of 2-Chloropyridine
Synthesis, Properties, and X-ray Structure of 6-Aza-5,7,12,14-tetrathiapentacene as a Novel Polyheterocyclic Electron Donor, and Related Compounds
Aminoborohydrides. 4. The Synthesis and Characterization of Lithium Aminoborohydrides: A New Class of Powerful, Selective, Air-Stable Reducing Agents
Synthesis of Extended Linear Aromatics Using Tandem Diels-Alder Aromatization Reactions
Synthesis and Regioselective Hydrolysis of 2-(Imidazol-1-yl)succinic Esters
Modification of Hydroxybenzopyranoids: Facile Deoxygenation of 2,2-Dimethyl-7-hydroxy-4-chromanones and a New Approach to Their Novel Mercapto Analogs
Solvolysis Reactions: Relative Abilities of Cyclopentyl/Phenyl Groups To Stabilize an Electron-Deficient Carbon
[2 + 2] Photocycloaddition of Cinnamyloxy Silanes
On the Synthesis of Phosphonamidate Peptides
A New Approach to the Synthesis of Monocyclic .beta.-Lactam Derivatives
Korupensamines A-D, Novel Antimalarial Alkaloids from Ancistrocladus korupensis
Characterization of [n]-Ladderanes of Unprecedented Length: A New Record for Fused Carbocyclic Arrays
First Syntheses of Novel Paclitaxel(Taxol) Analogs Modified at the C4-Position
Thiazole-Based Synthesis of Formyl C-Glycosides
A Simple and Cost Effective Synthesis of Chloromethyl Methyl Ether
Tungstate-Catalyzed Decarboxylative Oxidation of N-Alkyl-.alpha.-amino Acids: An Efficient Method for Regioselective Synthesis of Nitrones
Exploring the reactivity of alkenes bearing silicon and/or tin in the hydroxyl-directed hydrogenation. A diastereoselective synthesis of heterobimetallic compounds
Participation of an Extended p-Oxo Ketene Intermediate in the Dissociative Alkaline Hydrolysis of Aryl 4-Hydroxycinnamates
Proposed Intermediates in the Tautomerization of Benzofurazan 1-Oxide
Reaction of Pentadienyltrimethylsilane with N-Acyliminium Ion Intermediates. A Convenient Route to Pentadienyl-Substituted Lactams
Masthead
Asymmetric Synthesis of Isoindoline and Isoquinoline Derivatives Using Nickel(0)-Catalyzed [2 + 2 + 2] Cocyclization
Synthesis of Optically Active .alpha.-Hydroxy Lactones by Sharpless Asymmetric Dihydroxylations of Ketene Acetals, Enol Ethers, and Ene Lactones
Synthesis of Enantiomerically Pure Fluoro- and gem-Chlorofluorocyclohexane Derivatives
Use of a .DELTA.1-Piperidine for the Synthesis of a Differentially Protected Diamine Intermediate for the Preparation of the Iron Siderophore Desferrioxamine
Direct Fluorination of Diarylacetylenes to Diaryltetrafluoroethanes with Convenient F2 Equivalent Nitrosonium Tetrafluoroborate-Pyridinium Polyhydrogen Fluoride
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