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Radically Initiated Asymmetric Cyclizations as Model Reactionsfor Asymmetric Cyclocopolymerizations
A New Photoannulation Reaction of2-Aryl-3-alkoxy-1,4-naphthquinones.Synthesis of Dimethylnaphthgeranine E
Synthesis and Diatropicity oftrans-N-Cyclohexyl-2‘,5‘,10b,10c-tetramethyl-pyrrolo[3,4-e]-10b,10c-dihydropyrene. TheFirst Example of anIso[17]annulenopyrrole
Generation and Cyclization of Acyl Radicals from Thiol EstersUnder Nonreducing, Tin-Free Conditions
Lithium 2,2,6,6-Tetramethylpiperidide and Lithium2,2,4,6,6-Pentamethylpiperidide: Influence of TMEDA and RelatedChelating Ligands on the Solution Structures. Characterizationof Higher Cyclic Oligomers, Cyclic Dimers, Open Dimers, andMonomers
Synthesis and Chemistry of Quinone Methide Models for theAnthracycline Antitumor Antibiotics
Isolation and Structure Elucidation of Transient (Colored)Complexes of Arenediazonium with Aromatic Hydrocarbons asIntermediates in Arylations and Azo Couplings
Proton Transfers from ZCH3 to ZCH2- (Z = F, Cl, Br, OH, SH, SeH).An ab Initio Investigation
Room Temperature Catalytic Amination ofAryl Iodides
Cyclodextrin Inclusion Complexes. Molecular MechanicsCalculations on the Modification of π-Face Selectivity
Alignment Effects in High Field Proton NMR Spectra of theHydrogenated Fullerenes C60H2 and C60H4: Evidence for ResidualAnisotropic Dipole−Dipole Couplings
Stereoselective Diels−Alder Reactions ofHexachlorocyclopentadiene with Chiral Alkenes: New InsightsInto the “Inside-Alkoxy” Model of Stereoselectivity
Polymer-Supported Oligosaccharides vian-Pentenyl Glycosides: Methodology for aCarbohydrate Library,1
Cubylcarbinyl Cation: Fact or Fiction?
Cycloadditions of Ketenes Generated in the Wolff Rearrangement.Stereoselective Synthesis of Aminoalkyl-Substituted β-Lactamsfrom α-Amino Acids
A New Thermally Generated BiradicalCapable of Intermolecular Hydrogen AtomAbstraction
Palladium-Catalyzed Synthesis of Indoles by ReductiveN-Heteroannulation of 2-Nitrostyrenes
Base-Promoted Solid-Phase Synthesis ofSubstituted Hydantoins andThiohydantoins
Synthesis and Evaluation of CC-1065 and Duocarmycin AnalogsIncorporating the1,2,3,4,11,11a-Hexahydrocyclopropa[c]naphtho[2,1-b]azepin-6-one(CNA) Alkylation Subunit: Structural Features that GovernReactivity and Reaction Regioselectivity
Carbohydrate Phosphinites as Practical Ligands in AsymmetricCatalysis: Electronic Effects and Dependence of BackboneChirality in Rh-Catalyzed Asymmetric Hydrogenations. Synthesisof R- or S-Amino Acids Using Natural Sugars as Ligand Precursors
Stereoselective Synthesis ofC-Amino-Substituted d-Mannopyranosides.Easy Preparation of Novel Inhibitors forMannosidases
Visible Light Initiated Photosensitized Electron TransferCyclizations of Aldehydes and Ketones to Tetheredα,β-Unsaturated Esters: Stereoselective Synthesis of OpticallyPure C-Furanosides
Medium-Ring Systems. 6. Synthesis and Isomerizations ofMedium-Ring 3-Methylenecycloalkanones and3-Methylcycloalkenones
Utility of Complementary Molecular Reactivity and MolecularRecognition (CMR/R) Technology and Polymer-SupportedReagents in the Solution-Phase Synthesis of HeterocyclicCarboxamides
Charge Delocalization Pathways in Persistent 1-Pyrenyl-,4-Pyrenyl-, and 2-Pyrenylmethylcarbenium Ions as Models ofPAH−Epoxide Ring Opening: NMR Studies in Superacids andAM1 Calculations
A Reinvestigation of the Structure of theTransition State in Peracid Epoxidations.α- and β-Secondary Isotope Effects
Synthesis and Properties of the First Highly ConjugatedTetrathiafulvalene Analogues Covalently Attached to[60]Fullerene
Dynamic Kinetic Resolution Utilizing2-Oxoimidazolidine-4-carboxylate as a Chiral Auxiliary: Stereoselective Alkylation of α-Bromo Amides with Malonic EsterEnolates
Solvolyses of 2-Oxo Bridgehead Compounds: A CriticalExamination of π-Conjugative Stabilization of α-CarbonylCarbocations
A Novel Ring-Enlargement Reaction of(3-Oxa-2-silacyclopentyl)methyl Radicalsinto 4-Oxa-3-silacyclohexyl Radicals.Stereoselective Introduction of aHydroxyethyl Group via Unusual6-Endo-Cyclization Products Derived from3-Oxa-4-silahexenyl Radicals and ItsApplication to the Synthesis of a4‘-α-Branched Nucleoside1
AsymmetricSynthesis of the Volatile Anesthetic 1,2,2,2-TetrafluoroethylChlorofluoromethyl Ether Using a Stereospecific Decarboxylationof Unusual Stereochemical Outcome
Properties of Some Condensed Aromatic Systems
Palladium-Catalyzed Cyclocarbonylation of Terminal and InternalAlkynols to 2(5H)-Furanones
A Convenient Procedure for thePreparation of CamphorsulfonylOxaziridines
Tandem Aldol−Tishchenko Reactions ofLithium Enolates: A Highly StereoselectiveMethod for Diol and Triol Synthesis
Thermal Decomposition ofPentacarbonyl(1-acyloxyalkylidene)chromium(0) Complexes: Formation of Z-Enol Esters
Kinetics of the pH-Independent Hydrolysis ofBis(2,4-dinitrophenyl) Carbonate in Acetonitrile−Water Mixtures: Effects of the Structure of the Solvent
4,5-Cyclopropanocholestan-3β-ol Substrates for CholesterolOxidase and Their 1H NMR Assignments
Synthesis, Physicochemical Properties, and Amine-OxidationReaction of Indolequinone Derivatives as Model Compounds ofNovel Organic Cofactor TTQ of Amine Dehydrogenases
Synthesis of Mono-, Di-, andTrisilyl-Substituted Alkenes via theHydrosilylation of MethylenecyclopropanesCatalyzed by Rh(I) Complexes
Mechanism of the Chemoselective and Stereoselective RingOpening of Oxathiaphospholanes: An Ab Initio Study
Highly Diastereoselective Additions to Chiral α-Keto Acetals
The First Total Synthesis of (±)-Huperzine B
Formation of Attractive π-RedoxCyclophanes
Syntheses and Properties of Medium-Sized Metacyclophanediynes
Laser Flash, Laser-Drop, and Lamp Photolysis of1,3-Dichloro-1,3-diphenylpropane. One- versus Two-PhotonReaction Pathways
Effect of Solvent on the α-Effect: Nucleophilic SubstitutionReactions of p-Nitrophenyl Acetate with m-Chlorophenoxide andBenzohydroxamates in MeCN−H2O Mixtures of VaryingCompositions
Nitrogen Pronucleophiles in thePhosphine-Catalyzed γ-Addition Reaction
Stereoselective Synthesis of the C3−C17Bis-Oxane Domain of Phorboxazole A
Bis(pentafluorophenyl)borinic Acid as aHighly Effective Oppenauer OxidationCatalyst for Allylic and Benzylic Alcohols
Diastereoselective Enolsilane CouplingReactions
Facile, Regioselective Synthesis of Highly SolvatochromicThiophene-Spaced N-Alkylpyridinium Dicyanomethanides forSecond-Harmonic Generation
Olefinic Ozonation Electron Transfer Mechanism
Kinetics and Mechanism of the Aminolysis of PhenylDithioacetates in Acetonitrile
Copper Chloride-Catalyzed and Hydrochloric Acid-MediatedChemoselective Protiodestannylations of Alkyl (Z)- or(E)-2,3-Bis(trimethylstannyl)-2-alkenoates. StereoselectivePreparation of Alkyl (E)- and (Z)-3-Trimethylstannyl-2-alkenoates
Photolytic Mass Laddering for FastCharacterization of Oligomers on SingleResin Beads
Stereochemical Control over Three Contiguous StereogenicCenters in the Intramolecular Ene Reaction of Activated1,6-Dienes. Application to the Synthesis of (±)-Methyl Cucurbateand (±)-Methyl Epijasmonate
Photochemical Synthesis of s-Triazolo[3,4-b]benzothiazole andMechanistic Studies on Benzothiazole Formation
Synthetic Applications of 1-Aminoalkyl Chloromethyl Ketones.Synthesis of Enantiopure 3-Azetidinols and Aminoalkyl Epoxides
Diels−Alder Reaction of an Ene−Phospha−Yne
Glycomimetics: A Versatile de Novo Synthesis ofβ-1-C-Aryl-deoxymannojirimycin Analogues
Total Synthesis of the Annonaceous Acetogenins Asiminocin andAsiminecin by a Bidirectional Approach
A Novel Efficient Synthesis of Dihydroxyacetone Phosphate andBromoacetol Phosphate for Use in Enzymatic Aldol Syntheses
Palladium-Catalyzed Allylic Substitution inγ-Oxygenated Vinyl Sulfones: One-StepSynthesis of TetrasubstitutedDihydrofurans
A Novel Entry to theBicyclo[4.2.2]decatriene and TetraeneSystems: The Unexpected1,4-Cycloaddition of2-(Methylthio)acrylonitrile toCyclooctatetraene
Total Synthesis of the Annonaceous Acetogenin (+)-Asimicin.Development of a New Bidirectional Strategy
Zirconium-Mediated Intramolecular Coupling Reactions ofUnsaturated Anilines. Diastereoselective Synthesis of Azetidines
Synthesis of Benzofuran Derivatives onSolid Support via SmI2-Mediated RadicalCyclization
Bengacarboline, a New β-Carboline from aMarine Ascidian Didemnum sp.
A Convenient One-Pot Method for the Construction ofTetrasubstituted Phenols through a Michael Addition−AldolCyclization Sequence
Intramolecular 4 + 3 Cycloadditions.Further Studies of (Trimethylsilyl)methylAllylic Sulfones
A New Route to 3-Amino Sugars. A Concise Synthesis ofl-Daunosamine and d-Ristosamine Derivatives
Comparative Studies on the Synthesis of an anti,syn Stereotriadwith Chiral Allenylstannane and Allenylindium Reagents
Regiochemistry of Diels−Alder Reactions of Diverseβ-Functionalized Alkynyliodonium Salts with UnsymmetricalDienes
Generation of Iminyl Radicals through Sulfanyl Radical Additionto Vinyl Azides
Asymmetric Aldol Route toHydroxyethylamine Isostere: Stereoselective Synthesis of the Core Unitof Saquinavir
Design and Synthesis of a Taxoid Library Using RadiofrequencyEncoded Combinatorial Chemistry
Enantioselective Total Synthesis ofFumonisin B2
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