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Alkyl- and Arylthiodediazoniations of Dry Arenediazoniumo-Benzenedisulfonimides. Efficient and Safe Modifications of theStadler and Ziegler Reactions to Prepare Alkyl Aryl and DiarylSulfides
One-Step Synthesis of Biotinyl Photoprobes from UnprotectedCarbohydrates
A One-Step Synthesis of MonoprotectedPolyethylene Glycol Ethers
Regioselective Ring Opening of Malic AcidAnhydrides by Carbon Nucleophiles.Application in the Synthesis of ChiralTetronic Acids
Donor/Acceptor Fulleropyrrolidine Triads
A Universal OrganicSolvation Model.
Highly Efficient Selective Monohydrolysisof Symmetric Diesters
Regeneration of PAPS for the Enzymatic Synthesis of SulfatedOligosaccharides
Stereodivergent Approaches to the Synthesis of IsoxazolidineAnalogues of α-Amino Acid Nucleosides. Total Synthesis ofIsoxazolidinyl Deoxypolyoxin C and Uracil Polyoxin C
Zinc-Mediated Chain Extension of β-Keto Phosphonates
Mechanistic Evaluation of the Halocyclization of 4-Penten-1-ol bySome Bis(2-substituted pyridine) and Bis(2,6-disubstitutedpyridine)bromonium Triflates
New Generation of Organosilyl Radicals by PhotochemicallyInduced Homolytic Cleavage of Silicon−Boron Bonds
An Activated O → N Acyl Transfer Auxiliary: EfficientAmide-Backbone Substitution of Hindered “Difficult” Peptides
Synthesis of 3, 4-O-Isopropylidene-(3S,4S)-dihydroxy-(2R,5R)-bis(diphenylphosphino)hexane and ItsApplication in Rh-Catalyzed HighlyEnantioselective Hydrogenation ofEnamides
Vinyl and Alkynyl Pyrimidines as Michael Acceptors: AnApproach to a Cylindrospermopsin Substructure
Cyclohexadienone Diazeniumdiolates from Nitric Oxide Additionto Phenolates
Asymmetric Syntheses of (−)-8-epi-Swainsonine Triacetate and(+)-1,2-Di-epi-swainsonine. Carbonyl Addition Thwarted by anUnprecedented Aza-Pinacol Rearrangement
Synthesis ofAryldifluoromethylphosphonothioic Acidsfrom O,O-DiethylAryldifluoromethylphosphonothioates
Designing Large Triangular Chiral Macrocycles: Efficient [3 + 3]Diamine−Dialdehyde Condensations Based on ConformationalBias
Conformational Analysis in Solution of C2-Symmetric1,1‘-Binaphthyl Derivatives by Circular Dichroism Spectroscopyand Cholesteric Induction in Nematic Mesophases
Oxidation of Methyl Trimethylsilyl Ketene Acetals toα-Hydroxyesters with Urea Hydrogen Peroxide Catalyzed byMethyltrioxorhenium
Optimized Synthesis of Cavitand PhenolBowls
New and Highly Efficient Synthesis of Cis- and Trans-OpenedBenzo[a]pyrene 7,8-Diol 9,10-Epoxide Adducts at the ExocyclicN2-Amino Group of Deoxyguanosine
Dimethyl Azo(bisisobutyrate) and C60 Produce 1,4- and1,16-Di(2-carbomethoxy-2-propyl)-1,x-dihydro[60]fullerenes
Effect of Ligand Structure in theBisoxazoline Mediated AsymmetricAddition of Methyllithium to Imines
Enantioselective Reduction of OximeEthers with Borane Catalyzed byPolymer-Supported 2-Piperazinemethanol
A New Synthetic Methodology forTiazofurin
Steric Influence of E- or Z-Monosubstituted and TerminallyDisubstituted Vinyl Groups in Matrix-IsolatedCyclopentane-1,3-diyl Triplet Diradicals as Probed by theZero-Field EPR D Parameter
Amination of Bis(trimethylsilyl)-1,2-bisketene with SecondaryAmines: Formation of Aminodihydrofuranones
First TiCl4-Mediated DiastereoselectiveReduction of α-Nitro Ketones toAnti-β-Nitro Alcohols by BH3·SMe2
Conformational Design for 13α-Steroids
A Direct Retro-Barbier Fragmentation
Reaction of Nitric Oxide at the β-Carbon of Enamines. A NewMethod of Preparing Compounds Containing theDiazeniumdiolate Functional Group
Type-Two Intramolecular Diels−Alder Reactions ofPyrazolo-o-quinodimethanes
Asymmetric Conjugate Additions of Chiral Phosphonamide Anionsto α,β-Unsaturated Carbonyl Compounds. A Versatile Method forVicinally Substituted Chirons
Verrillin: A Highly Oxygenated MarineDiterpene Based on the Novel VerrillaneCarbon Skeleton
Hydrogen-Atom Abstraction/Cyclization in Synthesis. DirectSyntheses of Coumestan and Coumestrol
Kinetic Studies on the Thermal Cis−Trans Isomerization of1,3-Diphenyltriazene in Aqueous Solution. Effects of Acids andBases
Toward an Understanding of the Mechanisms of theIntramolecular [5 + 2] Cycloaddition Reaction of γ-PyronesBearing Tethered Alkenes. A Theoretical Study
A New Route to Diastereomerically Pure Cyclopropanes UtilizingStabilized Phosphorus Ylides and γ-Hydroxy Enones Derived from1,2-Dioxines: Mechanistic Investigations and Scope of Reaction
Selective Synthesis of Novel Cyclic Phenylazomethine Trimers
Ab Initio Computational Studies of Conformationally RestrictedCope Rearrangements. First Examples of Fully Concerted AllenylCope Rearrangements
Total Synthesis of (±)-2-Isocyanoallopupukeanane
Diastereoselective Ring-Closing Metathesis in the Synthesis ofDihydropyrans
6-s-cis Locked Analogues of the Steroid Hormone1α,25-Dihydroxyvitamin D3. Synthesis of Novel A-RingStereoisomeric 1,25-Dihydroxy-3-epi-19-nor-previtamin D3Derivatives
Oxazolium-Derived Azomethine Ylides. External OxazoleActivation and Internal Dipole Trapping in the Synthesis of anAziridinomitosene
Ferromagnetic Spin Alignment in Head-to-Tail CoupledOligo(1,4-phenyleneethynylene)s andOligo(1,4-phenylenevinylene)s Bearing Pendantp-Phenylenediamine Radical Cations
Synthesis and Optical Properties ofCross-ConjugatedBis(dimethylaminophenyl)pyridylvinyleneDerivatives
Pyrrolo-Annelated Tetrathiafulvalenes: The Parent Systems
The Effect of Polyamine Homologation on the Transport andCytotoxicity Properties of Polyamine−(DNA-Intercalator)Conjugates
Concurrent Induction of Two Chiral Centers from Symmetrical3,4-Disubstituted and 3,3,4-Trisubstituted 4-Pentenals UsingRh-Catalyzed Asymmetric Cyclizations
Synthesis and Characterization of the Native Anticodon Domainof E. coli tRNALys: Simultaneous Incorporation of ModifiedNucleosides mnm5s2U, t6A, and Pseudouridine UsingPhosphoramidite Chemistry
Preparation, Structure, and Unique Redox Properties of Mono-,Bis-, and Tris(diarylmethylene)-1,3,5-trithianesand Related Compounds
Solvent Effects on the Monobromination ofα,ω-Diols: A Convenient Preparation ofω-Bromoalkanols
Effect of Acyl Substituents on the Reaction Mechanism forAminolyses of 4-Nitrophenyl X-Substituted Benzoates
N- vs O-Protonation and the Transannular Substituent Interactionin 8-(Dimethylamino)-1-acetonaphthone
Highly Stereo- and RegioselectiveAllylations Catalyzed by Mo−PyridylamideComplexes: Electronic and Steric Effectsof the Ligand
Synthesis of 3,7-Anhydro-d-glycero-d-ido-octitol1,5,6-Trisphosphate as an IP3 Receptor Ligand Using a RadicalCyclization Reaction with a Vinylsilyl Tether as the Key Step.Conformational Restriction Strategy Using Steric Repulsionbetween Adjacent Bulky Protecting Groups on a Pyranose Ring
Theoretical Study of Intramolecular Aldol Condensation of1,6-Diketones: Trimethylsilyl Substituent Effect
The First Synthesis of the Pentacyclic Pyridoacridine MarineAlkaloids: Arnoamines A and B
A Convenient Method for the Synthesis of DNA-RecognizingPolyamides in Solution
Synthesis of Selectively Labeled d-Fructose and d-FructosePhosphate Analogues Locked in the Cyclic Furanose Form
Total Syntheses of (+)-Australine and (−)-7-Epialexine
Synthesis and Functionalization of DoublePicket Fence Porphyrins Starting from4,6-DisubstitutedPyrimidine-5-carbaldehydes
Enzymatic Kinetic Resolution of Piperidine Atropisomers: Synthesis of a Key Intermediate of the Farnesyl ProteinTransferase Inhibitor, SCH66336
Convenient Synthesis of3,4-methano-1,2,3,4-tetrahydroisoquinoline-3-carboxylic Acid andIts Derivatives as Doubly Constrained Nonproteinogenic AminoAcid Derivatives
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