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The High-Temperature Gas-Phase Reactions of o-Allylbenzyl Radicals Generated by Flash Vacuum Pyrolysis of Bis(o-allylbenzyl) Oxalate
Associative and Dissociative Pathways in the Alkaline Hydrolysis of Aryl 2-Hydroxycinnamates
Dihydro- and Tetrahydrofuran Building Blocks from 1,4:3,6-Dianhydrohexitols. 2. Synthesis of Acetal, Alcohol, Diol, Epoxide, Hydrocarbon, and Lactone Pheromones
Direct Preparation of N-Quaternized and N-Oxidized Polycyclic Azines by Palladium-Catalyzed Cross-Coupling. An Unequivocal Isomer Synthesis
Reaction of Heteroaryl Thiols with Conjugated Azoalkenes: Regioselective Preparation of 4-(Heteroarylthio)-1H-pyrazol-5(2H)-ones. X-ray Crystal Structures of Methyl 2-((Pyrimid-2-yl)thio)acetoacetate (Aminocarbonyl)hydrazone and 1-(Aminocarbonyl)-3-methyl-4-((pyrimid-2-yl)thio)-1H-pyrazol-5(2H)-one
Stereoselectivity of Addition of Organometallic Reagents to Pentodialdo-1,4-furanoses: Synthesis of L-Axenose and D-Evermicose from a Common Intermediate
Thermal and Photochemistry of Perfluoro-1,6-heptadiene and the Perfluoro-1,3,6-heptatrienes
Regioselective Haller-Bauer Cleavage in Tricyclo[5.2.1.02,6]dec-8-ene-3,10-dione. A Total Synthesis of (.+-.)-Pumiliotoxin C
Equilibration of the Oxidative Addition Product of Tetrakis(triphenylphosphine)palladium and Electron-Rich Aryl Halides Leads to Product Scrambling in the Stille Reaction
Is Selective Monosubstitution of Dihalides via SRN1 Reaction Feasible? An Electrochemical Approach for Dichloroarenes
A Three Component Coupling Approach to a Chiral 1.beta.-Methylcarbapenem Key Intermediate
Syntheses of Two Stereoselectively Trideuterated Vinylcyclopropanes
Selective Arylation of Diols Using Arene-Iron Chemistry
Highly Diastereoselective Ortho Lithiations of Chiral Oxazoline-Substituted Ferrocenes
Enantioselective Synthesis of (+)-Cyclophellitol
Chiral Synthesis via Organoboranes. 40. Selective Reductions. 55. A Simple One-Pot Synthesis of the Enantiomers of Trifluoromethyloxirane. A General Synthesis in High Optical Purities of .alpha.-Trifluoromethyl Secondary Alcohols via the Ring-Cleavage Reactions of the Epoxide
Aryl Mesylates in Metal-Catalyzed Homocoupling and Cross-Coupling Reactions. 1. Functional Symmetrical Biaryls from Phenols via Nickel-Catalyzed Homocoupling of Their Mesylates
Restricted Nitrogen Inversion in N-Methylpolyhalobenz-7-azanorbornadienes. 1H Dynamic NMR Studies and Molecular Conformation Trapping
A Novel Heterocycle-Stabilized Homoenolate Anion and Its Applications in the Syntheses of .beta.-Propenoylcarboxylic Esters, Cyclopropanecarboxylic Esters, 1-Vinyl-1-ethoxy Epoxides, and .gamma.-Lactones
A Versatile Synthesis of Deferrioxamine B
Regiospecific and Stereospecific Palladium-Catalyzed Cycloaddition of Azetidines and Carbodiimides
Regioselectivity in [3 + 4] and [3 + 5] Annulation Reactions of Bis(trimethylsilyl) Enol Ethers with Acylsilane Dicarbonyl Dielectrophiles
Facile Palladium-Catalyzed Carbonylation of Triarylstibines in the Presence of Ammonium Cerium(IV) Nitrate
The Sonochemical Barbier Reaction Extended to Carboxylate Salts. An Easy Access to 2-Furanyl Ketones
Rapid Chemical Synthesis of Sugar Nucleotides in a Form Suitable for Enzymic Oligosaccharide Synthesis
A Chemoenzymic Approach to Hydroperoxyeicosatetraenoic Acids. Total Synthesis of 5(S)-HPETE
A New Glycosidation Procedure Utilizing Rare Earth Salts and Glycosyl Fluorides, with or without the Requirement of Lewis Acids
Novel Phosphonium Cations. 2. Electrophilic Chemistry of Tetraphosphacubane: Novel Monophosphonium Ions of Ethylation, Benzylation, Acylation, and Adamantylation, Di- and Triphosphonium Ions of Acylation/Alkylation and Alkylation/Protonation, and Monoprotonation of Tetraoxo- and Tetrathioxotetraphosphacubane
Soluble Catalysts for Improved Pschorr Cyclizations
A Simple, Convenient, and Efficient Method for the Synthesis of Isocyanates from Urethanes
Carbohydrate-Based Strategy for the Synthesis of Zaragozic Acid via a Novel Lewis Acid-Mediated Reaction of an .alpha.-Acetoxy Sulfide
A 2-Propanol Treatment Increases the Enantioselectivity of Candida rugosa Lipase toward Esters of Chiral Carboxylic Acids
Synthesis and Configurational Analysis of a Novel Class of Cavitands Containing Four Dioxaphosphocin Moieties
Conformational Assignment, Absolute Configuration, and Chiral Separation of All the Stereoisomers Created by the Combined Presence of Stereogenic Centers and Stereogenic Conformational Axes in a Highly Hindered 1,5-Naphthyl Sulfoxide
Ring-Opening Rearrangements of 2-(Benzotriazol-1-yl) Enamines and a Novel Synthesis of 2,4-Diarylquinazoline
Effects of Through-Bond Electron Donor-Acceptor Interaction on the Nitrogen Inversion Potential in Piperidine Derivatives. A Quantum-Chemical Study
Total Synthesis of (-)-Cephalotaxine
Inhibition of Rearrangements in Stannane-Mediated Radical Reduction Reactions by Catalytic Quantities of Diphenyl Diselenide. An Example of Polarity Reversal Catalysis
Oxonium ion-initiated pinacolic ring expansion reactions. Application to the enantioselective synthesis of the spirocyclic sesquiterpene ethers dactyloxene-B and -C
Fluorination of (E)-.beta.-(Fluoromethylene)-m-Tyrosine: Regioselective Synthesis of 4-Fluoro-(E)-.beta.-(Fluoromethylene)-m-Tyrosine
Elimination of the 7-Trifluoromethyl Group from 6,7-Bis(trifluoromethyl)-8-ribityllumazines. Stereoselective Catalysis by the Lumazine Synthase of Bacillus subtilis
Asymmetric Synthesis of 1-Deoxy-8,8a-di-epi-castanospermine
Synthesis, Molecular Structure, and Spectroscopical Properties of Alkenylphosphonic Derivatives. 1. Vinyl-, Propenyl-, (Bromoalkenyl)-, and (Cyanoalkenyl)phosphonic Compounds
A Practical and Divergent Way to Trihydroxylated Pyrrolidine Derivatives as Potential Glycosidase Inhibitors via Stereoselective Intermolecular cis-Amidoalkylations
Studies Directed toward the Enantiospecific Synthesis of Gardneria, Voacanga, and Alstonia Oxindole Alkaloids
New Synthon for the Convergent Construction of Skipped Conjugation Polyenes: Synthesis of Ethyl Docosa-4,7,10,13,16,19-hexaenoate
Hydroesterification of Olefins Catalyzed by Pd(OAc)2 Immobilized on Montmorillonite
Homogeneous Sonochemistry: A Study of the Induced Isomerization of 1,2-Dichloroethene under Ultrasonic Irradiation
A Tandem Cyclization-Onium Ylide Rearrangement-Cycloaddition Sequence for the Synthesis of Benzo-Substituted Cyclopentenones
Regioselective Conversions of 1-Phenyl-Substituted Acetylenes to .alpha.,.alpha.-Difluoro Ketones with "F-TEDA-BF4"
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Conformational analysis of the 10- and 13-hydroxy derivatives of cembrene
Stereoselectivity in the Wittig Reaction of Aromatic Ketones: Origin of Preference for the Olefin Geometry
Restricted Rotation and NOE Transfer: A Conformational Study of Some Substituted (9-Anthryl)carbinol Derivatives
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