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Copyright © 1998 American Chemical Society
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Palladium(0)-Catalyzed Allylation of Highly Acidic andNonnucleophilic Anilines. The Origin of StereochemicalScrambling When Using Allylic Carbonates
Two Practical and Efficient Approaches to Fluorinated andNonfluorinated Chiral β-Imino Sulfoxides
Preparation of Substituted Alkylpyrroles via Samarium-CatalyzedThree-Component Coupling Reaction of Aldehydes, Amines, andNitroalkanes
Nucleophilic Substitution Reactions of(Alkoxymethylene)dimethylammonium Chloride
Unusual Regioselectivity of the Dipolar Cycloaddition Reactionsof Nitrile Oxides and Tertiary Cinnamides and Crotonamides1
A New Bromo Trienyne: Synthesis of all-E,Conjugated Tetra-, Penta-, and HexaenesCommon to Oxo Polyene MacrolideAntibiotics
A Novel Example for Optical Resolution ofRacemic Ketones Originating fromBatrachotoxin Synthesis
Transition State Structure for the Water-Catalyzed Hydrolysis ofp-Nitrophenyl Trifluoroacetate in Acetonitrile
Synthesis of Benzo[s]picene and itsPutative Carcinogenictrans-3,4-Dihydrodiol and Fjord Regionanti-Diol Epoxide Metabolites
Stereospecific Synthesis of 1,6-Dioxadecalins and 2,2‘-LinkedDitetrahydrofurans by Rearrangement of Steroidal Spiroacetals
Reactions of Thioaroylketene S,N-Acetalswith 1,3-Dicarbonyl Compounds in thePresence of Mercury(II) Acetate: A GeneralRoute to 2-Acyl- and 2-Aroyl-3-(alkylamino)-5-arylthiophenes and 2-(Ethoxycarbonyl)-3-(methylamino)-5-arylthiophenes
Diastereo- and Enantioselective Alkylation ofα-Imino Esters with Enol Silanes Catalyzedby (R)-Tol-BINAP−CuClO4·(MeCN)2
Formal Total Synthesis of Hemibrevetoxin B by an OxiranylAnion Strategy
Primary and Secondary Isotope Effects inthe Photooxidation of2,5-Dimethyl-2,4-hexadiene. Elucidation ofthe Reaction Energy Profile
Novel Bismethanofullerenes and Ethenofullerene from theReaction of Propiolates with C60 in the Presence ofTriphenylphosphine
Lewis Acid-Promoted Reactions of3-Methoxy-N-(benzenesulfonyl)-1,4-benzoquinone Monoimine withPropenylbenzenes
Methyl- and (Trifluoromethyl)alkene PeptideIsosteres: Synthesis and Evaluation of TheirPotential as β-Turn Promoters and PeptideMimetics
An Efficient Derivation of the Versatile Chiron Antipode1-tert-Butyldimethylsilylpenta-1,4-diyn-3-ol: Application to theSynthesis of (15E,R,R)-Duryne
Infrared and Raman Spectra of a Single Resin Bead for Analysisof Solid-Phase Reactions and Use in Encoding CombinatorialLibraries
Short Enantioselective Total Syntheses of the Piperidine Alkaloids(S)-Coniine and (2R,6R)-trans-Solenopsin A via CatalyticAsymmetric Imine Hydrosilylation
Cyclization of o-Allylstyrene via Hydrosilylation: MechanisticAspects of Hydrosilylation of Styrenes Catalyzed byPalladium−Phosphine Complexes
Remarkable Effect of Ethylene Gas in theIntramolecular Enyne Metathesis of TerminalAlkynes
Electron Transfer from a Cyclic Diaryliodine Species toArenediazonium Salts. Evidence for the Intermediacy of 9−I−2Structures in Iodine Atom Transfer Reactions1
Synthesis of Tethered Trisaccharides To Probe Inter-SaccharideFlexibility in Carbohydrate−Protein Interactions
Synthesis of Novel Bicyclo[2.2.1]Ribonucleosides: 2‘-Amino- and 2‘-Thio-LNAMonomeric Nucleosides
Chiral Lewis Acid-Mediated Enantioselective Pictet−SpenglerReaction of Nb-Hydroxytryptamine with Aldehydes
Reactions of Diphenyl(phenylethynyl)selenonium Salts withActive Methylene Compounds and Amides: First Isolation ofOxyselenuranes [10-Se-4(C3O)] as a Reaction Intermediate
Stereoselective Total Synthesis of (±)-Swainsonine Based on EndoMode Cyclization
Altering the Acidity and Solution Properties of Bilirubin.Methoxy and Methylthio Substituents
Synthesis of Acyclic Precursors to(3S,4S)-4-Hydroxy-2,3,4,5-tetrahydropyridazine-3-carboxylic Acid andIncorporation into a Luzopeptin/Quinoxapeptin Dipeptide
Regioselective Inverse Electron Demand Diels−Alder Reactions ofN-Acyl 6-Amino-3-(methylthio)-1,2,4,5-tetrazines
[2.2.2.2]Pagodane: Synthesis and Oxidationof Nonclassical Valence-Isomeric 4C/3e andσ-Bishomoaromatic 4C/2e Ions
Horseradish Peroxidase-Catalyzed Enantioselective Reduction ofRacemic Hydroperoxy Homoallylic Alcohols: A Novel EnzymaticMethod for the Preparation of Optically Active, Unsaturated Diolsand Hydroperoxy Alcohols
Allylation of Carbonyl Compounds Bearinga Hydroxyl Group by Tetraallyltin: HighlyStereoselective Allylation in aChelation-Controlled Manner
Synthesis of Diaryl Ethers, Diaryl Thioethers, and DiarylaminesMediated by Potassium Fluoride−Alumina and 18-Crown-6: Expansion of Scope and Utility1
A Synthetic Receptor Which Uses Multiple Edge−FaceInteractions To Bind Aromatic Guests
Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes.The Bridged Mode (β-Tether)
Practical Access to CarbacephemIntermediates via Asymmetric [2 + 2]Ketene−Imine Cycloaddition
The First General Synthesis of1,5-Dioxaspiro[3.2]hexanes
Energetics of Multistep versus One-step Hydride TransferReactions of Reduced Nicotinamide Adenine Dinucleotide (NADH)Models with Organic Cations and p-Quinones
A Mild and Efficient Epoxidation of OlefinsUsing in Situ GeneratedDimethyldioxirane at High pH
Microencapsulated Osmium Tetraoxide. ANew Recoverable and ReusablePolymer-Supported Osmium Catalyst forDihydroxylation of Olefins
Highly Enantioselective Synthesis of 1,3-Oxazolidin-2-imineDerivatives by Asymmetric Cycloaddition Reactions ofVinyloxiranes with Unsymmetrical Carbodiimides Catalyzed byPalladium(0) Complexes
Pd(0)/Ag+-Cocatalyzed Cyclization Reactionof 1,2-Allenic Carboxylic Acids with Aryl/Alkenyl Halides. An Efficient Synthesis ofButenolides
Synthesis of 2-Phenyl-1-(2-thienyl)- and2-Aryl-1-(2-furyl)ethanones by the SRN1Mechanism. Relative Reactivities ofEnolate Ions of Ketones
Preparation of β-Fluoro-α-ketoesters fromα-Ketoesters and Their Conversion to(Z)-β-Fluoro-α-aminoacrylate Derivatives
A Three-Step Procedure for AsymmetricCatalytic Reductive Amidation of Ketones
Stereoselective Cyclization of HighlyEnantioenriched Allylsilanes with Aldehydesvia Acetal Formation: New AsymmetricAccess to Tetrahydropyrans and Piperidines
Transition-State Mimetics for HIV Protease Inhibitors: Stereocontrolled Synthesis of Hydroxyethylene andHydroxyethylamine Isosteres by Ester-Derived Titanium EnolateSyn and Anti-Aldol Reactions
Synthesis and Synthetic Utilization of α-FunctionalizedVinylphosphonates Bearing β-Oxy or β-Thio Substituents
High Catalytic Activity of Chiral Amino Alcohol Ligands Anchoredto Polystyrene Resins
Bu3SnH-Mediated Pinacol Coupling of 1,5- and 1,6-DicarbonylCompounds: Synthetic and Mechanistic Studies
Wavelength-Dependent Photochemistry of4-Methoxybicyclo[3.1.0]hexenones
Efficient One-Pot Synthesis of Dithieno(dibenzothieno)-FusedCycloheptanones, Tropones, and Cyclooctanones
Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes.Asymmetric Synthesis of Highly FunctionalizedAminocyclopentanes Using the Bridged Mode (β-Tether) Process
Synthesis and Characterization of a Nitroxide−SemiquinoneBiradical
Intramolecular Binaphthyl Formation from Radical Cations ofTri-1-naphthyl Phosphate and Related Compounds inPhotoinduced Electron-Transfer Reactions Sensitized by9,10-Dicyanoanthracene
Kinetics of the Reactions of Benzylidene Meldrum's Acid withThiolate and Alkoxide Ions in Aqueous Dimethyl Sulfoxide
Additions of PH3 to Monosubstituted Alkenes of the FormulaH2CCH(CH2)x(CF2)yCF3: Convenient, Multigram Syntheses of aFamily of Partially Fluorinated Trialkylphosphines withModulated Electronic Properties and Fluorous Phase Affinities
Synthesis of Biphenyls Mimicking theStructure of the Antimitotic Rhazinilam
Synthesis of Chiral Nitroxides and an Unusual RacemizationReaction
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