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1999
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Copyright © 1999 American Chemical Society
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8
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On the Stability and the Bonding Model of n→σ* Type MolecularComplexes, R2Z−X−X: Proposal of 3c-4e Description for Z−X−X inthe Adducts
Prunolides A, B, and C: Novel Tetraphenolic Bis-Spiroketals fromthe Australian Ascidian Synoicum prunum
Carbocupration of Diethyl 1-AlkynylPhosphonates: Stereo- and RegioselectiveSynthesis of 1,2,2-Trisubstituted VinylPhosphonates
Molybdenum(II)-Catalyzed Allylation of Electron-Rich Aromaticsand Heteroaromatics
New Preparations of CyanophosphonateSalts
Palladium-Catalyzed Allylic Alkylations viaTitanated Nucleophiles: A New Early−LateHeterobimetallic System
Orbital Interactions and Solvent Effects Determining the Stabilityof Condensed Cyclopentadienides in Solution
Tris(trifluoromethanesulfonyl)methide(“Triflide”) Anion: ConvenientPreparation, X-ray Crystal Structures, andExceptional Catalytic Activity as aCounterion with Ytterbium(III) andScandium(III)
Submonomer Solution Synthesis ofHydrazinoazapeptoids, a New Class ofPseudopeptides
Mischmetall: An Efficient and Low CostCoreductant for Catalytic Reactions ofSamarium Diiodide
Total Synthesis of (+)-Polyoxin J
Preparation and Synthetic Applications of Enantiopure (2S,3S)- or(2R,3S)-2-Halomethyl-1,2-epoxyalkan-3-amines
Diverging Effects of Steric Congestion on the Reaction ofTributylstannyl Radicals with Areneselenols and Aryl Bromidesand Their Mechanistic Implications
Total Synthesis of (+)-Obtusenyne
Chemistry of Zerumbone. 1. Simplified Isolation, ConjugateAddition Reactions, and a Unique Ring Contracting TransannularReaction of Its Dibromide
Alkoxy-Directed Radical Reductions ofKetones Using Trichlorosilane
Synthesis of Lipophilic Paramagnetic Contrast Agents
Manifestations of Bridgehead−Bridgehead Interactions in theBicyclo[1.1.1]pentane Ring System
New Lewis-Acidic Molybdenum(II) and Tungsten(II) Catalysts forIntramolecular Carbonyl Ene and Prins Reactions. Reversal of theStereoselectivity of Cyclization of Citronellal
Quararibea Metabolites. 4. Total Synthesis and ConformationalStudies of (±)-Funebrine and (±)-Funebral
Intramolecular Anodic Olefin Coupling Reactions: The Use ofAllylsilane Coupling Partners with Allylic Alkoxy Groups
Unsaturated Nitriles: Precursors for a Domino Ozonolysis−AldolSynthesis of Oxonitriles
Phosphodiester Alkylation with a Quinone Methide
Kinetics of the Reaction of β-Methoxy-α-nitrostilbene withCyanamide in 50 DMSO−50 Water. Failure to Detect the SNVIntermediate
Design of New Organic Gelators Stabilizedby a Host−Guest Interaction
β-Silyl and β-Germyl Carbocations Stable at Room Temperature
Molybdenum(II)- and Tungsten(II)-Catalyzed Allylic Substitution
Development of a Second Generation Coenzyme A AnalogueSynthon
Unusual Formation of a Cyclyne Dimerand an Indenoindene Derivative
Enantioselective Photochemical Reactions of N-PhenylEnaminones in Inclusion Complex Crystals Using a Chiral HostCompound
Applications of 5-Endo-trigonal Cyclization: Construction ofCompounds Relevant to the Synthesis of Prostaglandins andMethyl epi-Jasmonate
Efficient Pd-Catalyzed Heterobenzylic Cross-Coupling UsingSulfonium Salts as Substrates and (PhO)3P as a SupportingLigand
Synthesis of New PolymerizableMetal-Chelating Lipids
Molecular Basis for Enantioselectivity of Lipase fromPseudomonas cepacia toward Primary Alcohols. Modeling,Kinetics, and Chemical Modification of Tyr29 to Increase orDecrease Enantioselectivity
A Two Steps Synthesis of γ-Substituted andγ,γ-Disubstitutedα-(Alkylmethylene)-γ-butyrolactones
Acylnitrene Route to Vicinal Amino Alcohols. Application to theSynthesis of (−)-Bestatin and Analogues
Cesium Fluoride Catalyzed Trifluoromethylation of Esters,Aldehydes, and Ketones with (Trifluoromethyl)trimethylsilane
Enantioselective Synthesis of α-AminoAcids from Chiral1,4-Benzodiazepine-2,5-diones Containingthe α-Phenethyl Group
Total Synthesis of Motuporin and 5-[l-Ala]-Motuporin
Organic-Fluorous Phase Switches: A Fluorous Amine Scavengerfor Purification in Solution Phase Parallel Synthesis
Electron Transfer Catalyzed [2 + 2] Cycloreversion of BenzeneDimers
Reactivity and Synthetic Utility of1-(Arenesulfonyloxy)benziodoxolones
Selective Inhibition of Type IIDehydroquinases
Chiral π-Allylpalladium-CatalyzedAsymmetric Allylation of Imines: Replacement of Allylstannanes byAllylsilanes
7-Hydroxymethyl-6-methyl-1-oxa-4-thiaspiro[4.5]dec-6-ene. Exceptionally HighAnti to Sulfur Diastereoselectivity underConditions of Johnson Ortho Ester ClaisenRearrangement Favors Cieplak Mode ofDiastereoselection
Stereoselective Cross-Coupling of BenzylicBromides and Vinyl Stannanes
A Pyrazole to Furan Rearrangement. Thermolysis of5-Azido-4-formylpyrazoles
Diastereoselective Hydroboration ofIsopropenylcyclopropanes
Electron-Transfer Nucleophilic Substitution Reactions onNeopentyl- and Phenyl-Substituted Alkyl Chlorides. Effect of theBridge Length on the Intramolecular Electron-Transfer Catalysis
Total Synthesis of (−)-Coriolin
Lateral Stereocontrol Using π-Allylmolybdenum Systems: The Useof Methyl Substitution To Effect Conformational Control Leadingto High Levels of Stereoselectivity
1,4-Naphthoquinone Disulfides and MethylSulfides: Self-Assembled Monolayers onGold Substrates
Synthesis of Calix[4]arenes with Four Different “Lower Rim”Substituents
Regiocontrolled Cyclization Reaction ofN-(2-Hydroxyethyl)ureas by Transfer ofActivation: One-Pot Synthesis of2-Imidazolidinones
Hydrotalcite-Catalyzed Epoxidation ofOlefins Using Hydrogen Peroxide andAmide Compounds
Synthesis and Biological Evaluation of Novel Paclitaxel (Taxol)D-Ring Modified Analogues
Nucleobase Recognition by Artificial Receptors Possessing aFerrocene Skeleton as a Novel Modular Unit for HydrogenBonding and Stacking Interactions
Investigation of Conditions Giving Minimal Scrambling in theSynthesis of trans-Porphyrins from Dipyrromethanes andAldehydes
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