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Solvolysis of Caryophyllen-8β-yl Derivatives: BiomimeticRearrangement−Cyclization to 12-Nor-8α-presilphiperfolan-9β-ol
A Sulfoxide-Based Ring Annelation Approach to Fused,Many-Membered Ring N,S-Heterocycles1
Intramolecular Cycloadditions of Nitrones Derived from1-Allyl-2-pyrrolecarbaldehyde as a Route to Racemic andEnantiopure Pyrrolizidines and Indolizidines
Studies on the Solvolytic Reactivity ofTertiary Chloroalkanes inHexafluoro-2-propanol by ab Initio andForce Field Calculations
A Simple Copper Catalyst for BothAziridination of Alkenes and Amination ofActivated Hydrocarbons withChloramine-T Trihydrate
Hydrated Tetrabutylammonium Fluorideas a Powerful Nucleophilic FluorinatingAgent
Synthesis of Bis(semiquinone)s and Their Electrochemical andElectron Paramagnetic Resonance Spectral Characterization
A Simple and Efficient Method for thePreparation of Hindered Alkyl−Aryl Ethers
Carbohydrate−Carbohydrate Interactions in Water withGlycophanes as Model Systems
Dehydrogenative Silylation of Terminal Alkynes Catalyzed byYtterbium−Imine Complexes
Variable-Temperature Solid-State 13C- and 15N-CPMAS NMRAnalyses of Alkyl-Substituted Porphycenes
Stereoselective Synthesis of CyclopropaneRings under Phase-Transfer-CatalyzedConditions
Anomeric Phosphorodithioates as NovelGlycosylating Agents
Thermal and Photochemical 1,3-DipolarCycloaddition of a Sulfine (FluorenethioneS-Oxide) to the Strained Triple Bond ofCyclooctyne
Asymmetric Fluorination of Enolates with NonracemicN-Fluoro-2,10-Camphorsultams
Cp2VCl2-Catalyzed Meso-Selective Pinacol Coupling Reaction ofAldimines in the Presence of Chlorosilane and Zinc Metal
Syntheses of Strychnan- and Aspidospermatan-Type Alkaloids. 11.Total Syntheses of (−)-Lochneridine and (−)- and Racemic20-epi-Lochneridine
Computational Studies of Halonium Ions of Cyclohexene andCyclopentene
Synthesis, Conformation, and Binding Properties of ResorcareneTetrasulfonates. Asymmetric Reorganization of Pendant SulfonylGroups via Intramolecular SO- - -H−O Hydrogen Bonds
Synthesis of Macrocyclic Diacyl/Dialkyl Glycerols ContainingDisulfide Tether and Studies of Their Effects upon Incorporationin DPPC Membranes. Implications in the Design of PhospholipaseA2 Modulators
Efficient Synthesis of 1,1-Diaryl 1,2-Dienesvia Pd(0)-Catalyzed Coupling of ArylHalides with Allenic/Propargylic ZincReagents
Mechanochemical Synthesis and Characterization of the FullereneDimer C120
Preparation of Chlorosilyl Enolates
Euthyroideones, Novel BrominatedQuinone Methides from the BryozoanEuthyroidesepiscopalis
Chemoselective Carbon−Carbon Couplingof Organocuprates with(Bromomethyl)methylmaleic Anhydride: Synthesis of Chaetomellic Acid A
Synthesis of Lactam and Acetamido Analogues of Sialyl Lewis xTetrasaccharide and Lewis x Trisaccharide
Stereoselection Parameters and Theoretical Model in theEnantioselective Protonation of Enolates with α-Sulfinyl Alcohols
A Novel Double Olefination. Highly Stereoselective Synthesis ofTrifluoromethylated 1,3-Butadienylphosphonates
Synthetic Studies on Quassinoids:Synthesis of (±)-Shinjudilactone and(±)-13-epi-Shinjudilactone
Face Selectivity in the Hydrogenation ofCalixarene Ethers
A New and Improved Synthesis of trans-1,2-Diiodoalkenes andTheir Stereospecific and Highly RegioselectiveTrifluoromethylation
Catalytic Isomerization of 1-Alkynyl-2,3-epoxy Alcohols toSubstituted Furans: Succinct Routes to Furanoid Fatty Acids andDifurylmethanes
Synthesis of Calix[4]arenylvinylene andCalix[4]arenylphenylene Oligomers byStille and Suzuki Cross-Coupling Reactions
Triphenylphosphine/Dichloroselenurane: ANew Reagent for a Selective Conversion ofAlcohols into Alkyl Chlorides
One-Step Palladium-Catalyzed Synthesis of SubstitutedDihydrofurans from the Carbonate Derivatives ofγ-Hydroxy-α,β-unsaturated Sulfones
Synthesis and Chiroptical Properties of Dendrimers Elaboratedfrom a Chiral, Nonracemic Central Core
Deprotection of Sulfonyl Aziridines
Competition between Hetero-Diels−Alder and CheletropicAddition of Sulfur Dioxide. Theoretical and ExperimentalSubstituent Effects on the Relative Stability of3,6-Dihydro-1,2-oxathiin-2-oxides (Sultines) and2,5-Dihydrothiophene-1,1-dioxides (Sulfolenes). Anomeric Effectsin Sultine and 6-Substituted Derivatives
Carbocationic Rearrangements of Silphinane Derivatives
Use of Fluorine Kinetic Isotope Effects in the Study of StericEffects in Nucleophilic Aromatic Substitution Reactions
Design, Synthesis, and Application of a C2 Symmetric ChiralLigand for Enantioselective Conjugate Addition of Organolithiumto α,β-Unsaturated Aldimine
Oxoammonium Salts. 6.4-Acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammoniumPerchlorate: A Stable and Convenient Reagent for the Oxidationof Alcohols. Silica Gel Catalysis
Syntheses of (Trifluoromethyl)imidazoles with AdditionalElectronegative Substituents. An Approach to Receptor-ActivatedAffinity Labels
Toward an Understanding of the Molecular Mechanism of theReaction between 1-Methylpyrrole and DimethylAcetylenedicarboxylate. An ab Initio Study
Kinetics of the Self-Assembly of α-Cyclodextrin[2]Pseudorotaxanes with1,12-Bis(4-(α-alkyl-α-methylmethanol)pyridinium)dodecaneDications in Aqueous Solution
Photochromism of Dithienylethenes Included in Cyclodextrins
Synthesis and Cytotoxicity of5-Amino-1-(chloromethyl)-3-[(5,6,7-trimethoxyindol-2-yl)carbonyl]-1,2-dihydro-3H-benz[e]indole (Amino-seco-CBI-TMI) andRelated 5-Alkylamino Analogues: New DNA Minor GrooveAlkylating Agents
Carbocyclization Reaction of Active Methine Compounds withUnactivated Alkenyl or Alkynyl Groups Mediated by TiCl4−Et3N
Highly Diastereoselective Pinacol Couplingof Secondary Aliphatic Aldehydes Induced by a Catalytic SystemConsisting of Vanadium Complex, Chlorosilane, and ZincMetal
A FacileSynthesis of 5-Mesyl-3-benzylbenz[e]indole: Implications for theInvolvement of a p-Quinone Methide Intermediate
Bicyclization of Enynes Using the Cp2TiCl2−Mg−BTC System: APractical Method to Bicyclic Cyclopentenones
Sonochemical Reactions of LeadTetracarboxylates with Styrene
Efficient Synthesis of (±)-, (+)-, and (−)-Conduritol C viaPalladium(II)-Catalyzed 1,4-Diacetoxylation in Combination withEnzymatic Hydrolysis
Hydrogenation of the Carbonyl Group in α-Ketoesters andα-Ketoamides Catalyzed by Ruthenium Clay
Sch 217048: A Novel Cyclodepsipeptidewith Neurokinin Antagonist Activity
A Second-Generation Radical-BasedSynthesis of (+)-7-Deoxypancratistatin
Preparation of(S)-3-Carbethoxy-3-benzylpiperidine andthe Growth Hormone SecretagogueL-163,540
Syntheses of Strychnan- and Aspidospermatan-Type Alkaloids. 10.An Enantioselective Synthesis of (−)-Strychnine through theWieland−Gumlich Aldehyde
Bicyclic Carbopalladation Reaction with Twogem-Reaction Centers. Efficient Constructionof Fused Bicyclic Skeletons
Protecting/Radical Translocating ChiralAuxiliaries: A New Concept inRadical-Mediated Asymmetric Synthesis
Trimethyl Orthoformate as a HighlySelective Mono-C-Methylating Agent forArylacetonitriles
Synthesis and Reactivity of Calix[4]arene-Based CopperComplexes1
Haller−Bauer-Type Cleavage ofCyclobutabenzofuranones
Catalytic Asymmetric Oxidation of Aryl Sulfides with a Ti/H2O/(R,R)-Diphenylethane-1,2-diol Complex: a Versatile and HighlyEnantioselective Oxidation Protocol
Highly 1,4-Syn Diastereoselective,Phosphoramide-Catalyzed Aldol Additionsof Chiral Methyl Ketone Enolates
Carbonyl Oxide Chemistry. 6.N-(Hydroperoxyalkyl)keto Nitrones andα-Oxime Ether Hydroperoxides viaDisubstituted Carbonyl Oxides andOximes
Development of the HofmannRearrangement of Nα-Tosylasparaginethrough Calorimetric and NMR Analysis
Reactivity of Organocerium Compoundswith Allyl Alcohols
A General, Stereocontrolled Route to theGeissoschizine Family of Alkaloids. ConciseSynthesis of the Apogeissoschizine Skeleton
A Formal Total Synthesis of Epothilone A: Enantioselective Preparation of the C1−C6and C7−C12 Fragments1
An Unexpectedly Small α-Effect inNucleophilic Attack at sp-Hybridized Carbon:Michael-Type Additions of Primary Amines to3-Butyn-2-one
Macrocyclic Amides Consisting of Helical Chiral1,12-Dimethylbenzo[c]phenanthrene-5,8-dicarboxylate
Di- and Tri-1-(1-naphthyl)ethylamino-Substituted 1,3,5-TriazineDerivatives: A New Class of Versatile Chiral Auxiliaries for NMRSpectroscopy
Grignard Addition to Aldonitrones. Stereochemical Aspects andApplication to the Synthesis of C2-Symmetric Diamino Alcoholsand Diamino Diols
Total Synthesis of Robustaflavone, a Potential Anti-Hepatitis BAgent
A High Yielding Chemical Synthesis of Sialyl Lewis xTetrasaccharide and Lewis x Trisaccharide; Examples of Regio-and Stereodifferentiated Glycosylations
Enantiospecific Total Synthesis of theSarpagine Related Indole Alkaloids Talpinineand Talcarpine: The Oxyanion−CopeApproach
Selenium-Linking Strategy for Traceless Solid-Phase Synthesis: Direct Loading, Aliphatic C−H Bond Formation upon Cleavageand Reaction Monitoring by Gradient MAS NMR Spectroscopy
Competition of Mechanisms in the Photochemical Cleavage of theC−X Bond of Aryl-Substituted Vinyl Halides
Synthesis of Active Antifeedant CDE Fragments of11-Ketoepoxyazadiradione Based on an ElectrocyclizationReaction Catalyzed by Perchloric Acid
Asymmetric Rh-Catalyzed Hydrogenationof Enamides with a Chiral1,4-Bisphosphine BearingDiphenylphosphino Groups
Intramolecular Cyclizations of Enynes UsingRuClH(CO)(PPh3)3
Stereochemical Research on the Hydrolysis of Optically PureSpirosulfuranes: Efficient Synthesis of Chiral Sulfoxides withCompletely Opposite Stereochemistry
Novel Preparation of Orthoquinol Acetatesand Their Application in OxygenHeterocyclization Reactions
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