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Transformations of Quinic Acid. Asymmetric Synthesis and Absolute Configuration of Mycosporin I and Mycosporin-gly
A Computational Study of the Thermal Cycloreversion of 2,2,6-Trimethyl-4H-1,3-dioxin-4-one and a Related Species: Retro-Diels-Alder Reaction or Concerted Nucleophilic Attack?
Palladium-Catalyzed Stereoselective Allylaminocyclization and 1,3-Butadien-2-ylaminocyclization of Allenyl Tosylcarbamates
MM2 Calculations on Cyclodextrins:Multimodal Inclusion Complexes
Sequential Homoaldolization. Cuprate Rearrangement in a Stereoselective Synthesis of Stannyl Dienes: Application to the Synthesis of the Western C10-C15 Subunit of (.+-.)-Tylosin Aglycon
Decomposition of N-Phosphorylated Nitrogen Mustards: A Mechanistic Investigation
Efficient Preparation of the .alpha.,.alpha.,.beta.,.beta.-Atropoisomer of meso-Tetrakis(o-aminophenyl)porphyrin
Epoxidation of Primary and Secondary Alkenylammonium Salts with Dimethyldioxirane, Methyl(trifluoromethyl)dioxirane, and m-Chloroperbenzoic Acid. A General Synthetic Route to Epoxyalkylamines
Functionalization of 2-Phenylsulfonyl 1,3-Dienes via Cyclopropanation and Epoxidation. Synthesis of Oxabicyclic Systems via BF3-Induced Rearrangement of Epoxide Derivatives
Neurosteroid Analogs. 2. Total Synthesis and Electrophysiological Evaluation of Benz[e]indene Analogs of the Anesthetic Steroid Alphaxalone
N,N'-Bis(2,2,2-trifluoroethyl)-N,N'-ethylenetartramide: An Improved Chiral Auxiliary for the Asymmetric Allylboration Reaction
Internal Oxidosqualenes: Determination of Absolute Configuration and Activity as Inhibitors of Purified Pig Liver Squalene Epoxidase
Serial Radical Cyclization of Pyranose-Derived Dienes in the Stereocontrolled Synthesis of Woodward's Reserpine Precursor
Enantioselective Total Syntheses of the Nitraria Alkaloids (-)-Nitramine and (+)-Isonitramine
Topologically Controlled Coulombic Interactions, a New Tool in the Developing of Novel Reactivity. Photochemical and Electrochemical Cleavage of Phenyl Alkyl Ethers
Epoxidation of Olefins Using Methyl(trifluoromethyl)dioxirane Generated in Situ
Regioselective Transformation of Malic Acid: A Practical Method for the Construction of Enantiomerically Pure Indolizidines
A Mild Preparation of Protected Phosphate Esters From Alcohols
A General and Facile Synthesis of Heterocyclo[b]-Fused Carbazoles
Asymmetric Functionalization of Chromium Carbene-Derived Optically Active 4,4-Disubstituted Butenolides
Dynamics of the Photochemical Debromination of Silicon-Substituted Vicinal Dibromides
Aldotetroses and C(3)-Modified Aldohexoses as Substrates for N-Acetylneuraminic Acid Aldolase: A Model for the Explanation of the Normal and the Inversed Stereoselectivity
Regioselective Annulation of 5-(1-Alkenyl)- and 5-Vinyl-1,3-benzodioxoles with 3-Chloro-3-cyclobutene-1,2-dione. Synthesis of 3,4-Dihydrocyclobuta[5,6]- naphtho[2,3-d][1,3]dioxole-1,2-diones and Cyclobuta[6,7]naphtho[2,3-d][1,3]dioxole- 1,2-diones
A Novel Approach to the Synthesis of Some Chemically-Modified Cyclodextrins
Reduction of 5-(Trifluoromethyl)isoxazoles with Lithium Aluminum Hydride: Synthesis of (2,2,2-Trifluoroethyl)aziridines
A General Strategy for the Synthesis of Cis-Substituted Pyrrolizidine Bases. The Synthesis of (-)-Rosmarinecine
Synthesis of Thrombin Inhibitor DuP 714
Serial Radical Reactions of Glycals: Ready Routes to Highly Functionalized C-Glycosyl Derivatives
Limonoid Model Insect Antifeedants. A Stereoselective Synthesis of Azadiradione C, D, and E Fragments through Intramolecular Diazo Ketone Cyclization
A Complete Set of 2A,6X-Di-O-diactivated .alpha.-Cyclodextrins
The Total Synthesis of (.+-.)-Scopadulcic Acids A and B and (.+-.)-Scopadulciol
(Z)-(E) Interconversion of Olefins by the Addition-Elimination Sequence of the (TMS)3Si.bul. Radical
Lewis Acid-Enhanced Reactivity of .alpha.,.beta.-Unsaturated Esters and Amides toward Radical Addition
New Synthetic Routes to 3-, 5-, and 6-Aryl-2-chloropyridines
1,2-Asymmetric Induction in the Zwitterionic Claisen Rearrangement of Allylamines
Products from the Acid-Catalyzed Reaction of Cyclic Monoterpenes and Phenol
First Synthesis of Fully Deprotected Diimidotriphosphoric Acid and Derivatives Designed for the Synthesis of "PNPNP" Nucleotides and Dinucleotides
Closed-Shell vs. Diradical States of Bis(methylene)phosphorane. Is the Phosphirane-Bis(methylene)phosphorane Interconversion a Pericyclic Reaction? A Theoretical Study
A PM3 and MNDO Study on the Mechanism and the Regioselectivity of the Lithiation of Lithium Methyl-1- and Methyl-2-naphthylcarbamate, Lithium 1,2,3,4-Tetrahydroisoquinolinecarbamate and Toluene
Intramolecular 1,4-Dipolar Cycloadditions of Cross-Conjugated Heteroaromatic Betaines. Synthesis of Hexahydrojulolidines and Related Peri- and Ortho-Fused Ring Systems
Dual Reactivity of the Formyl Cation as an Electrophile and a Broensted Acid in Superacids
Masthead
Lewis Acid-Promoted Reactions of Unsymmetrically Substituted Stilbenes with 2-Methoxy-1,4-benzoquinones: Stereoselective Synthesis of trans-2,3-Diaryl-2,3-dihydrobenzofurans
Synthesis of Isocoumarins from o-Iodobenzoic Acid and Terminal Acetylenes Mediated by Palladium Complexes and Zinc Chloride
The Diastereoselective Synthesis of Ester-Functionalized Alkenes through the Stereocontrolled Conjugate Addition (Michael Reaction) of Prochiral Enolates to Chiral .alpha.-Methylene .beta.-Lactones and Thermal Decarboxylation of the Resulting .alpha.-Substituted .beta.-Lactones
Convenient Syntheses of Bifunctional Metal Chelates
(2,4,6-Triisopropylphenyl)selenium Bromide (TIPPSe-Br). An in Situ-Generated Reagent for Effecting Highly Selective Ring Closures of Homoallylic Alcohols to Substituted Tetrahydrofurans
Preparation and Characterization of a Bis-Semiquinone: a Bidentate Dianion Biradical
Synthesis of C-Alkyl Calix[4]arenes. 3. Acid-Catalyzed Rearrangement of 2,6-Dimethoxycinnamate Prior to Tetramerization to Calix[4]arenes
Ferrier Rearrangement under Nonacidic Conditions Based on Iodonium-Induced Rearrangements of Allylic n-Pentenyl Esters, n-Pentenyl Glycosides, and Phenyl Thioglycosides
Lawesson's Reagent: An Efficient 1,3-Dipole Trapping Agent
A Concise, Practical Synthesis of the Pyrido[3,2,1-i,j]Cinnoline Ring System of Potent DNA Gyrase Inhibitors
Regioselective Enzyme-Mediated Acylation of Polyhydroxy Natural Compounds. A Remarkable, Highly Efficient Preparation of 6'-Acetyl and 6'-O-Carboxyacetyl Ginsenoside Rg1
Seven More Microcystins from Homer Lake Cells: Application of the General Method for Structure Assignment of Peptides Containing .alpha.,.beta.-Dehydroamino Acid Unit(s)
Cycloadditions. 53. Stereoselective Synthesis of Functionalized Pyrrolidines via Intramolecular 1,3-Dipolar Silyl Nitronate Cycloaddition
Rate Enhancement in Dilute Salt Solutions of Aqueous Ethanol: The Diels-Alder Reaction
Diazines 13: Metalation without Ortho-Directing Group - Functionalization of Diazines via Direct Metalation
First Preparation of Optically Pure Ketals of p-Benzoquinone
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