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À propos de : First Examples of Oxidizing Secondary Alcohols to Ketones in thePresence of the Disulfide Functional Group: Synthesis of NovelDiketone Disulfides        

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  • First Examples of Oxidizing Secondary Alcohols to Ketones in thePresence of the Disulfide Functional Group: Synthesis of NovelDiketone Disulfides
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  • The disulfide functionality is present in a number of organic compounds of interest in the fields ofboth chemistry and biology. Because the disulfide group is known to be highly susceptible to furtheroxidation by a wide range of agents, performing a chemoselective oxidation without further oxidizingthe disulfide moiety poses a synthetic challenge. Reported herein are the first examples of such achemoselective oxidation in which a series of novel secondary alcohol disulfides 2a−f have beenconverted to the corresponding symmetrical diketones 3a−f utilizing a modified Swern oxidation.
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