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À propos de : Photochemistry and Spectroscopy of “Stable Organic Radicals”: Steric and Electronic Effects in Intermolecular PhotoinducedElectron Transfer        

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  • Photochemistry and Spectroscopy of “Stable Organic Radicals”: Steric and Electronic Effects in Intermolecular PhotoinducedElectron Transfer
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  • The intermolecular reactivities of amino-substituted perchlorotriphenylmethyl radicals 1−3 werestudied, with particular emphasis on electron transfer (ET) reactions. The natural fluorescencelifetimes and the rates of the electron-transfer quenching were studied with several electron donorsand acceptors. Fluorescence quenching studies demonstrate the importance of the redox potentialsof the ET pair on the observed steric and electronic properties.
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