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Two-Directional Synthesis of Polycyclopropanes. An Approach tothe Quinquecyclopropane Fragment of U-106305
Synthesis of Pentacyclic Steroids via Tandem Stille Coupling andDiels−Alder Reactions
Approaches to StereoselectiveDioxygenation of Alkenes: ChiralPhosphite Ozonides
Asymmetric Hosomi−Sakurai Reaction of Allylsilanes ContainingArabinose-Derived Alcohols as Chiral Auxiliaries
Dimeric Products from the Base-CatalyzedCondensation of Benzaldehyde with2,3-Dihydro-1H-inden-1-one or2-(Phenylmethylene)-2,3-dihydro-1H-inden-1-one
Stereoselective Synthesis of2‘,3‘-Dideoxynucleosides by Addition ofSelenium Electrophiles to Glycals. AFormal Synthesis of D4T from2-Deoxyribose
Synthesis of Spiro Polycyclic Aromatic Hydrocarbons byIntramolecular Palladium-Catalyzed Arylation
Synthetic Studies toward theReveromycins: Asymmetric Synthesis ofthe Spiroketal Segment of Reveromycin B
Lithiated γ-Tosyl-Substituted Benzylmethallylamine: New γ-Amino MethallylSulfone Anions in Organic Synthesis
Syntheses of Steroidal Vinyl Ethers UsingPalladium Acetate−Phenanthroline asCatalyst
A C10 Chiron Applicable to the Synthesis ofArchaebacterial Lipids
Chemoenzymatic Synthesis of UnnaturalAmino Acids via Modified ClaisenRearrangement of Glycine Enolates.Approach to Morphine Synthesis
Asymmetric Total Synthesis of (+)-Apovincamine and a FormalSynthesis of (+)-Vincamine. Demonstration of a Practical“Asymmetric Linkage” between Aromatic Carboxylic Acids andChiral Acyclic Substrates
Facile and Efficient Guanylation of AminesUsing Thioureas and Mukaiyama's Reagent
Rapid Solution and Solid Phase Syntheses of Oligo(1,4-phenyleneethynylene)s with Thioester Termini: Molecular Scale Wires withAlligator Clips. Derivation of Iterative Reaction Efficiencies on aPolymer Support
An Approach toward the Illudin Family of Sesquiterpenes Usingthe Tandem Cyclization−Cycloaddition Reaction of RhodiumCarbenoids
Synthesis of the FirstPerfluoro-spiro-bis-crown Ethers
Half-Lives of Organolithium Reagents inCommon Ethereal Solvents
Solid-Phase Synthesis of 1,4-Benzodiazepine-2,5-diones. LibraryPreparation and Demonstration of Synthesis Generality
Homodienyl [1,5]-Hydrogen Shift of cis-and trans-N-Acyl-2-alkylcyclopropylimines
Regioselectivity in the Palladium-Catalyzed Addition of CarbonNucleophiles to Dihydropyran Derivatives
Construction of Preorganized Polytopic Ligands viaPalladium-Promoted Cross-Coupling Reactions
Pinacol−Pinacolone Rearrangements in vic-Dihydroxychlorinsand Bacteriochlorins: Effect of Substituents at the PeripheralPositions
Clocking Tertiary Cyclopropylcarbinyl Radical Rearrangements1
Alkylation and Reductive Decyanation of4-Cyano-2,2-dimethyl-1,3-dioxanes (Cyanohydrin Acetonides)
New Cytotoxic Metabolites from the Sponge Cacospongia scalaris
Preparation of Cinnamate Esters fromStyrenes
A Quantum Mechanically Derived All-Atom Force Field forPyranose Oligosaccharides. AMBER* Parameters and FreeEnergy Simulations
N-Nitration, 15N-Labeling, and N-to-NLinking of Hydroxyl-Silylated PyrimidineNucleosides
Synthesis and X-ray CrystallographicStructure of Leucine−PhenylalanylSuccinimide-Based Pseudopeptides
Didemnimides A−D: Novel, Predator-Deterrent Alkaloids from theCaribbean Mangrove Ascidian Didemnum conchyliatum
Chelation-Assisted IntermolecularHydroacylation: Direct Synthesis ofKetone from Aldehyde and 1-Alkene
First Enantioselective Catalyst for the Rearrangement of AllylicImidates to Allylic Amides
Magnesium Methyl Carbonate-Activated Alkylation of MethylKetones with an ω-Halo Nitrile, Esters, and Amides
NMR Studies of Conformations of N-Dansyl-l-leucine-Appendedand N-Dansyl-d-leucine-Appended β-Cyclodextrin as FluorescentIndicators for Molecular Recognition
An Unexpected RateAccelerationPractical Improvements inthe Baylis−Hillman Reaction
First Stereocontrolled Syntheses of Unsymmetrically SubstitutedBislactone Lignans: Stereocontrolled Syntheses of Four PossibleIsomers of Methyl 4,8-Dioxoxanthoxylol
Use of Acyclic Glycosyl Donors for Furanoside Synthesis
Ni-Catalyzed Cross Coupling ofAlkoxide-Containing Vinyl Halides withGrignard Reagents. A “One-Pot” Synthesisof 2-[(Trimethylsilyl)methyl]-2-propen-1-ylAcetate
Palladium-Catalyzed Amination of Aryl Triflates
Tributyltin Hydride-Mediated Free-Radical Cyclization ofAllene-Tethered Oxime Ethers and Hydrazones
Synthesis of Helical Conjugated Ladder Polymers
Novel Chiral Recognition in Host−GuestInclusion Complexes Depends on TheirMolar Ratios: Efficient Resolution of2,2‘-Dihydroxy-1,1‘-biphenyl Derivativesand CD Spectral Study of InclusionComplex Crystals
Complexes ofOxygenated trans-Azoalkanes and Tetracyanoethylene. TheInteraction of π Oxygen Anions with an Electron Poor Alkene
Molecular Mechanics/Continuum Reaction Field/QuantumMechanics Study of the Intramolecular Diels−Alder Reaction of2-Furfuryl Derivatives
Formation of2-[1-(Trimethylsilyl)alkylidene]-4-cyclopentene-1,3-dione fromLewis Acid-Catalyzed Reaction of Cyclobutenedione Monoacetalwith Alkynylsilane: Novel Cationic 1,2-Silyl Migrative RingOpening and Subsequent 5-Exo-Trig Ring Closure
Iodine as Acetylation Catalyst in thePreparation of 1,1-Diacetates fromAldehydes
Synthesis of α-Functionalized andNonfunctionalized Hydroximoyl Chloridesfrom Conjugated Nitroalkenes andNitroalkanes
Synthesis of a Novel Esterase-Sensitive Cyclic Prodrug of aHexapeptide Using an (Acyloxy)alkoxy Promoiety
Oxidation of Sulfur-Containing Compounds with HOF·CH3CN
Palladium-Catalyzed Amination of Aryl Triflates and Importanceof Triflate Addition Rate
Efficient Synthesis of Selectively Protectedl-Dopa Derivatives from l-Tyrosine viaReimer−Tiemann and Dakin Reactions
Rapid Syntheses of Oligo(2,5-thiophene ethynylene)s withThioester Termini: Potential Molecular Scale Wires with AlligatorClips
Multivalent Templated Saccharides: Convenient Syntheses of Spacer-Linked1,1‘-Bis -and 1,1‘,1‘‘-Tris-β-glycosides by theGlycal Epoxide Glycosidation Method
Palladium-Mediated Cyclization on Carbohydrate Templates. 1.Synthesis of Enantiopure Bicyclic Compounds
Electronic Effects of para- and meta-Substituents on the EPR DParameter in 1,3-Arylcyclopentane-1,3-diyl Triplet Diradicals. ANew Spectroscopic Measure of α Spin Densities and RadicalStabilization Energies in Benzyl-Type Monoradicals
Pestalotiopsins A and B: New Caryophyllenesfrom an Endophytic Fungus of Taxus brevifolia
Effect of Calcium Reagents on Aldol Reactions ofPhenolic Enolates with Aldehydes in Alcohol
Grignard Reactions on Ortho Dicarboxylic Arene Derivatives.Synthesis of 1,3-Dithienylisothianaphthene Compounds
Further Rearrangement of MeisenheimerProducts of Allyl Aryl Amine Oxides
Nucleosides and Nucleotides. 163. Synthesis of 3‘-β-BranchedUridine Derivatives via Intramolecular Reformatsky-TypeReaction Promoted by Samarium Diiodide1
Synthesis of a Novel Esterase-Sensitive Cyclic Prodrug System forPeptides That Utilizes a “Trimethyl Lock”-FacilitatedLactonization Reaction
α,β-Unsaturated Nitriles: Stereoselective Conjugate AdditionReactions
Transition-Metal-Mediated Exo-Selective Diels−Alder Reactionsfor the Preparation of Octalones with Unusual Stereochemistries.Reactions of 2-Cobaloxime-Substituted 1,3-Dienes withCyclohexenones in Thermal and Lewis Acid-Catalyzed [4 + 2]Cycloadditions
Direct Synthesis of β-Mannopyranosides bythe Sulfoxide Method
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