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Can Remote Substituent Effects Influence Reactivity and Stereoselectivity in the Diels-Alder Cycloadditions of p-Substituted 6-Phenyl-6-methylfulvenes?
New Generation Method for a Samarium(II) Equivalent: Me3SiX (X = Br and I)/Sm-Assisted Intermolecular Carbon-Carbon Bond Forming Reactions of Carbonyl Compounds
Masthead
The Chemistry of Phosphapeptides: Investigations on the Synthesis of Phosphonamidate, Phosphonate, and Phosphinate Analogs of Glutamyl-.gamma.-glutamate
In Quest of Tricyclo[4.4.1.04,11]undeca-1,3,5,7,9-pentaene, a Highly Strained, Cyclic 10.pi.-Electron, Polyunsaturated Hydrocarbon. Synthesis of a Methoxyl-Substituted Dihydro Derivative
Glycosidation Route to 4''-epi-(Methylamino)-4''-Deoxyavermectin B1 (MK-244, Emamectin Benzoate)
Preparation of 2,2-Dichloro-3(2H)-furanone and Its Reactions with Heteronucleophiles
Iminodithiocarbonates as Formaldehyde Imine Equivalents: Sequential Two Step Approach to 4-Unsubstituted .beta.-Lactams through Chromium(0) Carbene Photocycloaddition-Nickel Boride Desulfurization
General Enantiospecific Route to Isochromanquinones. Synthesis of (-)-Nanaomycin D
Peroxometalate Catalyzed Oxidations with Hydrogen Peroxide in Biphasic Reaction Media: Reactions in Inverse Emulsions
On the Transition State of the Chorismate-Prephenate Rearrangement
Kinetic Resolution of Phosphines and Phosphine Oxides with Phosphorus Stereocenters by Hydrolases
Ester Cleavage by Cyclodextrins in Aqueous Dimethyl Sulfoxide Mixtures. Substrate Binding versus Transition State Binding
A New Access to Kainoids via a Tandem Aza-Cope/Mannich Reaction. Application to the Enantioselective Synthesis of (-)-.alpha.-Allokainic Acid
Total Synthesis of ACRL Toxin IIIb: A Protocol for Parlaying Aldols into Synthons Containing Three Stereocenters Having an [n, n + 1, n + 4] Relationship
Synthesis and Evaluation of 3-Dehydroquinate Synthase Transition State Analogs
Syntheses of Strychnos- and Aspidospermatan-Type Alkaloids. 6. Total Syntheses of (.+-.)-Echitamidine, (.+-.)-Alstogustine, (.+-.)-19-epi-Alstogustine, and (.+-.)-Akuammicine
Editorial
Synthesis, Characterization, and Alkali Metal Stability Constants of a New Bis(phosphotriester) Macrobicyclic Polyether Cryptand
Rearrangement of (Polymethoxybenzyl)ammonium N-Methylides
A TMM Cycloaddition Strategy to the Bicyclo[6.3.0]undecyl Ring System. A Total Synthesis of 11-Hydroxyjasionone
Theoretical Characterization of Cycloaddition Reactions of the Cyclopropylcarbinyl Cation
Synthesis of New Tetrafluorobenzo Heteroaromatic Compounds
Boranes in Synthesis. 6. A New Synthesis of .beta.-Amino Alcohols from Epoxides. Use of Lithium Amides and Aminoborane Catalysts To Synthesize .beta.-Amino Alcohols from Terminal and Internal Epoxides in High Yield
Synthesis and Structure of 2,2'-Dihydroxybenzophenones and 1,8-Dihydroxyfluorenones
Conformationally Rigid Tricyclic Tripods: Synthesis and Application to Preparation of Enterobactin Analogs
Stereocontrolled Total Synthesis of Calcitriol Derivatives: 1,25-Dihydroxy-2-(4'-hydroxybutyl)vitamin D3 Analogs of an Osteoporosis Drug
Effects of Olefin Geometry on the Stereochemistry of Lewis Acid Mediated Additions of Crotylstannanes to Aldehydes
Stannylformylation of 1,6-Dienes Accompanied by Five-Membered Radical Ring Closure
Enantioselective Synthesis of Homoallylic Amines by Addition of Allylmetal Reagents to Imines Derived from (S)-Valine Esters
Stereoselective Synthesis of 6-Substituted Decahydroisoquinoline-3-carboxylates: Intermediates for the Preparation of Conformationally Constrained Acidic Amino Acids
A Novel Synthesis of Methyl 1,5-Disubstituted Imidazole-4-carboxylates Using 3-Bromo-2-isocyanoacrylates (BICA)
Synthesis of [1.1.1.1]Metacyclophane Macrocycle
Diastereoselective .alpha.-Alkylation of 2-Acyl-3-phenyl-l-menthopyrazoles
Remote Conformational Bias Effects on Diastereofacial Selectivity in SE2' Additions of .gamma.-Oxygenated Allylic Stannanes to Chiral Enals
Stereospecific Synthesis and NMR Conformational Studies of .gamma.-Butyrolactones of Nucleosides as Chiral Synthons for the Preparation of 2'-C- and 3'-C-Branched-Chain Nucleosides
Reactions of Benzaldehyde with Thiazolium Salts in Me2SO: Evidence for Initial Formation of 2-(.alpha.-Hydroxybenzyl)thiazolium by Nucleophilic Addition, and for Dramatic Solvent Effects on Benzoin Formation
The Chemistry of Phosphapeptides: Formation of Functionalized Phosphonochloridates under Mild Conditions and Their Reaction with Alcohols and Amines
Novel Cyclopentenone Synthesis by Base-Catalyzed Cyclization of Dienediones
Ruthenium Complex-Catalyzed Carbonylation of Allylic Compounds
A Novel, Mild, and Practical Regeneration of Alcohols from their Allylic Ethers by NBS/H2O
Resolution of Amino Acids in a Mixture of 2-Methyl-2-propanol/water (19:1) Catalyzed by Alcalase via in Situ Racemization of One Antipode Mediated by Pyridoxal 5-Phosphate
On the Stereoselectivity of the Reaction of N-(9-Phenylfluoren-9-yl)aspartate Enolates with Electrophiles. Synthesis of Enantiomerically Pure 3-Hydroxy-, 3-Amino-, and 3-Hydroxy-3-methylaspartates
Asymmetric Diels-Alder Reactions of Chiral (E)-2-Cyanocinnamates. 2. Synthesis of the Four 1-Amino-2-phenyl-1-cyclohexanecarboxylic Acids in Enantiomerically Pure Form
Stereocontrolled Formation of Quaternary Carbon Centers by Conjugate Addition of Lithium Enolates of Dioxanones to .beta.-Bromoacrylates and .beta.-Bromovinyl Sulfones: Dependence of Stereoselectivity on Alkene Geometry
Asymmetric Synthesis of 6,6'-Dialkoxy-2,2'-biphenyldiols by Using Menthone as a Chiral Template
Silylcarbobicyclization of 1,6-Diynes: A Novel Catalytic Route to Bicyclo[3.3.0]octenones
Nonionic Superbase-Promoted Synthesis of Oxazoles and Pyrroles: Facile Synthesis of Porphyrins and .alpha.-C-Acyl Amino Acid Esters
Urea-Derivatized p-tert-Butylcalix[4]arenes: Neutral Ligands for Selective Anion Complexation
Asymmetric Synthesis of Chiral Secondary Alcohols with Isopropyl Substituents by the Catalytic Enantioselective Addition of Diisopropylzinc to Aldehydes using N,N-Dialkylnorephedrines as Chiral Catalysts
Stereoselective Synthesis of .beta.-Oxygenated .alpha.-Hydroxyphosphonates by Lewis Acid-Mediated Stereoselective Hydrophosphonylation of .alpha.-Benzyloxy Aldehydes. An Application to the Synthesis of Phosphonic Acid Analogs of Oxyamino Acids
New 1H and 13C NMR Spectral Data on "Higher Order" Cyanocuprates. If the Cyano Ligand Is Not On Copper, Then Where Is It?
Total Synthesis of (.+-.)-Aspidofractinine and (.+-.)-Aspidospermidine
Syntheses of 4''-epi-Amino-4''-deoxyavermectins B1
Theoretical Study of Ethylene and Vinyl Alcohol Addition to 1,4-Dioxa-1,3-butadiene
Dualistic Reactivity of Lithium and Zinc Dienolates with Imines: Effects of Counterion, Temperature, and Substituents on .alpha.- and .gamma.-Coupling
Stereoselective Synthesis of 2'-Deoxy-.beta.-D-threo-pentofuranosyl Nucleosides by the NBS-Promoted Coupling Reaction of Thioglycosides with Silylated Heterocyclic Bases
Synthesis of .alpha.-Pyridone-Based Azaheteroaromatics by Intramolecular Vinylketene Cyclizations onto the C:N Bond of Nitrogen Heteroaromatics
Practical Synthesis of Chiral Synthons for the Preparation of HMG-CoA Reductase Inhibitors
Enediyne- and Tributyltin Hydride-Mediated Aryl Radical Additions onto Various Radical Acceptors
Design and Synthesis of a Conformationally Restricted Cysteine Protease Inhibitor
Synthesis and Exchange Reactions of 1,4,8,11-Tetraazacyclotetradeca-7(E),14(E)-diene-5,12-diones
Lewis Acid Promoted Additions of .gamma.-Alkoxy- and -(Silyloxy)crotylstannanes to (S)-2-(Benzyloxy)propanal
3-(Tri-n-butylstannyl)-2-cyclobuten-1-one: Synthesis and Stille Cross-Coupling as a Route to 3-Substituted Cyclobutenones
Methods for Combinatorial Organic Synthesis: The Use of Fast 13C NMR Analysis for Gel Phase Reaction Monitoring
Radical Cations of Benzo[a]pyrene and 6-Substituted Derivatives: Synthesis and Reaction with Nucleophiles
Thiol Mediated Free Radical Cyclization of Alkenyl and Alkynyl Isocyanides
Consequences of .alpha.-Bromo Substitution on the Course of Allylmetal Additions to 1-Oxaspiro[4.5]dec-7-en-6-one
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