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À propos de : Mechanistic Distinctions between Cation Radical and CarbocationPropagated Polymerization        

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  • Mechanistic Distinctions between Cation Radical and CarbocationPropagated Polymerization
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  • The polymerization of bis[4-(1-propenyl)phenyl] etherin the presence of tris(4-bromophenyl)aminiumhexachloroantimonate is found to occur by competing cation radical andcarbocation pathways.These pathways involve, respectively, cyclobutanation and linearaddition. Methods for favoringeach mechanistic type are proposed and explored.
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