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Dimethoxybenzoin Carbonates: Photochemically-Removable Alcohol Protecting Groups Suitable for Phosphoramidite-Based DNA Synthesis
An Asymmetric Carceplex and New Crystal Structure Yield Information Regarding a 1 Million-Fold Template Effect
An Efficient Synthesis of 1,2,9,9a-Tetrahydrocyclopropa[c]benz[e]indol-4-one CBI: An Enhanced and Simplified Analog of the CC-1065 and Duocarmycin Alkylation Subunits
Sensitized Photooxygenation of 6-Heteroatom-Substituted Fulvenes: Primary Products and Their Chemical Transformations
Mechanism of Palladium-Catalyzed Transfer Hydrogenolysis of Aryl Chlorides by Formate Salts
Catalytic Epoxidation of Alkenes with Oxone
Direct Regioselective Formylation of Tetraalkoxycalix[4]arenes Fixed in the Cone Conformation and Synthesis of New Cavitands
2-Substituted 2,3-Dihydro-4H-1,3-benzoxazin-4-ones: A Novel Auxiliary for Stereoselective Synthesis of 1-.beta.-Methylcarbapenems
Direct Total Syntheses of Frenolicin B and Kalafungin via Highly Regioselective Diels-Alder Reactions
Unsymmetrical Ketone Synthesis via a Three-Component Connection Reaction of Organozincs, Allylating Agents, and Carbon Monoxide
Carbanion or Enolate? A 1H, 13C, and 29Si NMR Spectroscopic Analysis
General and Efficient Method for the Solution- and Solid-Phase Synthesis of Vancomycin Carboxamide Derivatives
.alpha.-Bromo Carbonyl Compounds as Promoters for the Synthesis of (2-Bromoethyl)benzene by the Anti-Markovnikov Addition of Hydrogen Bromide to Styrene
Palladium-Templated Regio- and Stereoselective Cyclization of 2'-Alkenyl 2-Alkynoates and Its Synthetic Applications
Unusual Ring-Opening Reaction of 6,7-Dihydrothieno[3,2-d]pyrimidine-2,4-dione Derivatives Leading to 5-(Alkylthio)-6-vinyluracils
Epitaondiol: The First Polycyclic Meroditerpenoid Containing Two Fused Six-Membered Rings Forced into the Twist-Boat Conformation
Efficient 1,2-Asymmetric Induction in Radical Reactions: Stereoselective Radical Addition to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes
Stereocontrolled Syntheses of Diequatorial and Axial-Equatorial Furofuran Lignans
On the Mechanism of Buffer-Catalyzed Hydrolysis of RNA Models
Asymmetric Synthesis of the Volatile Anesthetic 1,2,2,2-Tetrafluoroethyl Chlorofluoromethyl Ether Using a Stereospecific Decarboxylation of Unusual Stereochemical Outcome
Tetrahydropyran Ring-Opening Reactions Promoted by SmI2
Diastereoselectivity in the Michael-Type Addition of Imines Reacting as Their Secondary Enamine Tautomers
Oxidation of Fully Protected Glycals by Hypervalent Iodine Reagents
Suitability of the Claisen ring expansion protocol for crenulide diterpene construction
Calix[4]arenes Blocked in a Rigid Cone Conformation by Selective Functionalization at the Lower Rim
Novel Alkaloids from the Sponge Batzella sp.: Inhibitors of HIV gp120-Human CD4 Binding
Structure and Reactivity of Free Arylium Ions. 2. Reactions of Decay-Formed Isomeric XC6H4+ Ions with Gaseous and Liquid Nucleophiles
Unusual Cycloaddition Reactions of Substituted-N-(arylsulfonyl)aziridines with Aryl and Alkyl Isothiocyanates in the Presence of Sodium Iodide as Catalyst
Synthesis of 3-Hydroxy-3-cyclobutene-1,2-dione Based Amino Acids
Cyclooligomeric Receptors Based on Trimesic Acid and 1,2-Diamines. Minimal Structure for Sequence-Selective Peptide Binding
Synthesis of Cyclic Acylated Enamino Esters from Enol Lactones, 4-Keto amides, and 5-Hydroxy Lactams
Highly Selective Formation of a .beta.-C-Glucosidic Bond in the Reactions of ArSCl-Glucal Adducts with Silicon-Containing Nucleophiles
A New Synthetic Method of Preparing Iodohydrin and Bromohydrin Derivatives through in Situ Generation of Hypohalous Acids from H5IO6 and NaBrO3 in the Presence of NaHSO3 [Erratum to document cited in CA122:55327]
Bis(sulfonyl) Ketones: A New Oxyallyl Cation Source
Free Radical Approach to Directed Aldol-Type Reactions Promoted by Allylic O-Stannyl Ketyls
Solvent Dependence of Enantioselectivity for a Base-Catalyzed 1,3-Hydron Transfer Reaction. A Kinetic Isotope Effect and NMR Spectroscopic Study
Reactions of 4-Substituted 1,1-Dimethylsemicarbazides and -thiosemicarbazides with Ethyl Bromoacetate
Polyols of a Cascade Type as a Water-Solubilizing Element of Carborane Derivatives for Boron Neutron Capture Therapy. [Erratum to document cited in CA116:40863]
Chiral Lewis Acid-Controlled Synthesis of Both Diastereomers. Enantioselective Synthesis of Both syn- and anti-2,3-Dihydroxy Ester Derivatives from the Same Starting Materials via Asymmetric Aldol Reactions by Choice of Chiral Ligands
Synthesis of 13-Acetoxy-13-demethylretinal, Its Pigment Formation with Bacteriopsin, and Apparent Dark-Inactivating Effect on the Pigment
Enantiomerically Enriched .alpha.-Methyl Amino Acids. Use of an Acyclic, Chiral Alanine-Derived Dianion with a High Diastereofacial Bias
Synthesis of Substituted 2,3,5,6-Tetraarylbenzo[1,2-b:4,5-b']difurans
Inside-outside stereoisomerism. VII. Methodology for the Synthesis of 3-Oxygenated Ingenanes. The First Ingenol Analogs with High Affinity for Protein Kinase C
Reactivities of Nitrenes Generated by Photolysis of 2-(.omega.-Phenylalkyl)phenyl Azides
Use of Thiazyl Chlorides, Alkyl Carbamates, and Thionyl Chloride To Fuse 1,2,5-Thiadiazoles to Quinones and To Oxidize, Chlorinate, and Aminate Them
Chloriolins A-C, Chlorinated Sesquiterpenes Produced by Fungal Cultures Separated from a Jaspis Marine Sponge. [Erratum to document cited in CA121:250796]
Enantioselective Synthesis of 2,3-Disubstituted Succinic Acids by Oxidative Homocoupling of Optically Active 3-Acyl-2-oxazolidones
Daphniphyllum Alkaloids. 17. A Possibly Biomimetic Transformation of the Secodaphnane to the Daphnane Skeleton
Synthetic Studies toward Mono-THF Annonaceous Acetogenins: A Diastereoselective and Convergent Approach to Corossolone and (10RS)-Corossoline
Syntheses of High Specific Activity 2,3- and 3,4-[3H]2-9-cis-Retinoic Acid
Sulfur-Directed Regioselective Radical Cyclization Leading to .beta.-Lactams: Formal Synthesis of (.+-.)-PS-5 and (+)-Thienamycin
1,1-Dimethylsila-, -germa-, and -stannacycloheptatrienes Fully Annelated with Bicyclo[2.2.2]octene: Syntheses, Structures, and Properties
Use of Hydrogen Bonds to Control Molecular Aggregation. Behavior of Dipyridones and Pyridone-Pyrimidones Designed To Form Cyclic Triplexes
Secosyrins 1 and 2 and syributins 1 and 2: novel structures produced by bacteria expressing the avrD gene
Directed Metalation of Diaryl Sulfone 2-Amides and 2-O-Carbamates. Regiospecific General Route to Thioxanthen-9-one 10,10-Dioxides via Anionic Friedel-Crafts and Remote Fries Rearrangement Equivalents. [Erratum to document cited in CA122:9823]
Daphniphyllum Alkaloids. 16. Total Synthesis of (+)-Codaphniphylline
Theonellamides A-E, cytotoxic bicyclic peptides, from a marine sponge Theonella sp.
Study of the Orientation of Lithiation of 1- and 2-Alkylbenzotriazoles
Asymmetric dihydroxylation of a meso-symmetric cyclic diene using AD-mix reagents: a new enantiocontrolled route to conduritol E. [Erratum to document cited in CA120:134996]
Masthead
Total Synthesis of (-)-Ilimaquinone
Asymmetric Synthesis of the Key Intermediates Leading to (-)-Aphanorphine and (-)-Eptazocine
Kinetics and Mechanism of Oxidation of Anilines by Hydrogen Peroxide As Catalyzed by Methylrhenium Trioxide
An Efficient and Simple Thallium(III)-Induced Cleavage of the Hydrazino Moiety
C-Glycoside Syntheses. 3. Diastereo-diversified C-Glycosides from D-Glucose
Generation, Detection, and Reaction of Ammonium Ylides in Reactions of [2-[(Dimethylamino)alkyl]phenyl]phenylcarbenes
Equilibrium Lithium Ion Pair Acidities of 2-Phenyl-1,3-dithiane and 2-p-Biphenylyl-1,3-dithiane: A New Approach
Studies on the Degradation of Mevinolin and Compactin: A Formal Route to Semisynthetic Analogs
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