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Diastereoselectivities Associated with the 1,2-Addition of Chiral (Racemic) Cyclopentenyl Organometallics to Bicyclo[2.2.2]octenones
Absolute Stereochemistry of the Squalene Synthase Inhibitor Zaragozic Acid C
A Novel BF3.cntdot.OEt2-Catalyzed [3 + 2] Annulation of N-Cbz-.alpha.-Amino Aldehydes with Allyltrimethylsilane. Highly Stereoselective Synthesis of Cis-2,3,5-Trisubstituted Pyrrolidines
Diastereoselective Diels-Alder Cycloadditions with Chiral 1-(Alkylsulfinyl)-2-nitroalkenes
Stepwise Regeneration and Recovery of Deoxyribonucleoside Phosphoramidite Monomers During Solid-Phase Oligonucleotide Synthesis
Synthesis of a Phosphotyrosine-Containing Peptide Fragment of the Regulatory Domain of pp60c-src
Asymmetric Syntheses of Protected Derivatives of Carnosadine and Its Stereoisomers as Conformationally Constrained Surrogates for Arginine
A New Method for the Synthesis of Nonsymmetric Dinucleating Ligands by Aminomethylation of Phenols and Salicylaldehydes
Synthesis of Polyfunctionalized 1-Aminobuta-1,3-dienes by Addition of Dimethyl Acetylenedicarboxylate to (Z)-.beta.-Enamino-.lambda.5-Phosphazenes. Configurational and Conformational Analysis Based on NOE Data, nJPX Coupling Constant, X-ray Structures, and Semiempirical Calculations
Mild, Zinc-Induced Defluorination of Butatrienes: Stereoselective Formation of Divinylacetylene Derivatives
Stereoselective Epoxidations and Electrophilic Additions to Partial Ergot Alkaloids and Conformationally-Fixed Styrenes. Experimental and Theoretical Modeling Evidence for the Importance of Torsional Steering as a Stereocontrol Element
Bismuth(III) Halide-Catalyzed Tandem Aldol-Halogenation Reaction: A Convenient Synthesis of .beta.-Halo Ketones and Esters
Thiol Peroxidase Activity of Diorganyl Tellurides
Regiocontrol by Remote Substituents. A Direct Total Synthesis of Racemic Hongconin
Arm-to-Arm Autoxidation in a Triglyceride: Remote Group Reaction Kinetics
Total Synthesis of 18-Oxo-3-virgene, a Constituent of the Waxy Surface Resins of Tobacco
Theoretical Study of the Metacyclophanes anti-Benzo[9,10-a][2.2]metacyclophan-1-ene, trans-12c,12d-Dihydrobenzo[e]pyrene, and Benzo[e]pyrene
Chiral Base-Mediated Asymmetric Synthesis of Tricarbonyl(.eta.6-arene)chromium Complexes
Facile Intramolecular Acylation Reactions of .gamma.- and .delta.-(Acyloxy)Sulfones: Synthesis of Substituted Chiral Dihydrofurans and Dihydropyrans
Biosynthetic studies on the xanthone antibiotics lysolipins X and I
Brevetoxin B: Chemical Modifications, Synaptosome Binding, Toxicity, and an Unexpected Conformational Effect
Ab Initio Examination of Anomeric Effects in Tetrahydropyrans, 1,3-Dioxanes, and Glucose
Abbreviated Ibogaine Congeners. Synthesis and Reactions of Tropan-3-yl-2- and -3-indoles. Investigation of an Unusual Isomerization of 2-Substituted Indoles Using Computational and Spectroscopic Techniques
Divergence between the enzyme-catalyzed and noncatalyzed synthesis of 3-dehydroquinate
Intramolecular Diyl Trapping Chemistry: Diyl-Decoupling and 7-endo-trig Cyclization
Transition Metal-Catalyzed, Chlorine-Transfer Radical Cyclizations of 2-(3-Alken-1-oxy)-2-Chloroacetates. Formal Total Synthesis of Avenaciolide and Isoavenaciolide
Selective Cross-Coupling of 2-Naphthol and 2-Naphthylamine Derivatives. A Facile Synthesis of 2,2',3-Trisubstituted and 2,2',3,3'-Tetrasubstituted 1,1'-Binaphthyls
Ring Opening of Azetidinols by Phenols: Regiochemistry and Stereochemistry
Synthesis of the First Thieno[3,4-c]thiophene Stabilized Only by Electronic Effects
Regioselective and in Some Cases Stereoselective Carbonylation of .alpha.-Allenic Alcohols to .alpha.-Vinylacrylic Acids Catalyzed by a Cationic Palladium Complex
Optically Active Total Synthesis of Calphostin D
A New and Improved Preparation of Acyclic .sigma.-Dialkoxyphosphoranes
Masthead
Synthesis and Coordination Properties of Pendant Arm Dipyridylmethane Derivatives
Cyclization and Reductive Cleavage of Monospirodienone Calix[4]arene Derivatives. Trihydroxy-p-tert-butylcalix[4]arene Revisited
Alkali metal salts of perfluorinated complex anions. Effective reagents for nucleophilic fluorination
Synthesis and Characterization of Large (30-60-Membered) Aliphatic Crown Ethers
Preparation of (Phenyloxazolo)-3-sulfolene. A Precursor for (Phenyloxazolo)-o-quinodimethane
Relevance of Conformational Constraints to the Regioselective Lithiation of Aromatic Diethers. Application to the Convenient Construction of the DEF Tricyclic Subunit of the Austalides
Simultaneous Multiple Synthesis of Peptide Amides by the Multipin Method. Application of Vapor-Phase Ammonolysis
Versatile [3 + 2] methylenecyclopentane annulations of unactivated and electron-rich olefins with [(trimethylsilyl)methylene]cyclopropanedicarboxylates
Synthesis of Chiral Hydroxylated Quinolizidines via Vinylogous Bischler-Napieralski Nitrilium Ion Cyclizations
Regioselectivity in Photochemical Chlorocarbonylation of Carbonyl Compounds
Orthoester-Dependent Alcoholysis of Lactones. Facile Preparation of 4-Alkoxybutanoates and 5-Alkoxypentanoates
Geometrical Isomerization and Restricted Rotation in Iminoxyl Radicals from Benzaldoximes
Andrimid and moiramides A-C, metabolites produced in culture by a marine isolate of the bacterium Pseudomonas fluorescens: structure elucidation and biosynthesis
A Novel Approach toward the Synthesis of Chiral 2,3-Dideoxy Nucleosides and Their Carbocyclic Analogs
Electrophilic Additions to 7-Methylenenorbornenes and 7-Isopropylidenenorbornenes: Can Remote Substituents Swamp Electrostatic Control of .pi.-face Selectivity?
Molybdenum(V)-Mediated Skeletal Rearrangement of an Organomercury Steroid. Stereoelectronic Control and Mechanism
Substituent Control of Biscarbene Electronic Configurations: m-Phenylenebis(chloromethylene)
Isomeric N-(Nitrenophenyl)nitrenobenzamides. Comparison of the Energy Differences between Their Singlet and Quintet States Obtained Computationally and Experimentally
Hydroboration. 90. Synthesis of 2-Isobutyl- and 2-Isopropylapopinenes. Rates and Stoichiometry of the Hydroboration of 2-Organylapopinenes with Borane-Methyl Sulfide and Borane-Tetrahydrofuran
Substituent Effects on Photochemical Hydrogen Abstraction in 2-Acylpyridines, 2-Acylpyrazines, and 4-Acylpyrimidines
Intramolecular Diels-Alder Reactions via Sulfone-Substituted 3-Sulfolenes
Kinetic Resolution of Pipecolic Acid Using Partially-Purified Lipase from Aspergillus niger
Conformational Analysis of the Sodium Channel Modulator, Brevetoxin A, Comparison with Brevetoxin B Conformations, and a Hypothesis about the Common Pharmacophore of the "Site 5" Toxins
Some Studies on the Uses of 2-Bromoethyl and 2-Iodoethyl Ester Blocking Groups in Peptide Synthesis: Samarium Diiodide-Mediated Deprotection
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