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Acyclic Stereodifferentiation: SelectiveConstruction of Tetrahydropyran/Oxepanevia Intramolecular Nitrone−AlkeneCycloaddition of Acyclic3-O-Allylmonosaccharides
Regioselective Porphyrin Bridge Cleavage Controlled byElectronic Effects. Coupled Oxidation of3-Demethyl-3-(trifluoromethyl)mesohemin IX and Identification ofIts Four Biliverdin Derivatives
Radical Ion Probes. 9. The Chemistry of Radical Cations Derivedfrom 9-Cyclopropylanthracene and9-Bromo-10-cyclopropylanthracene
Stereoselective Synthesis of a Key Precursor of Halicholactoneand Neohalicholactone
Total Synthesis of (±) Carbocyclic Polyoxin C and Its α-Epimer
An Enantioselective Synthesis of Cis PerhydroisoquinolineLY235959
Total Synthesis of (±)-Tremulenolide A and (±)-Tremulenediol Avia a Stereoselective Cyclopropanation/Cope RearrangementAnnulation Strategy
Free-Radical Reactions of Trialkylboranes with β-Nitrostyrenes ToGenerate Alkenes
The Hetero Diels−Alder Reactions betweend-Mannose-Derived HalonitrosoCompounds and Cyclopentadiene: Scopeand Limitations
Solid Phase Synthesis of β-Peptoids: N-Substitutedβ-Aminopropionic Acid Oligomers
A New Facile Anionic Domino RingExpansion of Cyclopentanones by Two andThree Carbons for the Flexible Preparationof Functionalized Seven- andEight-Membered Rings
The Role of Nonaromatic Isomers in thePhotochemistry of 3,5-DimethoxybenzylAcetate
Photoinduced Coupling of Acetylenes and Quinone in theSolid State as Preorganized Donor−Acceptor Pairs
Mechanism of Amine-Catalyzed Ester Formation from an AcidChloride and Alcohol
An Activated Germanium Metal-Promoted, HighlyDiastereoselective Reformatsky Reaction
Oxidative Pictet−Spengler Cyclizations
A Soluble Polymer Approach to the“Fishing Out” Principle: Synthesis andPurification of β-Amino Alcohols
Steric Course of the Methyl Transfer fromAdoMet to S-Farnesyl-3-thiopropionate byG-Protein Methyltransferase
Investigations on New Strategies for the Facile Synthesis ofPolyfunctionalized Phosphinates: Phosphinopeptide Analogues ofGlutathionylspermidine
The First Cembrane−PseudopteraneCycloisomerization
Metathesis Route to Resin Glycosides: Formal Total Synthesis of Tricolorin A
Sequential Ketyl−Olefin Coupling/β-Elimination ReactionsMediated by Samarium(II) Iodide
Application of 13C NMR Spectroscopy and 13C-LabeledBenzylammonium Salts to the Study of Rearrangements ofAmmonium Benzylides
Sodium N-Chlorobenzenesulfonamide as a Selective Oxidant forHexosamines in Alkaline Medium: A Kinetic and MechanisticStudy
Amino Zinc Enolate Carbocyclization Reactions. New Access toPolysubstituted Piperidine Derivatives
Synthesis, Structural Analysis, and Properties ofN-Alkylglucosyl(meth)acrylamides: New Reactive SugarSurfactants
Conformational Study of Some Saturated2-[Bis(2-chloroethyl)amino]-1,3,2-benzoxazaphosphorinane2-Oxides
Fluorination with XeF2. 44. Effect ofGeometry and Heteroatom on theRegioselectivity of Fluorine Introductioninto an Aromatic Ring
An Oxidative Mannich Cyclization Methodology for theStereocontrolled Synthesis of Highly Functionalized Piperidines
Absolute Rate Constants for α-Amide Radical Reactions
A Synthesis of (+)-Cyclophellitol fromd-Xylose
Cation Complexation by Chemically Modified Calixarenes. 11.Complexation and Extraction of Alkali Cations by Calix[5]- and-[6]arene Ketones. Crystal and Molecular Structures ofCalix[5]arene Ketones and Na+ and Rb+ Complexes
The Ugi Five-Component CondensationUsing CO2, CS2, and COS as OxidizedCarbon Sources
Diastereoselectivity in Organometallic Additions to the CarbonylGroup of Protected Erythrulose Derivatives
[3 + 2] Cycloaddition of Nonstabilized Azomethine Ylides. 7.Stereoselective Synthesis of Epibatidine and Analogues,
Synthesis and Characterization of Phenylnitroxide-SubstitutedZinc(II) Porphyrins
Rhodium-Catalyzed Insertion of Carbenoidsinto β C−H Bonds of Silacycloalkanes: AFacile and General Approach toFunctionalized Silacycloalkanes
A Highly Efficient and Practical Synthesisof Chromene Derivatives UsingRing-Closing Olefin Metathesis
Photochemistry of Diaryl Vicinal Tetraketones and Chemistry ofIntermediate (Aroyloxy)arylketenes1
Parabolic Relationship between the Basicity of the Nucleophileand π-Face Selection in Addition of the Substituted Acetylide Ionsto Cyclohexanone and Cyclohexanethione
Substituent Effects on Vinyl Radical Cyclizations onto Aryl Rings
Rearrangement of a Homoallylic Alcohol via an Acid-Catalyzed1,4-Hydride Shift Yields a Saturated Ketone
Reaction of Resorcinol with α,β-Unsaturated Ketones
Chiroptical Properties of the Ketene and Diazo Chromophores. 1.Conformation and Optical Activity of 1-Alken-1-ones and1-Diazoalkanes vs Aldehydes
Misacylated Transfer RNAs Having a Chemically RemovableProtecting Group
Probing the Phytopathogenic BlacklegFungus with a Phytoalexin Homolog
The Unique Behavior of a Chiral BinaphthylOxazoline in the Presence of Cu(I) and ItsRole as a Chiral Catalyst
Asymmetric Synthesis of Water-Soluble,Nonhydrolyzable Phosphonate Analogue ofPhosphatidylinositol 4,5-Bisphosphate
Mechanism of Hydrolysis of Isopropenyl Glucopyranosides.Spectroscopic Evidence Concerning the Greater Reactivity of theα Anomer
Synthesis and Characterization of a Highly Potent and SelectiveIsotopically Labeled Retinoic Acid Receptor Ligand, ALRT1550
Monosubstituted Oxazoles. 1. Synthesis of 5-Substituted Oxazolesby Directed Alkylation
Ortho-Directed Metalation of3-Carboxy-β-carbolines: Use of theSmI2-Cleavable9-N-(N‘,N‘-Dimethylsulfamoyl) BlockingGroup for the Preparation of9-N-Deprotected 4-Amino Derivatives viaAzide Introduction or aPalladium-Catalyzed Cross-CouplingReaction
Highly Regioselective Thioselenation ofAcetylenes by Using a (PhS)2−(PhSe)2Binary System
Synthesis and Reactivity of Optically Active Spiroketals byRing-Expansion of Chromium Carbene Complex-DerivedCyclobutanones
One-Pot Sequential AsymmetricHydrogenation Utilizing Rh(I) and Ru(II)Catalysts
Generation and Cyclization of aBenzyne-Tethered Alkyllithium: Preparationof 4-Substituted Indans
Synthesis of a Three-Helix Bundle Protein by ReductiveAmination
Synthesis and Herbicidal Activity of [3R*,5S*,6S*]-3-Benzyloxy-5-methoxy-1,7-dioxaspiro[5.5]undecane and[3R*,5S*,6S*]-3-Methoxy-5-benzyloxy-1,7-dioxaspiro[5.5]undecane
Intramolecular Homolytic Translocation Chemistry: An ab InitioStudy of 1,n-Halogen Atom Transfer Reactions in Someω-Haloalkyl Radicals
Alkylboranes in the Suzuki−Miyaura Coupling: Stereochemicaland Mechanistic Studies
Asymmetric Ring-Closing Metathesis Catalyzed by ChiralMolybdenum Alkylidene Complexes
Highly Regioselective Nitration Reactions Provide a VersatileMethod of Functionalizing Benzocycloheptapyridine TricyclicRing Systems: Application toward Preparation of NanomolarInhibitors of Farnesyl Protein Transferase
Chemoenzymatic Synthesis of All Four Stereoisomers ofSphingosine from Chlorobenzene: Glycosphingolipid Precursors1a
Synthesis of the Pentacyclic Skeleton of the AspidospermaAlkaloids Using Rhodium Carbenoids as Reactive Intermediates
Synthesis of α- and β-C-Aryl Δ2-Glycopyranosides fromp-tert-Butylphenyl Δ2-Glycopyranosides via Grignard Reagents
Reversible and Irreversible ElcB Mechanisms in the Hydrolysis of2,2,2-Trifluoroethanesulfonyl Chloride: Carbanion Intermediatesin Aqueous Acid1
8-Purinyl versus 2-Benzimidazolyl Carbanions: Charge Demandsof the Heterocycles and Ligand Properties of theBis(heteroaryl)methanes1
The Principle of Maximum Chiral Discrimination: ChiralRecognition in Permethyl-β-cyclodextrin
A New Palladium-Catalyzed Intramolecular Allylation toPyrrolidin-2-ones1
Synthesis of Discodermolide Subunits by SE2‘ Addition ofNonracemic Allenylstannanes to Aldehydes
Transmetalation of Alkylboranes to Palladium in the SuzukiCoupling Reaction Proceeds with Retention of Stereochemistry
Exploring the Reactivity of Dioxacyclic Compounds as a Route toPolysubstituted Decalins and Fused Polycycles
Key Intermediates in Combinatorial Chemistry: Access to VariousHeterocycles from α,β-Unsaturated Ketones on the Solid Phase
Stereo- and Regioselective Introduction of 1- or 2-HydroxyethylGroup via Intramolecular Radical Cyclization Reaction with aNovel Silicon-Containing Tether. An Efficient Synthesis of4‘α-Branched 2‘-Deoxyadenosines1
Synthesis and Characterization of theFood-Derived Carcinogens2-(Hydroxylamino)-α-carboline and2-(Hydroxylamino)-3-methyl-α-carboline
A Diastereospecific Synthesis of2-Methyl-5β-phenyl-5α-carbethoxy-2-azabicyclo[2.2.1]heptane: A Ring-ConstrainedAnalogue of Meperidine
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