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The Simplest Azabutadienes in Their N-Protonated Forms.Generation, Stability, and Cycloaddition Reactivity in the GasPhase
Total Synthesis of Petrosin, Petrosin A, and Petrosin B
Preparation of Medium-Ring Lactones andLactams by Electrophilic Cyclizations
Solvent and Reagent Accessibility within Oligo(ethylene glycol)Ether [PEG] Cross-Linked Polystyrene Beads
Stereocontrolled Synthesis and Cycloaddition of 1,4-Dialkoxy1,3-Dienes
Ru3(CO)12- and Rh4(CO)12-Catalyzed Reactions of Pyridylolefins orN-(2-Pyridyl)enamines with CO and Olefins. Carbonylation atOlefinic C−H Bonds
Pyramidalized Olefins: Ab Initio Study andX-ray Structure Determination ofBicyclo[2.2.2]octadienes
Reaction of (Trifluoromethyl)trimethylsilane withOxazolidin-5-ones: Synthesis of Peptidic and NonpeptidicTrifluoromethyl Ketones
Stereoselective Construction ofTetrasubstituted Exocyclic Alkenes fromthe [4 + 2]-Cycloaddition of Vinylallenes
Diastereoand Enantioselective Synthesis of Syn 1-FluoroalkylIsoserinates
Palladium-Catalyzed Hydroarylation of Propiolamides. A Regio-and Stereocontrolled Method for Preparing 3,3-Diarylacrylamides
Intramolecular Diels−Alder Reaction of Furans with AllenylEthers Followed by Sulfur and Silicon Atom-Containing GroupRearrangement
Direct Approach to α-Hydroxyphosphonic andα,ω-Dihydroxyalkane-α,ω-bisphosphonic Acids by the Reduction of(Bis)acylphosphonic Acids
Photochemical Ring Expansion of α-Alkoxycyclobutanones to2-Acetoxy-5-alkoxytetrahydrofurans: Nucleophilic Reactions atthe 2-Position
C-Arylglycosides via a BenzannulationMediated by Fischer Chromium CarbeneComplexes
Origins of Stereocontrol in the [2 + 2] Cycloaddition betweenAchiral Ketenes and Chiral α-Alkoxy Aldehydes. A PericyclicAlternative to the Aldol Reaction
Electropolymerization of Bis(2-cyano-2-α-thienylethenyl)arylenes
Regio- and Stereoselective Fe(III)- andPd(0)-Mediated Ring Openings of3-Aza-2-oxabicyclo[2.2.1]hept-5-ene Systems
Preparation of Congested Thiophenes Carrying BulkySubstituents on the 3- and 4-Positions and Their Conversion tothe Benzene Derivatives
Conformational Studies by Dynamic NMR. 65. Interconversionof Stereolabile Meso and Racemic Diastereoisomers of Hindered1,4-Diacylnaphthalenes
Highly Enantioselective Reduction of Carbonyl Compounds Usinga Reductase Purified from Bakers' Yeast
Molecular Addition Compounds. 11.N-Ethyl-N-isopropylaniline−Borane, A Superior Reagent forHydroborations and Reductions
Rate Increase in Consecutive Nucleophilic Aromatic SubstitutionReactions of Trichlorotrinitrobenzene: The Synthesis of1-(Alkylamino)-3,5-dichloro-2,4,6-trinitrobenzenes
Persistent and Transient Open-Shell Species Derived fromC60−TTF Cyclohexene-Fused Dyads
High-Yielding Method for On-ColumnDerivatization of Protected Oligodeoxy-nucleotides and Its Application to theConvergent Synthesis of 5‘,3‘-Bis-conjugates
Activation of Low-Valent Titanium Reagents with Iodine: FacileLow-Temperature McMurry Reaction and N/O-Debenzylation/Deallylation
Site-Specific Introduction of(5‘S)-5‘,8-Cyclo-2‘-deoxyadenosine intoOligodeoxyribonucleotides
Highly Functionalized Cyclohexenyl Systems: EnzymaticResolution and Selective Oxirane Opening Reactions ofp-Benzoquinone Derivatives
Highly Enantioselective 1,2-Addition of2-[(Trimethylsilyl)oxy]furan to Aldehydes: Application toMuricatacin Synthesis
Study on Radical Amidation onto Aromatic Rings with(Diacyloxyiodo)arenes
A Novel [3+2] Cycloaddition Approach to Nitrogen Heterocyclesvia Phosphine-Catalyzed Reactions of 2,3-Butadienoates or2-Butynoates and Dimethyl Acetylenedicarboxylate with Imines: A Convenient Synthesis of Pentabromopseudilin
Efficient Synthesis of DiverseMonosaccharide Derivatives in the SolidPhase
Formation of Some Oxygen-Containing Heterocycles by RadicalCyclization: The Stereochemical Influence of Anomeric Effects
Oxidative Cross-Coupling of N-(2‘-Phenylphenyl)benzene-sulfonamides or Benzoic and Naphthoic Acids with Alkenes Usinga Palladium−Copper Catalyst System under Air
Nitroarylamines via the Vicarious Nucleophilic Substitution ofHydrogen: Amination, Alkylamination, and Arylamination ofNitroarenes with Sulfenamides
Cationic Palladium/Boxax Complexes for Catalytic AsymmetricWacker-Type Cyclization
Highly Diastereoselective Conjugate Addition of Lithiated γ-Crotonolactone(But-2-en-4-olide) to Cyclic Enones To Give Syn-Adducts: Application to a Brefeldin Synthesis
Three-Step Access to the Tricyclic Benzo[a]quinolizine RingSystem
A Priori Prediction of Substituent and Solvent Effects in theBasicity of Nitriles
Highly Stereoselective Nucleophilic Epoxidation of Simple VinylSulfoxides
Synthesis of Petrosins C and D
Palladium-Catalyzed Reaction ofN-Allylbenzotriazoles with Amines: ANovel Method for the Preparation ofAllylamines
Synthesis and Excited-State Photodynamics of a Molecular SquareContaining Four Mutually Coplanar Porphyrins
Total Synthesis of Muconin by EfficientAssembly of Chiral Building Blocks
Reaction of Benzylic α-Hydroxythioamides with Thionyl Chloride
Novel Enantioselective Synthesis ofα-Methylthreonines andα,β-Dimethylcysteines
HIV-1 Protease Inhibitors Based on Acyclic Carbohydrates
Asymmetric Ring Opening of MesoEpoxides with Thiols: EnantiomericEnrichment Using a BifunctionalNucleophile
Ligand Recognition by E- and P-Selectin: ChemoenzymaticSynthesis and Inhibitory Activity of Bivalent Sialyl Lewis xDerivatives and Sialyl Lewis x Carboxylic Acids
Inactivation of Two Triterpene Cyclases by18(E)-(3S)-29-Methylidene-2,3-oxidosqualene
New Convenient One-Pot Methods of Conversion of Alkynes toCyclobutenediones or α,β-Unsaturated Carboxylic Acids UsingNovel Reactive Iron Carbonyl Reagents
Highly Regioselective Palladium-Catalyzed Internal Arylation ofAllyltrimethylsilane with Aryl Triflates
Chemoselective Hydrogenation ofα,β-Unsaturated Sulfones andPhosphonates via Palladium-AssistedHydrogen Transfer by Ammonium Formate
First Calix[8]arene with RegioselectivelyFunctionalized Upper Rim. ApparentObservation of IntramolecularHydrogen-Bond Flipping
Reactions via Carbonyl Anions. [4 + 1] Cyclocoupling of the Azadienyllithium with Carbon Monoxide
Aromaticity as a Quantitative Concept. 7. AromaticityReaffirmed as a Multidimensional Characteristic
Isolation and Stereochemical Studies of aCyclic Alkoxysulfonium Salt, an ImportantIntermediate in the Nucleophilic Reactionof Chlorooxasulfuranes
Use of Diisocyanates for in SituPreparation of Nitrile Oxides: Preparationof Isoxazoles and Isoxazolines
Total Synthesis of CryptophycinAnalogues. Isosteric Replacement of theC−D Ester
An Improved Synthesis of (4S,5S)-2-Phenyl-4-methoxycarbonyl-5-isopropyloxazoline from (S)-Phenylglycinol
New Reagent for Reductive Coupling ofCarbonyl and Imine Compounds: HighlyReactive Manganese-Mediated PinacolCoupling of Aryl Aldehydes, Aryl Ketones,and Aldimines
A New Generalized Karplus-Type Equation Relating VicinalProton-Fluorine Coupling Constants to H−C−C−F Torsion Angles
π-Cation and π-Dipole-Stabilizing Interactions in a Simple ModelSystem with Cofacial Aromatic Rings
Steroid-Bridged Anthryloligothienylporphyrins: Synthesis andStudy on the Intramolecular Energy Transfer
Aluminum-Mediated 1,2-Alkyl MigrationResulting from Hydrocyanation of anα-Epoxy Ketone
New and Efficient Synthesis of an AminoAcid for PreparingPhosphine-Functionalized Peptidomimetics
An Efficient Stereoselective Synthesis of Stypodiol andEpistypodiol
[3 + 2] Cycloadditions between α,β-Unsaturated Esters orNitroalkenes and Camphor-Derived Oxazoline N-Oxides: Experimental and Theoretical Study
Facile Synthesis of Terminal 1,2-Diols withHigh Optical Purity viaOxazaborolidine-Catalyzed AsymmetricBorane Reduction
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