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Total Synthesis, Absolute Configuration, and Later Isolation of (-)-Prehalenaquinone, a Putative Biosynthetic Precursor to the Marine Natural Products: Halenaquinone and Xestoquinone
A Novel Oxygenative Carbon-Carbon Bond Cleavage Reaction by Irradiation of Alkylcobaloximes Having a Phenyl Group at the .beta.-Position
A Novel, Practical Synthesis of Estra-1,3,5(10)-triene-3,17.beta.-dicarboxylic Acid 17-tert-Butylamide (SK&F 105656) from Estrone, via a Palladium-Catalyzed Methoxycarbonylation of a 3-Fluorosulfonate
Synthesis and Properties of 2,3,6,7-Tetrakis(alkoxymethyl)tetrathiafulvalenes
Five new alkaloids from the tropical ascidian, Lissoclinum sp. lissoclinotoxin A is chiral
Xylose: The First Ambident Acceptor Substrate for Galactosyltransferase from Bovine Milk
Difunctional Monomers Based on Perfluoropropylene Telomers
Masthead
Difunctionalized 4-Nitroisoxazoles as Synthetic Equivalents of the Corresponding 4,5-Didehydroderivative in [2 + 4] Cycloadditions with 2,3-Dimethylbuta-1,3-diene: Reductive Eliminations of the Activating Groups from the Primary Adducts
Diastereoselective Synthesis of the Antibiotic L-Azatyrosine
Use of Chloride Ion as a Catalyst for Dehydrochlorination Reactions: The Synthesis of 3,5,6-Trichloropyridin-2-ol
Fluorination of Nitro Compounds with Acetyl Hypofluorite
Trimethylsilyl Trifluoromethanesulfonate-Catalyzed Reaction of 2-[(Trimethylsilyl)oxy]furan with Nitrones
Tether-Mediated Stereocontrol in Intramolecular Azomethine Ylide Cycloadditions
Synthesis and Application of Bis-Silylethyl-Derived Phosphate-Protected Fmoc-Phosphotyrosine Derivatives for Peptide Synthesis
Does the Nucleophilic Substitution of Halogen in o- and p-Halonitrobenzenes with Cyanoacetate Carbanions Proceed via Single Electron Transfer and a Nonchain Radical Process?
Preparation of (Z)-1-Alkenyl Dioxaborolanes by Hydrolysis of Boryl Zirconocene 1,1-Dimetalloalkenes
Rate Constants for 5- and 6-Exo Secondary Alkyl Radical Cyclizations onto N,N-Diphenylhydrazones
The Osmium(II)-Promoted [4 + 2] Cycloaddition Reaction of Anisole and N-Methylmaleimide and Characterization of the .eta.2-4H-Anisolium Intermediate
Enantiomerically Pure Amino Alcohols and Diamino Alcohols from L-Aspartic Acid. Application to the Synthesis of Epi- and Diepislaframine
Chiral Host-Guest Interaction. A Water-Soluble Calix[4]resorcarene Having L-Proline Moieties as a Non-Lanthanide Chiral NMR Shift Reagent for Chiral Aromatic Guests in Water
Oxidation of 1-(Triphenylsilyl)cyclopropenes with Dimethyldioxirane
Preferred Conformation of C-Glycosides. 13. A Comparison of the Conformational Behavior of Several C-, N-, and O-Furanosides
Xanthate Transfer Cyclization of Glycolic Acid-Derived Radicals. Synthesis of Five- to Eight-Membered Ring Ethers
Reactions of Phosphine-Monoiodoboranes with 4,4'-Di-tert-butylbiphenylide and Electrophiles. Trial of Generation of Tricoordinate Boron Anions and Synthesis of B-Functionalized Phosphine-Boranes
Chemistry of Indolo[1,2-c]quinazoline: An Approach to the Marine Alkaloid Hinckdentine A
Competition of Mechanisms in Nucleophilic Substitution of Vinyl Halides. An Unequivocal Example of the Vinylic SRN1 Route1
Stable Monosubstituted Triazenes by Reduction of Some Tertiary Azides
Reactions of Dichlorocyclobutenones with nucleophiles: A Synthesis of Some New Cyclobutenones and an Unusual Ring Expansion to a Butenolide
Mechanism of the Gibbs Reaction. 3. Indophenol Formation via Radical Electrophilic Aromatic Substitution (SREAr) on Phenols
Regioselective Lewis Acid-Directed Reactions of 2-Alkoxy-5-alkyl-1,4-benzoquinones with Styrenes: Synthesis of Burchellin and Guianin Neolignans
Facile and Highly Stereoselective Synthesis of Homoallylic Alcohols Using Organosilicon Intermediates
Synthesis and Thermolysis of Ketal Derivatives of 3-Hydroxy-1,2-dioxolanes
3,4,6-Tri-O-benzyl-.alpha.-D-arabino-hexopyranos-2-ulosyl Bromide: A Versatile Glycosyl Donor for the Efficient Generation of .beta.-D-Mannopyranosidic Linkages
Amino-Imino Tautomerization of N2-(4-n-Butylphenyl)-2'-deoxy-3,5'-cycloguanosine
Scope and Limitations of the Palladium-Catalyzed Cross-Coupling Reaction of in situ Generated Organoboranes with Aryl and Vinyl Halides
Tandem Aldol-Cyclization Sequence for the Construction of Cyclic Ethers. The Formation of Substituted Tetrahydrofurans
Introduction of Allylic Side Chains onto Peptides by Pd(0)-Catalyzed "Ester Enolate Claisen Rearrangement"
Tetra-O-benzoylglucosylation: A New 1H Nuclear Magnetic Resonance Method for Determination of the Absolute Configuration of Secondary Alcohols
Two Practical Syntheses of Sterically Congested Benzophenones
Practical Synthesis of .beta.-D-Xyl-(1.fwdarw.2)-.beta.-D-Man-(1.fwdarw.4)-.alpha.-D-Glc-OMe, a Trisaccharide Component of the Hyriopsis schlegelii Glycosphingolipid
Lewis Acidity and Basicity: An Ab Initio Study of Proton and BF3 Affinities of Oxygen-Containing Organic Compounds
Deracemization of a Phosphine Oxide via Enantioselective Protonation
Functionalization of Benzonorbornadiene: High-Temperature Bromination and Electrochemical Oxidation
Aryl Proton Transfer Reactions of 9-Arylanthracene and 9-Substituted Anthracene Radical Cations with 2,6-Di-tert-butylpyridine
Highly Oxygenated Decalins via Michael-Claisen Condensation
Lone Pairs in Carbonyl Compounds and Ethers
Efficient Oxidative Coupling of 2-Naphthols Catalyzed by Alumina-Supported Copper(II) Sulfate Using Dioxygen as Oxidant
Directed Metalation of Diaryl Sulfone 2-Amides and 2-O-Carbamates. Regiospecific General Route to Thioxanthen-9-one 10,10-Dioxides via Anionic Friedel-Crafts and Remote Fries Rearrangement Equivalents
Synthesis and Biological Activity Of Unsymmetrical Bis-Steroidal Pyrazines Related to the Cytotoxic Marine Natural Product Cephalostatin 1
Stereoselective Synthesis of Higher Sugars by Homologation of Carbohydrate-Derived Enals with Nonracemic .gamma.-(Silyloxy) Allylic Stannanes and Substrate-Directed Hydroxylation
Stereoselective Synthesis Of Dimethylrobustadials
Synthesis and Multistage Redox Properties of 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene Derivatives Functionalized with Ferrocenyl and Tetrathiafulvalenyl Units
Enantiomeric Recognition between Chiral Triazole-18-crown-6 Ligands and Organic Ammonium Cations Assessed by 13C and 1H NMR Relaxation Times
A general approach to 3-phosphorylmethyl cycloalkenones by intramolecular Horner-Wittig reaction of bis-.beta.-ketophosphonates
Vinylogous Formylation of Aromatics with 3-Trifloxypropeneiminium Triflates
Manipulation of the Rapamycin Effector Domain. Selective Nucleophilic Substitution of the C7 Methoxy Group
2-(Alkylamino)-4-cyclopentene-1,3-diones via Addition of Imidoyl Lithiates to Cyclobutenediones
Cyclization of (4-Methoxy-5-hexenyl)lithium
Influence of BF4- Position on the N:N Distance of Trialkyldiazenium Cation Salts
Preparation of Nonracemic 3,5-Disubstituted-.gamma.-butyrolactones: An Effective Sequent Auxiliary for Amide Alkylation and Iodolactonization
Stereospecific Lewis Acid-Promoted Reactions of Styrenyl Systems with 2-Alkoxy-(6-Alkyl)-1,4-Benzoquinones: Scope, Limitations, and Synthetic Applications
General Photoisomerization Approach to trans-Benzobicyclo[5.1.0]octenes: Synthetic and Mechanistic Studies
Intramolecular Ene Reaction of Vinylphosphonates. Synthetic Application to Bicyclic Compounds and Cadalane and Valerenic Acid Terpenoids
Total Synthesis of (.+-.)-Dragmacidin: A Cytotoxic Bis(indole)alkaloid of Marine Origin
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