Documentation scienceplus.abes.fr version Bêta

À propos de : Experimental and Computational Evidence for the Formation ofIminopersulfinic Acids        

AttributsValeurs
type
Is Part Of
Subject
Title
  • Experimental and Computational Evidence for the Formation ofIminopersulfinic Acids
has manifestation of work
related by
Author
Abstract
  • An experimental and computational study of thereactions of singlet oxygen with N-substitutedsulfenamides is reported. Intermediates capable of epoxidizingnorbornene were observed duringthe photooxidations of three sulfenamides. These results are usedto argue for formation ofiminopersulfinic acids. The structural integrity of twoiminopersulfinic acids was supported bytheir successful location at the MP2/6-31G* level of theory.Furthermore, the inability to locatecomputationally significant persulfinimide precursors suggests that theiminopersulfinic acids formby enelike reactions involving near-simultaneous addition of singletoxygen to sulfur and hydrogenabstraction.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata