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A Study Directed to the Asymmetric Synthesis of theAntineoplastic Macrolide Acutiphycin under EnantioselectiveAcyclic Stereoselection Based on ChiralOxazaborolidinone-Promoted Asymmetic Aldol Reactions
Didemniserinolipids A−C, UnprecedentedSerinolipids from the Tunicate Didemnumsp.
Adociasulfates 1, 7, and 8: New Bioactive HexaprenoidHydroquinones from the Marine Sponge Adocia sp.
in- and out-Cyclophanes Bearing Non-HydrogenBridgehead Substituents
Alkynyliodonium Salts in Organic Synthesis. Preparation ofAnnelated Dihydropyrroles by Cascade Addition/Bicyclization ofDienyltosylamide Anions with Phenyl(propynyl)iodonium Triflate
Study on the Isomerization of1-Acylazetidine. A Comparative Study withthe Case of 1-Acylaziridine
First Stereocontrolled Synthesis of the (3S,5R,7R,10R,11R)-C1−C13Fragment of Nystatin A1
Formal Synthesis of (+)- and (−)-Perhydrohistrionicotoxin: A“Double Henry”/Enzymatic Desymmetrization Route to the KishiLactam1
Novel Water-Soluble Bisphosphinite Chiral Ligands Derived fromα,α- and β,β-Trehalose. Application to Asymmetric Hydrogenationof Dehydroamino Acids and Their Esters in Water or an Aqueous/Organic Biphasic Medium
Molecular Mechanics (MM3) Calculations on Oxygen-ContainingPhosphorus (Coordination IV) Compounds
A Simple Method for the SelectiveDeprotection of p-Methoxybenzyl Ethers byCerium(III) Chloride Heptahydrate andSodium Iodide
Ortho-Directed Lithiation of ω-Phenoxy Alcohols
Stereoselective Synthesis of Fused Bicyclic β-Lactams throughRadical Cyclization of Enyne-2-azetidinones1
Kinetics and Mechanism of the Aminolysis of Phenyl and Methyl4-Nitrophenyl Thionocarbonates
Synthesis of Enantio- and Diastereomerically Pure, Tetra- andPenta-Substituted Cyclopentanes by the Desymmetrization ofendo-Norborn-5-ene-2,3-dicarboxylic Anhydrides
Conformational Control in the Rebeccamycin Class ofIndolocarbazole Glycosides
Ab Initio Study of Intramolecular Ring Cyclization of Protonatedand BF3-Coordinated trans- and cis-4,5-Epoxyhexan-1-ol
New Proton-Ionizable Lariat Ethers with Picrylamino-Type SideArms and Their Alkali Metal Salts. Synthesis and StructuralStudies1
Mechanism of Alkaline Hydrolysis of Some HO-π-COOAr AcylDerivatives
A Novel, Nonaqueous Method forRegeneration of Aldehydes from BisulfiteAdducts
Toward Enediyne Mimics: Methanolysis of Azoesters and aBisazoester
Thiourea: A Novel Cleaving Agent for1,3-Dioxolanes
Synthesis and Characterization ofOligonucleotides Containing2‘-S,3‘-O-Cyclic Phosphorothiolate Termini
A Convenient Method for the Preparationof N2-Ethylguanine Nucleosides andNucleotides
Conformational Switching and the Synthesis ofSpiro[2H-indol]-3(1H)-ones by Radical Cyclization
Manganese Tetraphenylporphyrin-Catalyzed StereoselectiveEpoxidation of Thymidine Nucleosides
Air Oxidation of 2-Aryl-1-tetralones inBasic, Neutral, and Acidic Media: AnUnprecedented Oxidative Aryl Migrationto 2-Aryloxy-1-naphthols under AcidicCondition
Debrominations of vic-Dibromides withDiorganotellurides. 3. Rate Constants,Eyring and Arrhenius ActivationParameters, and Mechanistic Implications
New Strategies for the Synthesis of Fluorinated VinylogousAmidines and β-Enamino Ketones
Room-Temperature Palladium-Catalyzed Amination of ArylBromides and Chlorides and Extended Scope of Aromatic C−NBond Formation with a Commercial Ligand
Conformational Preferences of2,3,3a,8a-Tetrahydrofuro[2,3-b]benzofuran.The Chemical Modifications Drive thePseudorotational Preferences
Highly Conjugated Molecules from Dibromonaphthyl Derivativesand 4-Vinylpyridine or 4-Acetoxystyrene by the Heck Reaction
Methylenecyclopropane Rearrangement as a Probe for FreeRadical Substituent Effects. σ • Values for PotentRadical-Stabilizing Nitrogen-Containing Substituents
Are the Duocarmycin and CC-1065 DNA Alkylation ReactionsAcid-Catalyzed? Solvolysis pH−Rate Profiles SuggestThey Are Not
Extended Alkenyl Glycosides by Ruthenium-CatalyzedCross-Metathesis Reaction and Application toward NovelC-Linked Pseudodisaccharides
Chiral N-Acyl-tert-butanesulfinamides: The “Safety-Catch”Principle Applied to Diastereoselective Enolate Alkylations
Regioselective Introduction of Electrophiles in the 4-Position of1-Hydroxypyrazole via Bromine−Lithium Exchange
A Versatile Enantioselective Strategy Toward l-C-Nucleosides: ATotal Synthesis of l-Showdomycin
Synthesis of Catenane Structures via Ring-Closing Metathesis
Catalytic Asymmetric Cyclocarbonylation of Nitrogen-ContainingEnynes
N-Fluoro-3-cyclohexyl-3-methyl-2,3-dihydrobenzo[1,2-d]isothiazole 1,1-Dioxide: An Efficient Agent for ElectrophilicAsymmetric Fluorination of Enolates
Unique Solvent-Dependent Atropisomerism of a Novel CytotoxicNaphthoxanthene Antibiotic FD-594
Sequoiatones A and B: Novel Antitumor Metabolites Isolated froma Redwood Endophyte
Valence Bond Isomerization of Fused [1,2,3]Triazolium Salts withBridgehead Nitrogen Atom. Fused Azolium Salts. 19,
Synthesis and Biological Activity of 25-Methoxy-, 25-Fluoro-, and25-Azabrassinolide and 25-Fluorocastasterone: Surprising Effectsof Heteroatom Substituents at C-25
New Homochiral Ligands Bearing Nonstereogenic ChirotopicCenters. Lithiated N,N‘-Dialkylureas as Chiral Bases andSterically Crowded Phosphines for Asymmetric Catalysis
Origin of π-Facial Stereoselectivity in Nucleophilic Additions.Application of the Exterior Frontier Orbital Extension Model toImines and Iminium Ions
The CH by N Replacement Effects on the Aromaticity andReactivity of Phosphinines
Regioselective Photodimerization of9-Substituted Acridizinium Salts in theSolid State
Theoretical Study of the Conformations and Strain Energies of[n,n]Metaparacyclophanes: Indication of Stable Edge-to-Face andDisplaced Face-to-Face Conformers for n = 4
Studieson a Dithiane-Protected Benzoin Photolabile Safety Catch Linkerfor Solid-Phase Synthesis
C-Glycosyl Tyrosines. Synthesis and Incorporation intoC-Glycopeptides
Enantiospecific Synthesis of (+)-Nemorensic Acid, a Necic AcidComponent of the Macropyrrolizidine Alkaloid, Nemorensine
Synthesis of β-d-Galactosyl Ceramide Methylene Isostere
An Experimental and Computational Study about the Effect of aSpirocyclopropane Group on the Solvolysis Rates of BridgeheadTriflates
Adociasulfates 1−6, Inhibitors of Kinesin Motor Proteins from theSponge Haliclona (aka Adocia) sp.
Photoinduced C−F Bond Cleavage in Some Fluorinated7-Amino-4-quinolone-3-carboxylic Acids
Chemical Study and Absolute Configuration of a New MarineSecospatane from the Brown Alga Dilophus okamurae
Amidrazone and Amidoxime Inhibitors of Squalene HopeneCyclase
Novel 3-Aza-Grob Fragmentation inHydride Reduction of Ether-ProtectedAromatic Lactams
Synthetic and Mechanistic Aspects of the Reaction of1,1-Difluoro-2,2-bis(dimethylamino)ethene with Ethyl Propiolate
The Reactions of O2 (1Δg) with Anancomeric 1,3-Dithianes. TheFirst Experimental Evidence in Support of a HydroperoxySulfonium Ylide as a Precursor to Sulfoxide on the Sulfide SingletOxygen Reaction Surface
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