About: Unmasking the 6,7,5-Tricarbocyclic Frame of [5 + 2]/[4 + 2]Pyrone−Alkene Cycloadducts

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2000/volume_65/issue_8/w
Subject	Article
Title	Unmasking the 6,7,5-Tricarbocyclic Frame of [5 + 2]/[4 + 2]Pyrone−Alkene Cycloadducts
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2000/volume_65/issue_8/101021jo9917893/m/web http://hub.abes.fr/acs/periodical/joceah/2000/volume_65/issue_8/101021jo9917893/m/print
related by	http://hub.abes.fr/acs/periodical/joceah/2000/volume_65/issue_8/101021jo9917893/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2000/volume_65/issue_8/101021jo9917893/authorship/2 http://hub.abes.fr/acs/periodical/joceah/2000/volume_65/issue_8/101021jo9917893/authorship/3
Author	Castedo Luis Mascareñas José L. Ramón Rodríguez J.
Abstract	Opening of the bridging ether of 8-oxabicyclo[3.2.1]oct-6-ene systems 1,7-fused to a five-memberedcarbocycle that bears a double bond conjugated to that of the oxabicycle can be induced at lowtemperaure by the addition of an organolithium reagent. If this double bond is unsubstituted, theopening occurs via an anti-1,6-addition pathway, and if substituted it takes place by means of amore classical syn SN2‘ addition.
article type	research-article
is part of this journal	The Journal of Organic Chemistry

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