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A Safe Cost-Efficient Synthesis of4,6-Diaminoresorcinol
Conversion of Aziridinemethanol Sulfonate Esters to AllylicAmines via Tellurium Chemistry1
Fast Equilibrium inN-(Ethoxycarbonyl)-r-2,c-7-diphenylhexahydro-1,4-diazepin-5-onesin Flattened Boat Conformations
Synthesis and Further Reactivity of FunctionalizedLactam-Derived Enol Triflates
Utilization of the Phenylthio Substituent as a MultipurposeSynthetic Tool. Direct Application to the EnantioselectiveConstruction of (−)-Salsolene Oxide
Salicylihalamides A and B, Novel Cytotoxic Macrolides from theMarine Sponge Haliclona sp.
Addition of α-Substituted(γ-Alkoxyallyl)tins on Aldehydes: TheDramatic Influence of the Size of theα-Substituent on the Diastereoselection
Oxidative N-Dealkylation ofp-Cyclopropyl-N,N-dimethylaniline.A Substituent Effect on a Radical-ClockReaction Rationalized by Ab InitioCalculations on Radical CationIntermediates
Photoreduction of Azoalkanes by Direct Hydrogen Abstractionfrom 1,4-Cyclohexadiene, Alcohols, Stannanes, and Silanes
Total Syntheses of (+)-Secosyrins 1 and 2 and (+)-Syributins1 and 2
Improved Syntheses of3,5-Diaryl-Substituted Phenols
Synthesis of α- and β-d-(1→6)-C-Disaccharides by WittigOlefination of Formyl C-Glycosides with Glycopyranose6-Phosphoranes
Stereospecific Preparation of theN-Terminal Amino Acid Moiety ofNikkomycins KX and KZ via a MultipleEnzyme Synthesis
Synthesis of Mauritiamine
Theoretical Studies of Eliminations. 6. The Regiochemistry andStereochemistry of the Gas-Phase Reactions of3-Halocyclohexenes with Fluoride. An ab Initio Study
Endohedral Homoconjugation inCyclopentadiene Embedded in C60.Theoretical and Electrochemical Evidence
Synthesis of ML-3000, an Inhibitor ofCyclooxygenase and 5-Lipoxygenase
Addition Reactions of Tris(trimethylsilyl)germyl Radicals toUnsaturated Compounds. An EPR and Product Study
Solid-Phase Synthesis of β-Sultams
Efficient Preparation of2-Bromo-6-lithiopyridine viaLithium−Bromine Exchange inDichloromethane
Syntheses of Strychnan- and Aspidospermatan-Type Alkaloids. 9.The Enantioselective Generation of Tetracyclic ABCEIntermediates by a Tandem Condensation, [3,3]-SigmatropicRearrangement, and Cyclization Sequence
Polonovski-type Reaction Induced byO-Silylated Ketene Acetals
Preparation of 4-Oxo-l-norvaline viaDiazomethane Homologation of β-AspartylSemialdehyde
Photochemistry of 4-Thiothymine Derivatives in the Presence ofN-9-Substituted-Adenine Derivatives: Formation ofN-6-Formamidopyrimidines
Enantiomerically Pure α,β-Unsaturated Five-Membered-RingAldehydes by Ring Contraction of Epoxyhexopyranosides
Complex of 4-Fluorophenol withα-Cyclodextrin: Binding Mode in SolutionIs Opposite to That in the Solid State
Intramolecular Geminal and Vicinal Element Effects inSubstitution of Simple Bromo(chloro)alkenes by Methoxide andThiolate Ions. An Example of a Single Step Substitution?
Characterization of Low-Barrier Hydrogen Bonds. 5.Microsolvation of Enol−Enolate. An ab Initio and DFTInvestigation
First Stereoselective [4 + 2] CycloadditionReactions of 3-Cyanochromone Derivativeswith Electron-Rich Dienes: An Approachto the ABC Tricyclic Frame of Arisugacin1
A Convergent, Enantioselective TotalSynthesis of Streptogramin Antibiotic(−)-Madumycin II
Computational Comparison of SN2 Substitution ReactionsofCHX•- and CH2X- with CH3X (X = Cl, Br). Do Open-Shell andClosed-Shell Anions React Differently?
Synthesis of Polycyclic Oxanorbornanes via a SequentialEpoxyhexopyranoside Ring Contraction−IntramolecularDiels−Alder Reaction
The Direct Alkylation of π-Rich, Acid-Sensitive HeterocyclicCompounds via Essentially Free Carbocations1
Benzotriazole-Mediated Conversions of para-H-SubstitutedPyrylium, Benzo[b]pyrylium, and Xanthylium Salts intopara-Position Functionalized Derivatives (An IndirectElectrophilic Substitution of Electron-Deficient Heteroaromatics)
Kinetics of Proton Transfer from Benzoylnitromethane and1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance,Inductive, Solvation, Steric, and Transition StateHydrogen-Bonding Effects on Intrinsic Rate Constants
High-Temperature Behavior of1,8-Diethynylanthracene.Benz[mno]aceanthrylene, a TransientIntermediate for Cyclopenta[cd]pyrene
Nucleophilic Vinylic Substitutions of(Z)-(β-Haloalkenyl)phenyliodonium Salts with SodiumBenzenesulfinate: First Evidence of a Michael Addition ofNucleophiles to Alkenyliodonium Salts at the Cβ Atom
A Mild Protocol for the Conversion ofSimple Esters to tert-Butyl Esters
Modification of the Skeleton ofHomoharringtonine through UnusualRearrangements
A Novel High-Yield Synthesis of Substituted Isoindolequinones
Revised Structures for the LactonesObtained by Reduction of the Adduct ofErgosterol Acetate with Maleic Anhydride
Preparations of Trisubstituted Hydrazines and Pyrazolidines fromN-(1-Benzotriazolylalkyl)hydrazines
Asymmetric Synthesis of N-Substitutedα-Aminobenzlactam viaCrystallization-Induced AsymmetricTransformation of Covalent Diastereomer
Molecular Design of C-Pivot Tripodal Ligands: Importance of theGlycerol Structure for Effective Complexation toward Alkali MetalCations
Enantiopure N-Acyldihydropyridones as Synthetic Intermediates: Asymmetric Syntheses of Indolizidine Alkaloids (−)-205A, (−)-207A,and (−)-235B
Enantioselective Diels−Alder Reaction Using Chiral MgComplexes Derived from Chiral 2-[2-[(Alkyl- or2-[2-[(Arylsulfonyl)amino]phenyl]-4-phenyl-1,3-oxazoline
Regio- and Stereoselectivity of Water Elimination as a Function ofRing Size
An Improved Synthesis of 7-Substituted Pyrrolo[3,2-d]pyrimidines
Chemoselective Glycosylations. 2. Differences in Size ofAnomeric Leaving Groups Can Be Exploited in ChemoselectiveGlycosylations
Enantioselective and DiastereoselectiveBinding Study of Silica BoundMacrobicyclic Receptors by HPLC
On the ET (30), π*, Py, S‘, and SPPEmpirical Scales as Descriptors ofNonspecific Solvent Effects
An Efficient Acylation of Tertiary Alcohols with IsopropenylAcetate Mediated by an Oxime Ester and Cp*2Sm(thf)2
Chiral Auxiliary-Directed AsymmetricOrtho-Lithiation of(Arene)tricarbonylchromium Complexes
Synthesis of XylβCer, Galβ1−4XylβCer, NeuAcα2−3Galβ1−4XylβCerand the Corresponding Lactone and Lactam Trisaccharides
Trends in Inversion Barriers of Group 15 Compounds. 3. AreFluorinated Pyridone Derivatives Planar or Nonplanar?
Palladium-Catalyzed Cross-Coupling Syntheses of BenzotriazolylEnynes and a General Route to Enynyl Ketones and AlkynylKetones
Asymmetric Induction in theElectrochemical Cross-Coupling of ArylHalides with α-Chloropropionic AcidDerivatives Catalyzed by Nickel Complexes
Preparation of (R)-Fluoropyruvaldehyde N,S-Ketals by HighlyStereospecific Tandem Pummerer Rearrangement/1,2-p-TolylthioGroup Migration of (R)-α-(Fluoroalkyl)-β-sulfinylenamines
General Synthesis of Polysubstituted Benzo[b]furans
An Improved Synthesis of O-Benzoyl Protected Hydroxamates
A Novel C−C Single-Bond Formation Accompanying C−O BondCleavage by Use of a Ketone, an Alkylating Reagent, and aLow-Valent Vanadium Complex in the Presence of a CatalyticAmount of Molecular Oxygen
Ab-Initio MO Study of the Peracid Oxidation of DimethylThiosulfinate
Synthesis of Biaryls via a Nickel(0)-Catalyzed Cross-CouplingReaction of Chloroarenes with Arylboronic Acids
Reactivity of Acyl Derivatives towardDialkoxytitanacyclopropane
Enantioselective Synthesis ofent-Stellettamide A via a Novel DipolarCycloaddition Reaction of(Trimethylsilyl)diazomethane
Lewis Acid Catalysis in the Oxidative Cycloaddition ofThiophenes1
Reactions of Vinyl Sulfoxides with Magnesium Amides. One-PotSynthesis of Symmetrical and Unsymmetrical β-(Dialkylamino)Dithioacetals
Synthesis, Optical Resolution and Complexation Properties ofInherently Chiral Monoalkylated p-tert-Butyl-(1,2)-calix[4]crownEthers
Taxamycin Studies: CrCl2/NiCl2-MediatedCyclizations and Unusual SeO2 Oxidations
An Improved Photosensitizer for thePhotoinduced Electron-TransferDeoxygenation of Benzoates andm-(Trifluoromethyl)benzoates
An Artificial Antiparallel β-SheetContaining a New PeptidomimeticTemplate
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