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À propos de : Ferrocenyl Derivatives with One, Two, or Three Sulfur-ContainingArms for Self-Assembled Monolayer Formation        

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  • Ferrocenyl Derivatives with One, Two, or Three Sulfur-ContainingArms for Self-Assembled Monolayer Formation
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  • Self-assembled monolayers of electroactive molecules can form on gold electrodes if the moleculesinclude a sulfur-containing group to coordinate with the gold surface. We have prepared a moleculewith a tripod of sulfur groups that has the potential of fixing the geometry of the molecule relativeto the gold surface. The target (3) contained the good one-electron donor ferrocene connected througha benzene spacer to an isobutane tripod, with each arm of the tripod ending in a methylthio group.Analogous compounds with one (1) and two (2) coordinating arms were also prepared.
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