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Diastereoselective Diels-Alder Reactions via Cyclic Vinyloxocarbenium Ions
Reduction of 2-Acylaziridines by Samarium(II) Iodide. An Efficient and Regioselective Route to .beta.-Amino Ketones and Esters
Phosphatase Catalysis Developed via Combinatorial Organic Chemistry
Enzymic Resolution of a C2 Symmetric Diol Derived from p-Benzoquinone: Synthesis of (+)- and (-)-Bromoxone
On the Mechanism of Ti-TADDOLate-Catalyzed Asymmetric Diels-Alder Reactions
Hydrocarbons with Carbon Frameworks Represented on the Buckminsterfullerene Surface: Indeno[7,7a,1,2,3-lmno]-1,12-ethenochrysene
Electrostatic vs Hyperconjugative Effects as Stereoinductive Factors in the Adamantane Ring System. [Erratum to document cited in CA121:133430]
Nucleophilic Cleavage Products from .beta.-Deprotonated Sesquidiazabicyclooctane Dication
Practical and Enantiospecific Synthesis of LY303870, a Novel NK-1 Antagonist
Asymmetric Pauson-Khand Cyclization: A Formal Total Synthesis of Natural Brefeldin A
A One-Step Ring Transformation/Ring Annulation Approach to Pyrrolo[2,3-d]pyrimidines. A New Synthesis of the Potent Dihydrofolate Reductase Inhibitor TNP-351
A Highly Enantiocontrolled Strategy for the Synthesis of Benzylic Quaternary Carbon Centers. A Formal Total Synthesis of (-)-Mesembrine
Assignment of the Absolute Configuration of Natural Lentiginosine by Synthesis and Enzymic Assays of Optically Pure (+) and (-)-Enantiomers
[2,3-13C2]-4-Hydroxy-L-threonine
Enantio- and Diastereoselective Aldol-Addition of Chiral Boron Enolates of Carboxylic Acids to Benzaldehyde
Catalytic Asymmetric Synthesis of .alpha.-Amino Phosphonates Using Lanthanoid-Potassium-BINOL Complexes
Transformation of Cycloolefins into .alpha.-Ethoxysulfo-Substituted Ketones via SO3-Mediated Nitrosation
The Quest for a Planar and Pyramidal Carbon Atom. 3. Can a Tetrahedrally Coordinated Carbon Form a Nearly Linear C-C-C Bond Angle?
Bradsher Cycloaddition of 4-Alkoxyisoquinolinium Salts as a Route to a Fully Functionalized B Ring of the Angucycline Antibiotics
Synthesis and Structures of Tricyclic Diureas
Thermally Induced Endo/Exo Isomerization of Polyimides. An AM1 Study Using Nadimide as a Model for the Reactive End-Caps of PMR Prepolymers
Substituent Effects of -NO and -NO2, Groups in Aromatic Systems
New synthetic applications of water-soluble acetate Pd/TPPTS catalyst generated in Situ. evidence for a true Pd(0) species intermediate
Synthesis of Monoprotected 2-Alkylidene-1,3-propanediols by an Unusual SN2' Mitsunobu Reaction
A Simple Synthesis of Supercryptands
Intramolecular Photoaddition of Alkenes to Chiral 1,3-Dioxin-4-ones: Evidence for Effect of Pyramidalization on the Facial Selectivity
A Highly Convergent Synthesis of the Tetragalactose Moiety of the GPI Anchor of the VSG of Trypanosoma brucei
t-BuOK-Induced Cleavage of Dihydrofuran Derivatives: Synthesis of .beta.-(Diethoxyphosphinyl)-.beta.,.gamma.-unsaturated Ketones
Nucleic Acid Related Compounds. 87. Nucleophilic Functionalization of Cytidine and 2'-Deoxycytidine Derivatives via Elaboration of the 4-Amino Group into a Readily Displaced 1,2,4-Triazol-4-yl Substituent
Diastereoselective Synthesis of Substituted Glutamic Acid Derivatives via Michael Additions of N-[Bis(methylthio)methylene]glycinates under Solid-Liquid Phase Transfer Catalysis
Synthesis of .gamma.-(Electron-withdrawing group)-Substituted .alpha.,.alpha.-Difluoro Ketones by UV-Initiated Addition of Iododifluoromethyl Ketones with Electron-Deficient Alkenes
Aryl Mesylates in Metal Catalyzed Homo- and Cross-Coupling Reactions. 4. Scope and Limitations of Aryl Mesylates in Nickel Catalyzed Cross-Coupling Reactions
A Simple One-Step Conversion of Carboxylic Acids to Esters Using EEDQ
Synthetic Studies of the Angucycline Antibiotics. Stereocontrolled Assembly of the SF 2315B Ring System
Pseudodistomin C, a new piperidine alkaloid with unusual absolute configuration from the Okinawan tunicate Pseudodistoma kanoko
Development of a New Family of Thiol Specific Photoactivatable Crosslinking Agents
Stereocontrolled Synthesis of DTPA Analogs Branched in the Ethylene Unit
Phenylpyrroles by Suzuki Cross Coupling and a Synthesis of Type I Tetramethyltetraphenylporphyrin
Regioselective Synthesis of Allylic Alcohols Using the Mislow-Evans Rearrangement: A Theoretical Rationalization
Strain-Free Transition States in the Formation of Strained Rings: An ab Initio Study of Thiirane, Thietan, and Tetrahydrothiophene
Stereospecific Amination by Dynamic Kinetic Resolution Utilizing 2-Oxoimidazolidine-4-carboxylate as a Novel Chiral Auxiliary
Synthesis of .beta.-Methoxy, Methyl-Capped .alpha.-Oligothiophenes
One-Pot Base-Promoted Tandem Michael Addition-Intramolecular Aldolization. Stereoselective Synthesis and Reactivity of 2-Hydroxybicyclo[3.2.1]octan-8-ones
Mechanism-based inactivation of ribonuclease A
Synthesis of Oligo(Deoxyribonucleoside Phosphorodithioate)s by the Dithiaphospholane Approach
A Rapid Synthesis of Pyranoid Glycals from Glycosyl Bromides
Ring Closure Reactions of Substituted 4-Pentenyl-1-oxy Radicals. The Stereoselective Synthesis of Functionalized Disubstituted Tetrahydrofurans
Diallyl (Lithiodifluoromethyl)phosphonate: A New Reagent for the Introduction of the (Difluoromethylene)phosphonate Functionality
Syntheses, Structures, and Enzymic Evaluations of Conformationally Constrained, Analog Inhibitors of Carnitine Acetyltransferase: (2R,6R)-, (2S,6S)-, (2R,6S)-, and (2S,6R)-6-(Carboxylatomethyl)-2-(hydroxymethyl)-2,4,4-trimethylmorpholinium
Synthetic Studies on Quinocarcin: Total Synthesis of (.+-.)-Quinocarcinamide via Dipole Cycloaddition of an Azomethine Ylide Generated by NBS Oxidation
Asymmetric Synthesis of (R)-(+)-.beta.-Phenylalanine from (S)-(+)-Benzylidene-p-toluenesulfinamide. Regeneration of the Sulfinimine Precursor
Preparation of .alpha.-Alkoxy Amides and .alpha.-Hydrazino Amides by Base-Promoted Reactions of N-Sulfonyloxy Amides
Allylic Metalation of Endo- and Exo-Cyclic Alkenes: Anomalous High Reactivity of .beta.-Pinene
A New Synthesis of .alpha.-Asymmetric Nitroxide Radicals
Studies Directed toward the Total Synthesis of Kalmanol. An Approach to Construction of the C/D Diquinane Substructure
Synthesis of Positron Labeled Photoactive Compounds: 18F Labeled Aryl Azides for Positron Labeling of Biochemical Molecules
Novel Approach to Lactams via (Triisopropylsilyl)azidohydrin Formation and Photoinduced Schmidt Rearrangement
Glycosylation of 2,2'-Indolylindolines
Facile Conversion of Succinic to Maleic-Type Anhydrides, Thioanhydrides, and Imides
Emmottene, from the gorgonian Briareum polyanthes, contains the first naturally occurring trans-bicyclo[5.1.0]octane
Preparation and Reactivity of Allyl N-[(Arylsulfonyl)oxy]carbamates, New Reagents for Electrophilic Transfer of an NHAlloc Group
A Novel Synthesis of 2-Aryllactic Acids via Electrocarboxylation of Methyl Aryl Ketones. [Erratum to document cited in CA122:132695]
Masthead
Optimization of Enantiocontrol for Carbon-Hydrogen Insertion with Chiral Dirhodium(II) Carboxamidates. Synthesis of Natural Dibenzylbutyrolactone Lignans from 3-Aryl-1-propyl Diazoacetates in High Optical Purity
Electrolytic Oxidation of Ketones in Ammoniacal Methanol in the Presence of Catalytic Amounts of KI
Photochemistry of 1-alkoxy- and 1-(benzyloxy)-9,10-anthraquinones in methanol: A facile process for the preparation of aldehydes and ketones
Isolation, Structure Elucidation, and Synthesis of Irlbacholine, 1,22-Bis[[[2-(trimethylammonium)ethoxy]phosphinyl]oxy]docosane: A Novel Antifungal Plant Metabolite from Irlbachia alata and Anthocleista djalonensis
Reactions of Fervenulone. An Unprecedented Ring Contraction of a 7-Azapteridine Ring System
Preparation of 3-Thienylzinc and -magnesium Halide via Oxidative Addition of Active Zinc and Magnesium to 3-Iodothiophene
Selective Binding of Diamines to a Chiral Lewis Acid with Two Boron Centers
Enantiopreference of Lipase from Pseudomonas cepacia toward Primary Alcohols
Michael Additions of .alpha.-Sulfinyl and .alpha.-Sulfonyl Carbanions: The Unprecedented Reaction of .beta.-Keto Sulfoxides and .beta.-Keto Sulfones with Highly Stabilized Michael Acceptors
High Diastereoselective Synthesis of Threo or Erythro Aminoalkyl Epoxides from .alpha.-Amino Acids
Matrix Isolation and ab Initio Molecular Orbital Study of Fluorocyclopropenone and Fluoro(ketenyl)carbene
Synthesis of Macrocyclic Oligomers of Pivalolactone. Crystal Structure and Properties of Tetrolide
Catalytic, Enantioselective Aldol Reaction with an Artificial Aldolase Assembled from a Primary Amine and an Antibody
A Kinetic Study on the Reactivity of a cis-Dioxoruthenium(VI) Complex. Oxidation of Alcohols, Aromatic Hydrocarbons, and Alkenes by cis-[RuVI(Tet-Me6)O2]2+
Biosynthesis of the Hypotensive Metabolite Oudenone by Oudemansiella radicata. 1. Intact Incorporation of a Tetraketide Chain Elongation Intermediate
Novel Macrocycles Incorporating Cyclic Urea Units
Sonochemical and Triethylborane-Induced Tin Deuteride Reduction for the Highly Diastereoselective Synthesis of (2'R)-2'-Deoxy[2'-2H]ribonucleoside Derivatives
Oteromycin: A Novel Antagonist of Endothelin Receptor
A New 5-Formylbilinone as the Major Chlorophyll a Catabolite in Tree Senescent Leaves
gem-Dialkoxy Effect in Radical Cyclizations To Form Cyclopropane Derivatives: Unusual Oxidation of a Dialkoxyalkyl Radical
Synthesis of a Novel N-Hydroxypyrrole via Lithium Perchlorate Accelerated Diels-Alder Methodology. [Erratum to document cited in CA123:143573]
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